Porphyrins with exocyclic rings. Part 22: Synthesis of deoxophylloerythroetioporphyrin (DPEP), three ring homologues, and five related nonpolar bacteriopetroporphyrins using a western ring closure and an improved b-bilene methodology

Tetrahedron

Volumn 63, Issue 50, 2007, Pages 12324-12342

  Lash, Timothy D ^a   Li, Wei ^a   Quizon Colquitt, Desiree M ^a  

^a ILLINOIS STATE UNIVERSITY   (United States)

Author keywords

b Bilenes; Cyclopenta b pyrroles; Petroporphyrins; Porphyrin synthesis; Pyrrole chemistry

Indexed keywords

2,4 HEPTANEDIONE; 3 METHYL 2,4 HEPTANEDIONE; 3,6 DIMETHYL 2,4 HEPTANEDIONE; 6 (5 TERT BUTOXYCARBONYL 3 ETHYL 4 METHYL 2 PYRROLYL) 3 ETHYLCYCLOPENTA[B]PYRROLE 2 CARBOXYLIC ACID; 6 METHYL 2,4 HEPTANEDIONE; 7 (5 TERT BUTOXYCARBONYL 3 ETHYL 4 METHYL 2 PYRROLYL) 3 METHYL 4,5,6,7 TETRAHYDROINDOLE 2 CARBOXYLIC ACID; BACTERIOPETROPORPHYRIN DERIVATIVE; BENZYL 3 ETHYL 4,5 DIMETHYLPYRROLE 2 CARBOXYLATE; BENZYL 3 ETHYLCYCLOPENTA[B]PYRROLE 2 CARBOXYLATE; BENZYL 3 ISOBUTYL 4,5 DIMETHYLPYRROLE 2 CARBOXYLATE; BENZYL 4,5 DIMETHYL 3 PROPYLPYRROLE 2 CARBOXYLATE; BENZYL 5 ACETOXYMETHYL 3 ETHYL 4 METHYLPYRROLE 2 CARBOXYLATE; BENZYL 5 ACETOXYMETHYL 3 ISOBUTYL 4 METHYLPYRROLE 2 CARBOXYLATE; BENZYL 5 ACETOXYMETHYL 4 METHYL 3 PROPYLPYRROLE 2 CARBOXYLATE; BENZYL 5' TERT BUTOXYCARBONYL 3' ETHYL 3,4' DIMETHYL 3 PROPYL 2,2' DIPYRRYLMETHANE 5 CARBOXYLATE; BENZYL 5' TERT BUTOXYCARBONYL 3' ETHYL 4 ISOBUTYL 3,4' DIMETHYL 2,2' DIPYRRYLMETHANE 5 CARBOXYLATE; BENZYL 5' TERT BUTOXYCARBONYL 3',4 DIETHYL 3,4' DIMETHYL 2,2' DIPYRRYLMETHANE 5 CARBOXYLATE; BENZYL 5' TERT BUTOXYCARBONYL 4 ETHYL 3,3',4' TRIMETHYL 2,2' DIPYRRYLMETHANE 5 CARBOXYLATE; BENZYL 6 (5 TERT BUTOXYCARBONYL 3 ETHYL 4 METHYL 2 PYRROLYL) 3 ETHYLCYCLOPENTA[B]PYRROLE 2 CARBOXYLATE; BENZYL 6 ACETOXY 3 ETHYLCYCLOPENTA[B]PYRROLE 2 CARBOXYLATE; BENZYL 7 (TERT BUTOXYCARBONYL 3 ETHYL 4 METHYL 2 PYRROLYL) 3 METHYL 4,4,6,7 TETRAHYDROINDOLE 2 CARBOXYLATE; BENZYL 8 (TERT BUTOXYCARBONYL 3 ETHYL 4 METHYL 2 PYRROLYL) 3 METHYLCYCLOHEPTA[B]PYRROLE 2 CARBOXYLATE; BENZYL 9 (TERT BUTOXYCARBONYL 3 ETHYL 4 METHYL 2PYRROLYL) 3 METHYLCYCLOOCTA[B]PYRROLE 2 CARBOXYLATE; CARBOXYLIC ACID DERIVATIVE; DEOXOPHYLLOERYTHROETIOPORPHYRIN; ETHYL 3 ISOBUTYL 4,5 DIMETHYLPYRROLE 2 CARBOXYLATE; ETHYL 4,5 DIMETHYL 3 PROPYLPYRROLE 2 CARBOXYLATE; ETIOPORPHYRIN DERIVATIVE; PORPHYRIN DERIVATIVE; TERT BUTYL 4 ETHYL 3 METHYLPYRROLE 2 CARBOXYLATE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHROMATOGRAPHY; CYCLIZATION; DEPROTECTION REACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PRIORITY JOURNAL; SYNTHESIS;

EID: 35548963731     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2007.09.059     Document Type: Article

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