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Sum of covalent radii: r(S) = 1.04, 0.94, 0.87 and r(N) = 0.7, 0.6, 0.55 (for a single, double, triple bond); Holleman Wiberg, Lehrbuch der Anorganischen Chemie, 101. Aufl., Walter de Gruyter, 1995, Anhang IV and V.
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35648975064
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It is known that for adducts in the solid state and gas phase, structural data and donor-acceptor energies can be quite different. Leopold et al. have indicated that the donoracceptor bond is much shorter in the solid state than in the gas phase, and this change has been associated with the substantial dipole moment of the adduct;
-
(a) It is known that for adducts in the solid state and gas phase, structural data and donor-acceptor energies can be quite different. Leopold et al. have indicated that the donoracceptor bond is much shorter in the solid state than in the gas phase, and this change has been associated with the substantial dipole moment of the adduct;
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35
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0035133946
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and references therein
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36
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35649007128
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NBO population analysis for 1 and 3 was carried out with the structure fixed at that determined from X-ray analysis to investigate the bonding and hybridization in this experimentally observed species [single point at B3LYP level].
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NBO population analysis for 1 and 3 was carried out with the structure fixed at that determined from X-ray analysis to investigate the bonding and hybridization in this experimentally observed species [single point at B3LYP level].
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