Application of N,N′-Dimethyl-N,N′-Di(4-Chlorophenyl) tetradecyl malonamide for the selective recovery of iron(III) from Concentrated chloride solutions

Solvent Extraction and Ion Exchange

Volumn 25, Issue 6, 2007, Pages 791-807

  Mowafy, E A ^a  

^a Atomic Energy Authority   (Egypt)

Author keywords

Hydrochloric acid; Iron(III); N,N dimethyl N,N di(4 chlorophenyl)tetradecyl malonamide; Solvent extraction

Indexed keywords

AMIDES; BINARY MIXTURES; HYDROCHLORIC ACID; IRON; METAL RECOVERY; TOLUENE;

MULTICOMPONENT MIXTURES; QUANTITATIVE STRIPPING; SELECTIVE RECOVERY;

SOLVENT EXTRACTION;

AMIDES; BINARY MIXTURES; HYDROCHLORIC ACID; IRON; METAL RECOVERY; SOLVENT EXTRACTION; TOLUENE;

EID: 35248887478     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366290701634321     Document Type: Article

References (40)

1. Saji, J., Rao, T. Prasada, Iyer, C. S. P. and Reddy, M. L. P. (1998) Extraction of iron(III) from acidic chloride solutions by Cyanex 923. Hydrometallurgy, 49, pp. 289-296.
2. Saji, J., Rao, T. Prasada, Ramamohan, T. R. and Reddy, M. L. P. (1999) Studies on the liquid-liquid extraction of iron(III) and titanium(IV) with 3-phenyl-4-benzoyl-5-isoxazolone. Talanta, 50, pp. 1065-1071.
3. -3 HCl media. Hydrometallurgy, 57:2, pp. 151-165.
4. Voshkin, A. A., Belova, V. V. and Kholkin, A. I. (2003) Extraction of iron by binary extractants based on quaternary ammonium bases and organic acids. Russ. J. Inorg. Chem., 48:4, pp. 608-613.
5. Mettzler, D. E. and Myers, R. J. (1950) The distribution of ferric ion between hydrochloric acid and isopropyl ether solutions. III. Spectral, isopiestic and magnetic susceptibility studies. J. Am. Chem. Soc., 72, pp. 3776-3789.
6. Sekine, T., Horida, H. and Zeniya, Y. (1979) Kinetic studies of solvent extraction of metal complexs VI. Equilibrium and rate of solvent extraction of iron(III) perchlorate with trioctylphosphine oxide in hexane. J. Inorg. Nucl. Chem., 38, pp. 1347-1350.
7. Dalton, R. F., Diaz, G., Price, R. and Zunckel, A. D. (1991) The Cuprex metal extraction process: Recovering from sulfides ores. JOM, 43:8, pp. 51-56.
8. Ritcey, G. M. and Ashbrook, A. W. (1979) Solvent Extraction-Principles and Application to Process Metallurgy; Elsevier: Amsterdam, pp. 253-361.
9. Reddy, B. R. and Sarma, P. V.R. Bhaskara (1996) Extraction of iron(III) at macro-level concentrations using TBP, MIBK and their mixtures. Hydrometallurgy, 43, pp. 299-306.
10. Majumdar, S. K. and De, A. K. (1960) Liquid-liquid extraction of iron(III) with tributylphosphate: Separation from mixtures. Talanta, 7, pp. 1-6.
11. Cox, M. (1992) Solvent extraction in hydrometallurgy. Principle and Particles of Solvent Extraction, pp. 357-412. Marcel Dekker: Inc, New York
12. Edward, R. I. and Riele, W. A.M. te (1983) Commercial processes for precious metals. Handbook of Solvent Extraction, pp. 725-732. John Wiley and Son, New York
13. Islam, F., Biswas, R. K. and Mustafa, G. M. (1985) Solvent extraction of Ti(IV), Fe(III), and Fe(II) from acidic sulfate medium with di-o-tolyl phosphoric acid-benzene - hexan-1-ol system: A separation and mechanism study. Hydrometallurgy, 13, pp. 365-376.
14. Alguacil, F. J. and Amer, S. (1986) The extraction of iron(III) from aqueous sulphate solutions by primene sulphate. Hydrometallurgy, 15, pp. 337-350.
15. Alguacil, F. J., Amer, S. and Luis, A. (1987) The influence of the diluent on the extraction of iron(III) from aluminium sulphate solutions by the amine primene 81R sulphate. Hydrometallurgy, 18, pp. 65-73.
16. Biswas, R. K. and Begum, D. A. (1999) Study of kinetics of forward extraction of iron(III) from chloride medium by di-2-ethylhexylphosphoric acid in kerosene using the single drop technique. Hydrometallurgy, 54:1, pp. 1-23.
17. Biswas, R. K. and Begum, D. A. (1998) Solvent extraction of iron(III) from chloride solution by D2EHPA. Hydrometallurgy, 50:2, pp. 153-168.
18. Roddy, J. W., Coleman, C. F. and Arai, S. (1971) Mechanism of the slow extraction of iron(III) from acid perchlorate solutions by di(2-ethylhexyl)phosphoric acid in n-octane. Inorg. Nucl. Chem., 33, pp. 1099-1118.
19. Cote, G. (2000) Hydrometallurgy of strategic metals. Solvent Extr. Ion Exch., 18:4, pp. 703-727.
20. Islam, F., Rahman, H. and Ali, M. (1979) Solvent extraction separation study of Ti(IV), Fe(III), and Fe(II) from aqueous solutions with di-2-ethylhexyl phosphoric acid in benzene. Inorg. Nucl. Chem., 41, pp. 217-221.
