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19
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34948827971
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19). Detailed structural and spectroscopic characterization of the complexes will be reported in a full article.
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19). Detailed structural and spectroscopic characterization of the complexes will be reported in a full article.
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20
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34948869763
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1)(tmeda)] at a higher temperature (80°C). Only the monoamido complexes 1 and 2 were isolated under the latter reaction conditions.
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1)(tmeda)] at a higher temperature (80°C). Only the monoamido complexes 1 and 2 were isolated under the latter reaction conditions.
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21
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34948891489
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Magnetic moments of the complexes were measured by the Evans method in toluene at 298 K. Evans, D. F. J. Chem. Soc. 1959, 2003-2005.
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Magnetic moments of the complexes were measured by the Evans method in toluene at 298 K. Evans, D. F. J. Chem. Soc. 1959, 2003-2005.
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22
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0032517288
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Rheingold, A.L.6
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0037021483
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Lachicotte, R.J.5
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27
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34948812964
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Data collection for 3: C18H37FeN 3Si, Mr, 379.45, crystal dimensions 0.4 x 0.3 x 0.2 mm3, triclinic (P1, a, 8.036(14) Å, b, 10.296-(16) Å, c, 14.97(2) Å, α, 75.74(3)°, β, 76.18(3)°, γ, 70.79-(3)°, V, 1114(3) Å3, Z, 2, ρcalcd, 1.131 g/cm3, μ, 0.734 mm-1, Mo Kα radiation λ, 0.710 73 Å, T, 273(2) K, reflections measured, 6817, independent reflections, 4788 (Rint= 0.0506, observed reflections, 2522 [I > 2σ(I, final R indices R1, 0.0615 and wR2, 0.1514. Data collection for 4: C18H37CoN 3Si, Mr, 382.53, crystal dimensions 0.3 x 0.2 x 0.18 mm3, triclinic (P1, a, 8.0103(5) Å, b, 10.24026
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int, = 0.0663), observed reflections = 1663 [I > 2σ(I)], final R indices R1 = 0.0528 and wR2 = 0.1115.
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28
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0345403746
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Abel, E. W, Stone, F. G. A, Wilkinson, G, Eds, Pergamon: New York, Chapter 2
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(a) Kerber, R. C. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: New York. 1995; Vol. 7, Chapter 2.
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Kerber, R.C.1
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33744570531
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Abel, E. W, Stone, F. G. A, Wilkinson, G, Eds, Pergamon: New York, Chapter 1
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(b) Sweany, R. L. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: New York. 1995; Vol. 8, Chapter 1.
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Sweany, R.L.1
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30
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34948821118
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2, respectively, may lead to a variation in their coordination properties.
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2, respectively, may lead to a variation in their coordination properties.
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