Extraction behaviors of trivalent lanthanides from nitrate medium by selected substituted malonamides

Solvent Extraction and Ion Exchange

Volumn 24, Issue 5, 2006, Pages 677-692

  Mowafy, E A ^a   Aly, H F ^a  

^a Egyptian Atomic Energy Authority   (Egypt)

Author keywords

Lanthanides; Liquid extraction; Malonamides extractants; Nitric acid

Indexed keywords

EXTRACTION; NITRATES; NITRIC ACID; STOICHIOMETRY; SYNTHESIS (CHEMICAL);

LIQUID EXTRACTION; MALONAMIDES EXTRACTANTS; NITRATE MEDIUM; TRIVALENT LANTHANIDES;

RARE EARTH ELEMENTS;

EXTRACTION; NITRATES; NITRIC ACID; RARE EARTH ELEMENTS; STOICHIOMETRY; SYNTHESIS (CHEMICAL);

EID: 33747070830     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366290600762322     Document Type: Article

References (31)

1. Madic, C. and Hudson, C.(1998) High level liquid waste partitioning by means of completely incinerable extractants, Report Number EUR 18038 EN. In. European Commission on Nuclear Science and Technology.
2. Myung, Chan. and Duk-Jun, Koh. and Sung, Shin.(1995). Feasibility study on transmutation of minor actinides in conventional fission power reactors. Proceedings of The International Conference VersaillesFranceSept 11-15. In In evaluation of emerging nuclear fuel cycle systems-global 95 [pp. 1098 -].
3. Cuillerdier, C. and Musikas, C. and Hoel, P. and Nigond, L. and Vitart, X. (1991) Malonamides as new extractants for nuclear waste solutions Sep. Sci. Technol., 23(9), pp. 1229-1244.
4. Nigond, N. and Condamies, P. and Cordier, J. and Livet, C. and Madic, C. and Cuillerdier, C. and Musikas, C. and Hudson, M. (1995) Recent advances in the treatment of nuclear waste by the use of the diamide and picolinamide extractant Sep. Sci. Technol., 30, pp. 2075.
5. Mowafy, E. and Aly, H. (2002) Extraction behaviors of Nd(III), Eu(III), La(III), Am(III), and U(VI) with some substituted malonamides from nitrate medium Solvent Extr. Ion Exch., 20(2), pp. 177-194.
6. Madic, C.(1993). Elaborated reprocessing separation of minor actinides from high-level radioactive raffinates. The Plutonium in Question (SFEN) ParisFranceApril 27. In The DIAMEX Process [pp.]. CEA-CONF-11740
7. Nash, K. (1993) Review of the basic chemistry and recent development of trivalent-f-elements Separation Solvent Extr. Ion Exch., 11, pp. 729.
8. Nash, K. and Rickert, P. (1993) Thermal unstable complexants: Stability of Lanthanide/Actinide complexes, thermal instability of the ligands, and applications in actinide separations Sep. Sci. & Technol, 28, pp. 25-41.
9. Mathur, J. and Murali, M. and Nash, K. (2001) Actinides partitioning-A Review Solvent Extr. Ion Exch., 19, pp. 357.
10. Thiollet, G. and Musikas, C. (1989) Synthesis and use of the amides extractants Solvent Extr. Ion Exch., 7(5), pp. 813-827.
11. Charbonnel, M. and Musikas, C.(1986). Extraction of Actinides and Fission Products Ions by Non-Chelating N,N′-Teraalkyldiamides. Proceeding of The International Solvent Extraction Conference-ISEC'86 MunichGermanySep 11-16. In [pp.].
12. Wang, Y. and Sun, G. and Bao, B. (1997) N,N,N′,N′-Tetrabutylmalonamides as a new extractant for extraction of Nitric Acid and Uranium(VI) in Toluene J. Radioanal. Nucl. Chem., 244, pp. 151-153.
13. Spjuth, L. and Liljenzin, J. and Skalberg, M. and Hudson, M. and Chan, G. and Drew, M. and Feaviour, M. and Iveson, P. and Madic, C. (1997) Extraction of actinides and lanthanides from nitric acid solution by malonamides Radiochim. Acta., 78, pp. 39.
