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Volumn 46, Issue 19, 2007, Pages 7695-7697

Unusual iron(II) and cobalt(II) complexes derived from monodentate arylamido ligands

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EID: 34948890498     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic700850e     Document Type: Article
Times cited : (30)

References (30)
  • 2
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    • and references cited therein
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    • (1988) Chem. Rev , vol.88 , pp. 1163-1188
    • Bryndza, H.E.1    Tam, W.2
  • 17
    • 0002266675 scopus 로고    scopus 로고
    • Herrmann, W. A, Ed, Springer: Berlin
    • (c) Anwander, R. In Topics in Current Chemistry; Herrmann, W. A., Ed.; Springer: Berlin, 1996; Vol. 179; pp 33-112.
    • (1996) Topics in Current Chemistry , vol.179 , pp. 33-112
    • Anwander, R.1
  • 19
    • 34948827971 scopus 로고    scopus 로고
    • 19). Detailed structural and spectroscopic characterization of the complexes will be reported in a full article.
    • 19). Detailed structural and spectroscopic characterization of the complexes will be reported in a full article.
  • 20
    • 34948869763 scopus 로고    scopus 로고
    • 1)(tmeda)] at a higher temperature (80°C). Only the monoamido complexes 1 and 2 were isolated under the latter reaction conditions.
    • 1)(tmeda)] at a higher temperature (80°C). Only the monoamido complexes 1 and 2 were isolated under the latter reaction conditions.
  • 21
    • 34948891489 scopus 로고    scopus 로고
    • Magnetic moments of the complexes were measured by the Evans method in toluene at 298 K. Evans, D. F. J. Chem. Soc. 1959, 2003-2005.
    • Magnetic moments of the complexes were measured by the Evans method in toluene at 298 K. Evans, D. F. J. Chem. Soc. 1959, 2003-2005.
  • 27
    • 34948812964 scopus 로고    scopus 로고
    • Data collection for 3: C18H37FeN 3Si, Mr, 379.45, crystal dimensions 0.4 x 0.3 x 0.2 mm3, triclinic (P1, a, 8.036(14) Å, b, 10.296-(16) Å, c, 14.97(2) Å, α, 75.74(3)°, β, 76.18(3)°, γ, 70.79-(3)°, V, 1114(3) Å3, Z, 2, ρcalcd, 1.131 g/cm3, μ, 0.734 mm-1, Mo Kα radiation λ, 0.710 73 Å, T, 273(2) K, reflections measured, 6817, independent reflections, 4788 (Rint= 0.0506, observed reflections, 2522 [I > 2σ(I, final R indices R1, 0.0615 and wR2, 0.1514. Data collection for 4: C18H37CoN 3Si, Mr, 382.53, crystal dimensions 0.3 x 0.2 x 0.18 mm3, triclinic (P1, a, 8.0103(5) Å, b, 10.24026
    • int, = 0.0663), observed reflections = 1663 [I > 2σ(I)], final R indices R1 = 0.0528 and wR2 = 0.1115.
  • 28
    • 0345403746 scopus 로고
    • Abel, E. W, Stone, F. G. A, Wilkinson, G, Eds, Pergamon: New York, Chapter 2
    • (a) Kerber, R. C. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: New York. 1995; Vol. 7, Chapter 2.
    • (1995) Comprehensive Organometallic Chemistry II , vol.7
    • Kerber, R.C.1
  • 29
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    • Abel, E. W, Stone, F. G. A, Wilkinson, G, Eds, Pergamon: New York, Chapter 1
    • (b) Sweany, R. L. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: New York. 1995; Vol. 8, Chapter 1.
    • (1995) Comprehensive Organometallic Chemistry II , vol.8
    • Sweany, R.L.1
  • 30
    • 34948821118 scopus 로고    scopus 로고
    • 2, respectively, may lead to a variation in their coordination properties.
    • 2, respectively, may lead to a variation in their coordination properties.


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