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- ion was refined with geometrical constraints (B-F fixed at 1.43 Å). The hydrogen atoms attached to carbon atoms in the complex were generated and assigned isotropic thermal parameters, riding on their parent carbon atoms. CCDC-245747 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk). The powder diffractogram of 1 was registered on a Philips X'Pert diffractometer to be sure that the samples contained only one phase. All reflections were indexed with the cell parameters obtained from the single-crystal X-ray study on 1.
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- ion was refined with geometrical constraints (B-F fixed at 1.43 Å). The hydrogen atoms attached to carbon atoms in the complex were generated and assigned isotropic thermal parameters, riding on their parent carbon atoms. CCDC-245747 (1) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12, Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk). The powder diffractogram of 1 was registered on a Philips X'Pert diffractometer to be sure that the samples contained only one phase. All reflections were indexed with the cell parameters obtained from the single-crystal X-ray study on 1.
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