14. Spjuth, L. and Liljenzin, J. and Hudson, M. and Drew, M. and Iveson, P. and Madic, C. (2000) Comparison of extraction behavior and basicity of some substituted malonamides Solvent Extr. Ion Exch., 18(1), pp. 1-23.
15. Mahajan, G. and Prabhu, D. and Manchanda, V. and Badheka, L. (1998) Substituted Malonamides as extractants for partitioning of actinides from nuclear waste solutions Waste Management., 18, pp. 125-133.
16. Tian, Q. and Hughes, M. (1994) Synthesis and characterization of diamide extractants for the extraction of neodymium Hydrometallurgy., 36, pp. 79-94.
17. Lefrancois, L. and Hebrant, M. and Tondre, C. and Delpuech, J. and Berthon, C. and Madic, C. (1999) Z,E Isomerism and hindered rotations in malonamides: An NMR study of N,N′-dimethyl-N,N′-dibutyl-2-tertradecylpropane-1,3-diamide J. Chem. Soc., Perkin Trans., 2, pp. 1149.
18. Sakaki, Y. and Tachimori, S. (2002) Extraction of Actinides (III), (IV), (VI) and Lanthanides (III) by structurally tailored diamides Solvent Extr. Ion Exch., 20(1), pp. 21-34.
19. Nakamura, T. and Miyake, C. (1995) Extraction of Lanthanide(III) and Uranyl (VI) from nitric acid solution by N,N′-dimethyl-N,N-dibutylmalonamide Solvent Extr. Ion Exch., 13(2), pp. 235-273.
20. El-Reefy, S. and Mowafy, E. and Abdel-Badei, M. and Aly, H. (1997) Extraction of Uranium and selected fission products from nitric acid medium by certain diamides Radiochemica Acta, 77, pp. 195-206.
21. Mowafy, E. and Aly, H. (2001) Extraction of actinides and selected fission product from nitric acid medium using long chain monoamides Solvent Extr. Ion Exch., 19(4), pp. 629-641.
22. Mowafy, E. and Aly, H. (2001) Synthesis and characterization of N,N,N′N″-tetrabutyl-succinamide as extracrant for Uranium(VI) and Thorium(IV) Ions from Nitric Acid Solution J. Radioanal. Chem., 250(1), pp. 199-203.
23. Mowafy, E. and Shalash, A. and El-Naggar, I. (2003) Extraction of certain radionuclides by bipicolinamides as new extractants from nitric acid medium Indian Journal of Chemistry, 42, pp. 3012-3016.
24. Mowafy, E.(1999) Extraction of some elements of nuclear interest by new organic extractants. PhD Thesis. In. Zagazig Univ.
25. Marezenko, Z.(1986) Rare earth elements (Lanthanides and Yttrium). In In Spectrophotometric Determination of Elements. (pp. 438-447). John Wiley and Sons Inc.
26. Horwitz, E. and Martin, K. and Diamond, H. and Kaplan, L. (1986) Extraction of Am from nitric acid by carbameyl-phosphoryl extractants: The influence of substituents on the selectivity of Am over Fe and selected fission products Solvent Extr. Ion Exch., 4, pp. 449.
27. Sun, Guoxin and Cui, Yu and Xu, Rongqi and Jiang, Runtian and Sun, Sixiu. (2003) Extraction of Dy(III) with N,N,N′,N′-tetrabutylmalonamide J. Radioanal. Nucl. Chem., 258(1), pp. 181-184.
28. Nigond, L. and Musikas, C. and Cullerdier, C. (1994) Extraction by N,N,N′,N′-teraalkyl-2-alkylpropane-1,3-diamides II. U(VI) and Pu(IV). Solvent Extr. Ion Exch., 12(2), pp. 297-323.
29. 3 and other inorganic acids. Solvent Extr. Ion Exch., 6(6), pp. 1007-1034.
30. Nigond, L.(1992) Extracting Propeeties of N,N,N′,N′-tetraalkyl-2-alkylpropane-1,3-Diamides. PhD Thesis. In. University of Clermont -Ferrand II. CEA-R-5610
31. McNamara, B. and Lumetta, G. and Rapko, B. (1999) Extraction of Europium ion with terahexylmalonamides Solvent Extr. Ion Exch., 17(6), pp. 1403-1421.