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ox values were obtained for solutions of 1-3 as diastereomeric mixtures. Note that the values were not sensitive to the diastereoisomerism as the CV's were identical for dl- and meso-3.
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ox values were obtained for solutions of 1-3 as diastereomeric mixtures. Note that the values were not sensitive to the diastereoisomerism as the CV's were identical for dl- and meso-3.
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All attempts to separate the enantiomers of 1 were unsuccessful. We tested the following chiral columns with a variety of eluents, i.e., Daicel Chiralcel OD-H, OJ, AD, IA, IB, OJ-RH, and OD-RH as well as Sumichiral OA-2000 and OA-3300.
-
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