Meso and racemic isomers of a new S-bridged diruthenium(II) complex with pendant aminoalkyl groups

Chemistry Letters

Volumn 34, Issue 9, 2005, Pages 1252-1253

  Matsuura, Noriyuki ^a   Igashira Kamiyama, Asako ^a   Kawamoto, Tatsuya ^a   Konno, Takumi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 28444482119     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2005.1252     Document Type: Article

References (22)

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13. 4+ was not recognized when Haet was used instead of Haet·HCl.
14. sh, 34.6 (4.86), 41.3 (4.68).
15. See Supporting Information.
16. + hydrogen atoms of Haet ligands were found from difference maps and refined isotropically.
17. 2 core so far reported.
18. -1)]: 18.8 (-5.09), 22.4 (+12.8), 26.9 (-13.1), 30.4 (+20.5), 32.5 (-73.8), 33.5 (+112), 35.2 (-64.6), 39.5 (+28.3), 42.0 (-14.5), 43.6 (-15.3).
19. R. J. Crutchley, Adv. Inorg. Chem., 41, 273 (1994).
20. II mixed-valence species.
21. 4+ displayed essentially the same bpy-centered redox couples in the region of -1.6V-2.4V. See Supporting Information.
22. 3a,3b indicating that the CV difference is based on the difference in the meso-racemic isomerism, rather than the difference in the bridging ligands.