Reactivity and utility of allenylphosphonates: Formation of a novel hydroperoxide and propargylic alcohol and facile thiol addition under catalyst-free, solvent-free conditions

Synthesis

Volumn , Issue 20, 2007, Pages 3171-3178

  Chakravarty, Manab ^a   Swamy, K C Kumara ^a  

^a UNIVERSITY OF HYDERABAD   (India)

Author keywords

Allenes; Allenylphosphonates; Horner Wadsworth Emmons reaction; Oxygenation; Thiol addition

Indexed keywords

ALLENES; ALLENYLPHOSPHONATES; HORNER-WADSWORTH-EMMONS REACTION; THIOL ADDITION;

ALCOHOLS; MOLECULAR OXYGEN; OXYGENATION; REACTION KINETICS; REGIOSELECTIVITY; X RAY CRYSTALLOGRAPHY;

PHOSPHORUS COMPOUNDS;

2 (2 CYCLOHEXYLSULFANYLPROP 1 ENYL) 5,5 DIMETHYL 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 2 (3 HYDROXY 3 METHYLBUT 1 YNYL) 5,5 DIMETHYL 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 2 (BUTA 1,2 DIENYL) 5,5 DIMETHYL 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 2 [(2 HYDROXYETHYL)SULFANYL] 3 METHYLBUT 2 ENYL] 5,5 DIMETHYL 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 2 [2 (4 CHLOROPHENYLSULFANYL) 3 METHYLBUT 2 ENYL] 5,5 DIMETHYL 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 2 [2 (4 CHLOROPHENYLSULFANYL)BUT 1 ENYL] 5,5 DIMETHYL 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 2 [2 (4 CHLOROPHENYLSULFANYL)BUT 2 ENYL] 5,5 DIMETHYL 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 2 [2 (4 CHLOROPHENYLSULFANYL)PROP 1 ENYL] 5,5 DIMETHYL 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 2 [2 (4 CHLOROPHENYLSULFANYL)PROP 2 ENYL] 5,5 DIMETHYL 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 4 CHLOROTHIOPHENOL; 5,5 DIMETHYL 2 (3 METHYLBUTA 1,2 DIENYL) 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; 5,5 DIMETHYL 2 (PROPA 1,2 DIENYL) 1,3,2 DIOXAPHOSPHINANE 2 OXIDE; ALCOHOL DERIVATIVE; ALLENE DERIVATIVE; HYDROPEROXIDE; OXIDE; PHOSPHONIC ACID DERIVATIVE; PROPARYGYLIC ALCOHOL; SOLVENT; THIOL DERIVATIVE; THIOPHENOL DERIVATIVE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYST; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; HEATING; HORNER WADSWORTH EMMONS REACTION; MICROWAVE RADIATION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 35549010981     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-990794     Document Type: Article

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