Dissociation of acetaldehyde on β-Mo2C to yield ethylidene and oxo surface groups: A possible pathway for active site formation in heterogeneous olefin metathesis

Journal of the American Chemical Society

Volumn 126, Issue 31, 2004, Pages 9514-9515

  Siaj, Mohamed ^a   Reed, Corey ^b   Oyama, S Ted ^b   Scott, Susannah L ^c   McBreen, Peter H ^a  

^a UNIVERSITÉ LAVAL   (Canada)

^b State University   (United States)

^c University of California   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETALDEHYDE; ALKENE; OXOACID;

ANALYTIC METHOD; ARTICLE; CATALYSIS; DISSOCIATION; FOURIER TRANSFORMATION; INFRARED SPECTROSCOPY; REACTION ANALYSIS; RING CLOSING METATHESIS; SURFACE PROPERTY;

EID: 3543117327     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja048640f     Document Type: Article

References (40)

1. (a) Hérisson, P. L.; Chauvin, Y. Makromol. Chem. 1970, 141, 161.
2. (b) Trnka, T. M.; Grubbs, R. H. Acc. Chem. Res. 2001, 34, 18.
3. (c) Schrock, R. R. Chem. Rev. 2002, 102, 145.
4. (a) Ivin, K. J.; Mol, J. C. Olefin Metathesis and Metathesis Polymerisation; Academic Press: San Diego, 1997.
5. (b) Spessard, G. O.; Miessler, G. L. Organometallic Chemistry; Prentice-Hall: Englewood Cliffs, NJ, 1997.
6. (a) Wu, G.; Tysoe, W. T. Surf. Sci. 1998, 397, 197.
7. (b) Ephritikhine, M.; Green, M. L. H. J. Chem. Soc., Chem. Commun. 1976, 926.
8. (c) Fischer, E. O.; Held, W. J. Organomet. Chem. 1976, 112, C56.
9. (d) Laverty, D. T.; Rooney, J. J.; Stewart, A. J. Catal. 1976, 45. 110.
10. (e) Schrock, R. R. J. Am. Chem. Soc. 1975, 97, 6577.
11. (f) Chen, X.; Zhang, X.; Chen, P. Angew. Chem., Int. Ed. 2003, 42, 3798.
12. (a) Handzlik, J.; Ogonowski, J. Catal. Lett. 2003, 88, 119.
13. (b) Brenner, A.; Burwell, R. L., Jr. J. Catal. 1978, 52, 364.
14. Zahidi, E.; Oudghiri Hassani, H.; McBreen, P. H. Nature 2001, 409, 1023.
15. (a) Kapoor, R.; Oyama, S. T. In Synthesis and Characterization of Advanced Materials; Serio, M. A., Gruen, D. M., Malhotra, R., Eds.; ACS Symposium Series 681; American Chemical Society: Washington, DC, 1996.
16. (b) Wang, J.; Castonguay, M.; Deng, J.; McBreen, P. H. Surf. Sci. 1997, 374, 197.
17. (a) Kim, S. H.; Stair, P. C. Surf. Sci. 2000, 457, L347.
18. (b) Nart, F. C.; Friend, C. M. J. Phys. Chem. B 2001, 105, 2773.
19. Shekhar, R.; Barteau, M. A.; Plank, R. V.; Vohs, J. M. J. Phys. Chem. B 1997, 101, 7939.
20. Wiberg, K. B.; Thiel, Y.; Goodman, L.; Leszczynski, J. J. Phys. Chem. 1995, 99, 13850.
21. DFT calculations were performed using Gaussian 98, B3LYP correlation functional, and LANL2DZ basis set. A scaling factor of 0.9516 was used for the vibrational frequencies. (a) Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
22. (b) Pople, J. A.; Head-Gordon, M.; Fox, D. J.; Raghavachari, K.; Curtiss, L. A. J. Chem. Phys. 1989, 90, 5622
23. Vikulov, K. A.; Shelimov, B. N.; Kazansky, V. B. J. Mol. Catal. 1991, 65, 393.
24. Handzlik, J. J. Catal. 2003, 220, 23. Handzlik, J. J. Mol. Catal. A 2004, 218, 91.
25. Handzlik, J. J. Catal. 2003, 220, 23. Handzlik, J. J. Mol. Catal. A 2004, 218, 91.
26. (a) Korolev, A. V.; Rheingold, A. L.; Williams, D. S. Inorg. Chem. 1997, 36, 2647.
27. (b) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds; Wiley: New York. 1988.
28. Cheon, J.; Dubois, L. H.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6814.
29. (a) Chen, J. G.; Colaianni, M. L.; Weinberg, W. H.; Yates, J. T., Jr. Chem. Phys. Lett. 1991, 177, 113.
30. (b) Houston, J. E. Surf. Sci. 1991, 255, 303.
31. (c) Shinn, N. D.; Madey, T. E. Phys. Rev. Lett. 1984, 53, 2481.
32. (d) Zaera, F.; Kollin, E.; Gland, J. L. Chem. Phys. Lett. 1985, 121, 464.
33. (a) Chisholm, M. H.; Huffman, J. C.; Lucas, E. A.; Sousa, A.; Streib, W. E. J. Am. Chem. Soc. 1992, 114, 2711.
34. (b) Chisholm, M. L. H.; Folting, K.; Glasgow, K. G. Lucas, E. Streib, W. E. Organometallics 2000, 19, 884.
35. (a) Bryan, J. C.; Mayer, J. M. J. Am. Chem. Soc. 1987, 109, 7213.
36. (b) Bryan, J. C.; Mayer, J. M. J. Am. Chem. Soc. 1990, 112, 2298.
37. Desikan, N. A.; Zhang, W.; Oyama, S. T. J. Catal. 1995, 157, 740.
38. Basrur, G.; Patwardhan, S. R.; Vyas, S. N. J. Catal. 1991, 127, 86.
39. Sullivan, D. L.; Roark, R. D.; Eckerdt, J. G.; Deutsch, S. E.; Gates, B. C. J. Phys. Chem. 1995, 99, 3678.
40. Villiers, C.; Ephritikhine, M. J Chem. Eur. J. 2001, 7, 3043.