메뉴 건너뛰기




Volumn 126, Issue 49, 2004, Pages 16058-16065

Deoxygenation and other photochemical reactions of aromatic selenoxides

Author keywords

[No Author keywords available]

Indexed keywords

CONDENSATION; DERIVATIVES; OXIDATION; PHOTOLYSIS; SELENIUM COMPOUNDS; SOLVENTS;

EID: 10344224062     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja045935k     Document Type: Article
Times cited : (46)

References (67)
  • 1
    • 10344246042 scopus 로고    scopus 로고
    • note
    • Photochemistry and Photophysics of Aromatic Sulfoxides. 22. For paper 21 in the series, see ref 29.
  • 10
    • 0003063471 scopus 로고
    • Patai, S., Rappaport, Z., Stirling, C. J. M., Eds.; John Wiley & Sons Ltd.: New York
    • Still, I. W. J. In The Chemistry of Sulfones and Sulfoxides; Patai, S., Rappaport, Z., Stirling, C. J. M., Eds.; John Wiley & Sons Ltd.: New York. 1988; pp 873-887.
    • (1988) The Chemistry of Sulfones and Sulfoxides , pp. 873-887
    • Still, I.W.J.1
  • 25
    • 10344221528 scopus 로고    scopus 로고
    • note
    • The photochemistry of pyridine oxides is complex. Unfortunately, only a small percentage of the material undergoes deoxygenation.
  • 35
    • 10344222084 scopus 로고    scopus 로고
    • note
    • The solvent obscured the HPLC retention time of X and Y when toluene was used.
  • 37
    • 10344258533 scopus 로고    scopus 로고
    • note
    • The spectrum is given in the Supporting Information.
  • 38
  • 39
    • 10344260630 scopus 로고    scopus 로고
    • note
    • The spectrum is given in the Supporting Information.
  • 43
    • 10344249863 scopus 로고    scopus 로고
    • note
    • We also note that the apparent quantum yield is somewhat lower in deuterated benzene than in ordinary benzene. We attribute this to a low level of quenching impurities in the deuterated solvent, which is not subject to the same level of purification as the "spectrograde" ordinary benzene we ordinarily use.
  • 47
    • 10344240341 scopus 로고    scopus 로고
    • note
    • The G3Large basis set for Se is not currently implemented in Gaussian, though it is available from PNNL.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.