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Volumn 633, Issue 13-14, 2007, Pages 2362-2366

Adducts of gallium trichloride and bis(trimethylsilyl)sulfur diimide

Author keywords

Bis(trimethylsilyl)sulfur diimide; Crystal structures; Heterocycles

Indexed keywords


EID: 35648976133     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200700245     Document Type: Article
Times cited : (17)

References (39)
  • 2
    • 28744451070 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 7790-7793.
    • (2005) Chem. Int. Ed , vol.44 , pp. 7790-7793
    • Angew1
  • 23
    • 35648954419 scopus 로고    scopus 로고
    • Sum of covalent radii: r(S) = 1.04, 0.94, 0.87 and r(N) = 0.7, 0.6, 0.55 (for a single, double, triple bond); Holleman Wiberg, Lehrbuch der Anorganischen Chemie, 101. Aufl., Walter de Gruyter, 1995, Anhang IV and V.
    • Sum of covalent radii: r(S) = 1.04, 0.94, 0.87 and r(N) = 0.7, 0.6, 0.55 (for a single, double, triple bond); Holleman Wiberg, Lehrbuch der Anorganischen Chemie, 101. Aufl., Walter de Gruyter, 1995, Anhang IV and V.
  • 29
    • 35648998258 scopus 로고    scopus 로고
    • E. D. Glendening, A. E. Reed, J. E. Carpenter, F. Weinhold, F. NBO Version 3.1;
    • (a) E. D. Glendening, A. E. Reed, J. E. Carpenter, F. Weinhold, F. NBO Version 3.1;
  • 32
    • 84926111067 scopus 로고    scopus 로고
    • F. Weinhold, C. Landis, Valency and Bonding. A Natural Bond Orbital Donor-Acceptor Perspective, Cambridge University Press, 2005 and references therein;
    • (d) F. Weinhold, C. Landis, Valency and Bonding. A Natural Bond Orbital Donor-Acceptor Perspective, Cambridge University Press, 2005 and references therein;
  • 34
    • 35648975064 scopus 로고    scopus 로고
    • It is known that for adducts in the solid state and gas phase, structural data and donor-acceptor energies can be quite different. Leopold et al. have indicated that the donoracceptor bond is much shorter in the solid state than in the gas phase, and this change has been associated with the substantial dipole moment of the adduct;
    • (a) It is known that for adducts in the solid state and gas phase, structural data and donor-acceptor energies can be quite different. Leopold et al. have indicated that the donoracceptor bond is much shorter in the solid state than in the gas phase, and this change has been associated with the substantial dipole moment of the adduct;
  • 36
    • 35649007128 scopus 로고    scopus 로고
    • NBO population analysis for 1 and 3 was carried out with the structure fixed at that determined from X-ray analysis to investigate the bonding and hybridization in this experimentally observed species [single point at B3LYP level].
    • NBO population analysis for 1 and 3 was carried out with the structure fixed at that determined from X-ray analysis to investigate the bonding and hybridization in this experimentally observed species [single point at B3LYP level].


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