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Volumn 36, Issue 9, 2007, Pages 1174-1175

Different magnetic properties for diastereomers of alkoxide-bridged (β-diketonato)ruthenium(III) binuclear complexes

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Indexed keywords


EID: 34948849663     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2007.1174     Document Type: Article
Times cited : (8)

References (29)
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    • 2] and a binucleating bridging ligand in ethanol.
    • 2] and a binucleating bridging ligand in ethanol.
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    • J. Yoshida, H. Sato, A. Yamagishi, N. Hoshino, J. Am. Chem. Soc. 2005, 127, 8453. To separate the racemic mixture 1r, the ΛΛ-enantiomers were first eluted with methanol, while all the ΔΔ-enantiomers were tightly retained in the column. The ΔΔ-enantiomers were finally eluted with chloroform.
    • J. Yoshida, H. Sato, A. Yamagishi, N. Hoshino, J. Am. Chem. Soc. 2005, 127, 8453. To separate the racemic mixture 1r, the ΛΛ-enantiomers were first eluted with methanol, while all the ΔΔ-enantiomers were tightly retained in the column. The ΔΔ-enantiomers were finally eluted with chloroform.
  • 25
    • 34948856711 scopus 로고    scopus 로고
    • Crystal data for [1r]·C2H4Cl2; fw 759.60; Monoclinic, C2/c, 15, Z, 8, a, 28.515(3, b, 10.842(1, c, 20.670(2)Å, β, 108.45(1)°, V, 6062.0(9)Å3, Dcalcd, 1.664gcm -3, μ(MoKα, 12.22 cm-1, Final Ti, 0.083 (R w, 0.211) for 32299 observed reflections (unique: 6819, For [1m, fw 660.64; Monoclinic, P21/n, 14, Z, 2, a, 8.721(5, b, 8.116(5, c, 18.386(11)Å, β, 108.95(1)°, V, 1268.3(13)Å3, Dcalcd, 1.730gcm-3, μ(MoKα, 12.43cm-1, Final R, 0.029 (Rw, 0.089) for 9802 observed reflections (unique: 2872, Crystallographic data have been deposited to the CCDC (Supplymentary No. CCDC-642749 (1r) and CCDC-642748 1m
    • w = 0.089) for 9802 observed reflections (unique: 2872). Crystallographic data have been deposited to the CCDC (Supplymentary No. CCDC-642749 (1r) and CCDC-642748 (1m)).
  • 26
    • 0035796154 scopus 로고    scopus 로고
    • H. Miyasaka, H.-C. Chang, K. Machizuki, S. Kitagawa, Inorg. Chem. 2001, 40, 3544; [Ru2(Cl4Cat) 4(μ-OMe)2Na2(MeOH)6] 2, 2.606(1 )Å, Ru2(Cl4Cat) 4(μ-OEt)2Na2(MeOH)6] 2, 2.628(2)Å
    • 2-: 2.628(2)Å.
  • 27
    • 0000173614 scopus 로고    scopus 로고
    • 1HNMR at room temperature. D. R. Eaton, J. Am. Chem. Soc. 1965, 87, 3097.
    • 1HNMR at room temperature. D. R. Eaton, J. Am. Chem. Soc. 1965, 87, 3097.
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    • -1 for methanol). W. Haberditzl, Angew. Chem. 1966, 78, 277.
    • -1 for methanol). W. Haberditzl, Angew. Chem. 1966, 78, 277.
  • 29
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    • Supporting Information is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem-lett/index.html.
    • Supporting Information is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem-lett/index.html.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.