Advances in asymmetric synthesis

Pharmaceutical Technology

Volumn 31, Issue 9, 2007, Pages 58-65

  Van Arnum, Patricia ^a  

^a Bldg F ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIOCATALYSTS; ENANTIOSELECTIVITY; HYDROFORMYLATION; HYDROGENATION;

ASYMMETRIC HYDROGENATION; ASYMMETRIC SYNTHESIS;

CATALYST ACTIVITY;

ASYMMETRIC SYNTHESIS; CATALYSIS; ENANTIOSELECTIVITY; HYDROFORMYLATION; HYDROGENATION; REVIEW;

EID: 34748881846     PISSN: 15432521     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Review

References (19)

1. M. Beller and K. Kumar, "Hydroformylation: Applications in the Synthesis of Pharmaceuticals and Fine Chemicals," in Transition Metals for Organic Synthesis, M. Beller, C. Bolm, Eds. (Wiley-VCH, Weinheim, Germany 2004), Vol. 1, pp. 29-55.
2. B. Breit, "Synthetic Aspects of Stereoselective Hydroformylation, " Acc. Chem. Res. 36 (4), 264-275 (2003).
3. I. Ojima and K. Hirai, "Asymmetric Hydrosilylation and Hydrocarbonylation," in Asymmetric Synthesis, J.D. Morrison, Ed. (Academic Press, New York, 1985), Vol. 5, pp. 126-145.
4. K. Nozaki, "Hydrocarbonylation of Carbon-Carbon Double Bonds," in Comprehensive Asymmetric Catalysis, E.N. Jacobsen, A. Pfaltz, and H. Yamamoto, Eds. (Springer, Berlin, 1999), Vol. 1, pp. 382-409.
5. K. Nozaki, H. Takaya, and T. Hiyama, "Enantioselective Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of Chiral Phosphine-Phosphite Ligands, Topics in Catalysis 4 (3-4), 175-185 (1997).
6. C.R. Landis et al., "Highly Active, Regioselective, and Enantioselective Hydroformylation with Rh Catalysts Ligated by Bis-3,4-diazaphospholanes," J. Am. Chem. Soc. 127 (14), 5040-5042 (2005).
7. C.J. Cobley et al., "Parallel Ligand Screening on Olefin Mixtures in Asymmetric Hydroformylation Reactions," Org. Lett. 6 (19), 3277-3280 (2004).
8. C.J. Cobley et al., "Synthesis and Application of a New Bisphosphite Ligand Collection for Asymmetric Hydroformylation of Allyl Cyanide," J. Org. Chem. 69 (12), 4031-4040 (2004).
9. A.T. Axtell et al., "Highly Regio- and Enantioselective Asymmetric Hydroformylation of Olefins Mediated by 2,5-Disubstituted Phospholane Ligands," Ange. Chem. Int. Ed. 44 (36), 5834-5838 (2005).
10. P.J. Thomas et al., "Asymmetric Hydroformylation of Vinyl Acetate: Application in the Synthesis of Optically Active Isoxazolines and Imidazoles," Org. Lett. 9 (18), 2665-2668 (2007).
11. C.R. Landis et al., "Rapid Access to Diverse Arrays of Chiral 3,4-Diazaphospholanes," Ange. Chem. Int. Ed. 40 (18), 3432-3434 (2001).
12. T.P. Clark, et al.,"Resolved Chiral 3,4-Diazaphospholanes and their Application to Catalytic Asymmetric Allylic Alkylation," J. Am. Chem. Soc. 125 (39), 11792-11793 (2003).
13. C.R. Landis and T.P. Clark, "Solid-Phase Synthesis of Chiral 3,4-Diazaphospholanes and their Application to Catalytic Asymmetric Allylic Alkylation," Proc. Nat. Acad. Sci. U.S.A. 101 (15), 5428-5428 (2004).
14. C.R. Landis, et al., "Synthesis, Characterization, and Transition-Metal Complexes of 3,4-Diazaphospholane Organometallics 25 (21) 1377-1391 (2006).
15. A.T. Axtell, J.Klosin, and K.A. Abboud, "Evaluation of Asymmetric Hydrogenation Ligands in Asymmetric Hydroformylation Reactions: Highly Enantioselective Ligands Based on Bis-phosphacycles," Organometallics 25 (21), 5003-5009 (2006).
16. Y. Yan and X. Zhang, "A Hybrid Phosphorus Ligand for Highly Enantioselective Asymmetric Hydroformylation," J. Am. Chem. Soc 128 (22), 7198-7202 (2006).
17. S. Singh et al., "Development of a Large-Scale Stereoselective Process for (1R,4S)-4-(3,4-Dichlorophenyl)-1,2,3,4- tetrahydronaphthalen-1-amine Hydrochloride," Org. Process Res.Dev. 11 (4) 726-730 (2007).
18. K. Vedha-Peers et al., "Creation of a Broad-Range and Highly Stereoselective D-Amino Acid Dehydrogenase for the One-Step Synthesis of D-Amino Acids," J. Am. Chem. Soc 128 (33), 10923-10929 (2006).
19. P.Van Arnum, "Chiral Separations: Developments in SMB Liquid Chromatography and SFC," Pharm. Technol. 30 (4), 60 (2006).