Synthesis, structure, and evaluation of the effect of multiple stacking on the electron-donor properties of π-stacked polyfluorenes

Journal of the American Chemical Society

Volumn 125, Issue 29, 2003, Pages 8712-8713

  Rathore, Rajendra ^a   Abdelwahed, Sameh H ^a   Guzei, Ilia A ^a,b  

^a Marquette University   (United States)

^b UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FLUORENE DERIVATIVE; POLYFLUORENE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; ELECTRON; GEOMETRY; MOLECULAR INTERACTION; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

FLUORENES; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; POLYMERS;

EID: 0038298140     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja035518s     Document Type: Article

References (19)

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10. Full details of the syntheses of F1-F4 will be published separately.
11. X-ray crystallography data for F2 and F3 have been deposited with the Cambridge Crystallographic Data Center as supplementary publication nos. CCDC207410 and CCDC207411, respectively. Also see Supporting Information.
12. Note that the lowering of redox potentials as a result of cofacial juxtaposition in arene moieties has ample precedents, for example, see: Rathore, R.; Kochi, J. K. Can. J. Chem. 1999, 121, 913-921 and references therein.
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15. Full analysis of the photoelectron spectra of F1-F4, including molecular orbital calculations, will be presented separately: Rathore, R.; Gruhn, N. E.; Abdelwahed, S. H.
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17. Also see: (a) Klaemer, G.; Miller, R. D. Macromolecules 1998, 31, 2007-2009.
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19. Preliminary spectral studies show strong through-space interactions in F2-F4 cation radicals as evidenced by the appearance of new broad bands in the near-IR region. Full details will be disclosed in a separate manuscript.