Facile synthesis of C2-symmetric chiral crown ethers with two reactive hydroxymethyl groups

Synthesis

Volumn , Issue 19, 2007, Pages 2973-2978

  Nakatsuji, Yohji ^a   Nakahara, Yoshio ^b   Nagamiya, Katsumori ^b   Itoh, Yuki ^b   Uesugi, Kentaro ^b   Ishida, Naohisa ^a   Muraoka, Masahiro ^b   Kida, Toshiyuki ^b   Akashi, Mitsuru ^b  

^a OSAKA INSTITUTE OF TECHNOLOGY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

C pivot carbons; C2 symmetric chiral crown ethers; Chiral subunit; Lipase ql; Optical resolution

Indexed keywords

C-PIVOT CARBONS; CHIRAL SUBUNIT; LIPASE QL; OPTICAL RESOLUTION;

METHANOL; SYNTHESIS (CHEMICAL);

ETHERS;

({[2,2,4 TRIMETHYL 1,3 DIOXOLANE 4 YL]METHOXY}ETHOXY) 4 TOLUENESULFONATE; 1,3 DIOXOLANE DERIVATIVE; 2 METHYLPROPANE 1,2,3 TRIOL; 2 {[ 2,2,4 TRIMETHYL 1,3 DIOXOLANE 4 YL]METHOXY}ETHANOL; 2,12 BIS(BENZYLOXYMETHYL) 2,12 DIMETHYL 1,4,7,10,13,16 HEXAOXACYCLOOCTADECANE; 2,12 BIS(HYDROXYMETHYL) 2,12 DIMETHYL 1,4,7,10,13,16 HEXAOXACYCLOOCTADECANE; 3 BENZYLOXY 2 METHYLPROPANE 1,2 DIOL; 4 BENZYLOXYMETHYL 2,2,4 TRIMETHYL 1,3 DIOXOLANE; 4,14 DIMETHYL 1,17 DIPHENYL 2,6,9,12,16 PENTAOXAHEPTADECANE 4,14 DIOL; [2,2,4 TRIMETHYL 1,3 DIOXOLANE 4 YL]METHANOL; [2,2,4 TRIMETHYL 1,3 DIOXOLANE 4 YL]METHYL ACETATE; ALCOHOL DERIVATIVE; DECANE; ESTER DERIVATIVE; PROPANE; SULFONIC ACID DERIVATIVE; UNCLASSIFIED DRUG; {[ 2,2,4 TRIMETHYL 1,3 DIOXOLANE 4 YL]METHOXY}ACETIC ACID METHYL ESTER;

ACETALIZATION; ARTICLE; CHEMICAL REACTION; CHIRALITY; GAS CHROMATOGRAPHY; HYDROGENATION; HYDROLYSIS; OPTICAL RESOLUTION; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 35348982425     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-983892     Document Type: Article

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