21. Sahu, K. K. and Das, R. P. (2000) Mixed solvent systems for the extraction and stripping of iron(III) from concentrated acid chloride solutions. Met. Mater. Trans. B., 31, p. 1169.
22. Sahu, K. K. and Das, R. P. (1997) Synergistic Extraction of iron(III) at higher concentrations in D2EHPA-TBP mixed solvent systems. Met. Mater. Trans. B., 28, p. 181.
23. Rao, P. R. Vasudeva and Kolarik, Zdenek (1996) A review of third phase formation in extraction of actinides by neutral organophosphorus extractants. Solvent Extr. Ion Exch., 14:6, pp. 955-993.
24. Agatzini, S., Kontopoulos, A., Marabouties, P. and Xenidis, A. (1986) Removel of iron from iron-nickel-cobalt solution by precipitation and solvent extraction techniques. Iron Control in Hydrometallurgy, pp. 353-373. Ellis Horwood, Chichester
25. Hirato, T., Zhi-Chu, W., Yamada, Y. and Majima, H. (1992) Improvement of the stripping characteristics of Fe(III) utilizing a mixture of di(2-ethylhexyl) phosphoric acid and tri-n-butylphosphate. Hydrometallurgy, 28:1, pp. 81-93.
26. Paiva, A. P. and Costa, M. C. (2005) Application of N,N′-tetrasubstituted malonamides to the recovery of iron(III) from chloride solutions. Hydrometallurgy, 77, pp. 103-108.
27. Mowafy, E. A. and Aly, H. F. (2006) Extraction behaviors of trivalent lanthanides from nitrate medium by selected malonamides, Solvent Extr. Ion Exch., 24, pp. 677-692.
28. Cuillerdier, C., Musikas, C. and Nigond, L. (1993) Diamides as actinide extractants for various waste treatments, Sep. Sci. Technol., 28:1, pp. 155-175.
29. Madic, C. (1993) Elaborated reprocessing separation of minor actinides from high-level radioactive raffinates. The DIAMEX Process. The plutonium in Question (SFEN) Paris, France
30. Madic, C., Lecomte, M., Baron, P. and Boullis, B. (2002) Separation of long-lived radionuclides from high active nuclear waste. C. R. Phys., 3, pp. 797-811.
31. Mahajan, G. R., Prabhu, D. R., Manchanda, V. K. and Badheka, L. P. (1998) Substituted malonamides as extractants for partitioning of actinides from nuclear waste solutions. Waste Management, 18, pp. 125-133.
32. Mowafy, E. A. and Aly, H. F. (2002) Extraction behaviors of Nd(III), Eu(III), La(III), Am(III), and U(VI) with some substituted malonamides from nitrate medium. Solvent Extr. Ion Exch., 20:2, pp. 177-194.
33. Spjuth, L., Liljenzin, J. O., Hudson, M. I., Drew, M. G. B., Iveson, P. B. and Madic, C. (2000) Comparison of extraction behavior and basicity of some substituted malonamides. Solvent Extr. Ion Exch., 18:1, pp. 1-23.
34. Mowafy, E. A., El-Naggar, I. M. and Shalash, A. M. (2004) Extraction and separation of U(VI), Th(IV), and Fe(III) with N,N-di-alkyl-4-pyridine carboxamides and N,N'-tetra-alkyl-2,6-pyridine dicarboxamides as new organic extractants from chloride medium. Arab. J. Nucl. Sci. Appl., 37:3, pp. 69-82.
35. Costa, M. C., Martins, M. and Paiva, A. P. (2004) Solvent extraction of iron(III) from acidic chloride media using N,N'-dimethyl-N,N'dibutylmalonamide. Sep. Sci. Tech., 39:15, pp. 3573-3599.
36. Costa, M. C., Carvalho, A., Uryga, A. and Paiva, A. P. (2003) Solvent extraction of iron(III) from hydrochloric acid solutions using N,N prime-dimethyl-N,N′-diphenylmalonamide and N,N′-dimethyl-N,N′-diphenyltetradecylmalonamide. Solvent Extr. Ion Exch., 21:5, pp. 653-686.
37. Mowafy, E. A., Shalash, A. M. and El-Naggar, I. M. (2003) Extraction of certain radionuclides by dipicolinamides as new extractants from nitric acid medium. Indian J. Chem., 42, p. 3012.
38. Mowafy, E. A. (2007) Evaluation of selectivity and radiolysis behavior of some promising isonicotinamides and dipicolinamides as extractants, Radiochim. Acta., 95, pp. 539-545.
39. Tain, Q. and Hughes, A. (1994) Synthesis and characterization of diamides extractants for the extraction of neodymium. Hydrometallurgy, 36, pp. 79-94.
40. Chan, G. Y. S., Drew, M. G. B., Hudson, M. J., Iveson, P. B., Liljenzin, J. -O., Skalberg, M., Spjuth, L. and Madic, C. (1997) Solvent Extraction of metal ions from nitric acid solution using N,N.substituted malonamides. Experimental and crystallographic evidence for two mechanisms of extraction, metal complexation and ion-pair formation. J. Chem. Soc., Dalton Trans., pp. 649-660.