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34748830158
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A mixture of (1S,2S)-1 (10 mg, 0.088 mmol) and dicarboxylic acid derivatives (0.088 mmol) was dissolved in n-alkyl alcohol solution (2-3 mL) and left to stand at room temperature. After a few days, several colorless crystals were produced.
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A mixture of (1S,2S)-1 (10 mg, 0.088 mmol) and dicarboxylic acid derivatives (0.088 mmol) was dissolved in n-alkyl alcohol solution (2-3 mL) and left to stand at room temperature. After a few days, several colorless crystals were produced.
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15
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34748852941
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This weight is the total crop of obtained crystals in one batch
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This weight is the total crop of obtained crystals in one batch.
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16
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34748896407
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Crystal data for I: C6H14N 2·C22H14O4·H 2O·CH4O, M, 506.58 orthorhombic, space group P212121, a, 8.9189(5) Å, b, 10.2904(5) Å, c, 27.9198(14) Å, U, 2562.5(2) Å3, Z, 4, Dc, 1.313 g cm-3, μ(Mo Kα, 0.092 mm-1, 22726 reflections measured, 5949 unique, final R(F2, 0.0399 using 5432 reflections with I > 2.0σ(I, R(all data, 0.0452, T, 120(2) K
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2) = 0.0399 using 5432 reflections with I > 2.0σ(I), R(all data) =0.0452, T = 120(2) K.
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17
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34748833329
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Crystal data for II: C6H14N 2·C22H14O4·H 2O·C2H6O, M, 520.61 orthorhombic, space group P212121, a, 8.8746(5) Å, b= 10.4445(6) Å, c, 28.2830(15) Å, U, 2621.6(3) Å3, Z, 4, Dc, 1.319 g cm-3, μ(Mo Kα, 0.092 mm-1, 16376 reflections measured, 6007 unique, final R(F2, 0.0443 using 5552 reflections with I > 2.0σ(I, R(all data, 0.0485, T, 120(2) K
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2) = 0.0443 using 5552 reflections with I > 2.0σ(I), R(all data) = 0.0485, T = 120(2) K.
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18
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34748833330
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Crystal data for III: C6H14N 2·2C22H14O4·3C 3H8O, M, 979.14 orthorhombic, space group P212121, a, 9.1854(6, b, 15.1465(11, c, 36.763(3) Å, U, 5114.7(6) Å3, Z, 4, Dc= 1.272 g cm -3, μ(Mo Kα, 0.087 mm-1, 31926 reflections measured, 11675 unique, final R(F2, 0.0497 using 10434 reflections with I > 2.0σ(I, R(all data, 0.0571, T, 120(2) K
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2) = 0.0497 using 10434 reflections with I > 2.0σ(I), R(all data) =0.0571, T = 120(2) K.
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