Aerobic oxidation of aqueous ethanol using heterogeneous gold catalysts: Efficient routes to acetic acid and ethyl acetate

Journal of Catalysis

Volumn 251, Issue 2, 2007, Pages 332-337

  Jørgensen, Betina ^a   Egholm Christiansen, Sofie ^a   Dahl Thomsen, Marie Louise ^a   Christensen, Claus Hviid ^a  

^a TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

Author keywords

Acetic acid; Aerobic oxidation; Bioethanol; Ethyl acetate; Gold; Heterogeneous catalysis

Indexed keywords

ACETIC ACID; CATALYSIS; DEHYDROGENATION; GOLD; OXIDATION; REACTION KINETICS;

AEROBIC OXIDATION; AQUEOUS ETHANOL; BIOETHANOL; ETHYL ACETATE;

ETHANOL;

EID: 34748861450     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2007.08.004     Document Type: Article

References (41)

1. Hutchings G.J., and Haruta M. Appl. Catal. A 291 (2005) 2
2. Haruta M., and Daté M. Appl. Catal. A 222 (2001) 427
3. Thompson D. Gold Bull. 31 (1998) 111
4. Thompson D. Gold Bull. 32 (1999) 12
5. Haruta M., Tsubota S., Kobayashi T., Kageyama H., Genet M.J., and Delman B. J. Catal. 144 (1993) 175
6. Nkosi B., Coville N.J., Hutchings G.J., Adams M.D., Friedl J., and Wagner F.E. J. Catal. 128 (1991) 366
7. Janssens T.V.W., Clausen B.S., Larsen B.H., Falsig H., Christensen C.H., Bligaard T., and Nørskov J.K. Top. Catal. 44 (2007) 15
8. Haruta M. Gold Bull. 37 (2004) 27
9. Tsunoyama H., Sakurai H., Negishi Y., and Tsukuda T. J. Am. Chem. Soc. 127 (2005) 9374
10. Tsunoyama H., Sakurai H., and Tsukuda T. Chem. Phys. Lett. 429 (2006) 528
11. Biffis A., and Minati L. J. Catal. 236 (2005) 405
12. Abad A., Almela D., Corma A., and García H. Tetrahedron 62 (2006) 6666
13. Besson M., and Gallezot P. Catal. Today 57 (2000) 127
14. Hayashi T., Inagaki T., Itayama N., and Baba H. Catal. Today 117 (2006) 210
15. Biella S., Prati L., and Rossi M. Inorg. Chim. Acta 349 (2003) 253
16. Enache D.I., Knight D.W., and Hutchings G.J. Catal. Lett. 103 (2005) 43
17. Biella S., Prati L., and Rossi M. J. Catal. 206 (2002) 242
18. Biella S., Prati L., and Rossi M. J. Mol. Catal. A 197 (2003) 207
19. Biella S., and Rossi M. Chem. Commun. (2003) 378
20. Comotti M., Pina C.D., Matarrese R., Rossi M., and Siani A. Appl. Catal. A 291 (2005) 204
21. Prati L., and Porta F. Appl. Catal. A 291 (2005) 199
22. Bianchi C., Porta F., Prati L., and Rossi M. Top. Catal. 13 (2000) 231
23. Porta F., Prati L., Rossi M., and Scari G. J. Catal. 211 (2002) 464
24. Prati L., and Rossi M. J. Catal. 176 (1998) 552
25. Prati L., and Martra G. Gold Bull. 32 (1999) 96
26. Enache D.I., Edwards J.K., Landon P., Solsona-Espriu B., Carley A.F., Herzing A.A., Watanabe M., Kiely C.J., W Knight D., and Hutchings G.J. Science 311 (2006) 362
27. Carrettin S., McMorn P., Johnston P., Griffin K., Kiely C.J., and Hutchings G.J. Phys. Chem. Chem. Phys. 5 (2003) 1329
28. Carrettin S., McMorn P., Johnston P., Griffin K., and Hutchings G.J. Chem. Commun. (2002) 696
29. Dimitratos N., Villa A., Bianchi C.L., Prati L., and Makkee M. Appl. Catal. A 311 (2006) 185
30. Abad A., Concepción P., Corma A., and Garcia H. Angew. Chem. Int. Ed. 44 (2005) 4066
31. Abad A., Almela C., Corma A., and García H. Chem. Commun. (2006) 3178
32. Sheng P.-Y., Bowmaker G.A., and Idriss H. Appl. Catal. A 261 (2004) 171
33. Christensen C.H., Jørgensen B., Rass-Hansen J., Egeblad K., Madsen R., Klitgaard S.K., Hansen S.M., Hansen M.R., Andersen H.C., and Riisager A. Angew. Chem. Int. Ed. 45 (2006) 4648
34. Rass-Hansen J., Falsig H., Jørgensen B., and Christensen C.H. J. Chem. Technol. Biotechnol. 82 (2007) 329
35. Soetaert W., and Vandamme E. In: Lens P., Westermann P., Haberbauer M., and Moreno A. (Eds). Biofuels for Fuel Cells (2005), IWA Publishing, London 37
36. http://www.gold.org/discover/sci_indu/gold_catalysts/refcat.html
37. Yoneda N., Kusano S., Yasui M., Pujado P., and Wilcher S. Appl. Catal. A 221 (2001) 253
38. Mirescu A., Berndt H., Martin A., and Prüße U. Appl. Catal. A 317 (2007) 204
39. E. Iglesia, personal communication, 2007
40. R. Sakamuri, Esters, Organic in Kirk-Othmer Encyclopedia of Chemical Technology, online version on Wiley InterScience
41. Nielsen I.S., Taarning E., Egeblad K., Madsen R., and Christensen C.H. Catal. Lett. 116 (2007) 35