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Volumn 129, Issue 38, 2007, Pages 11686-11687

Tandem reductive perfluoroalkylation of esters with perfluoroalkyl titanate-type reagents

Author keywords

[No Author keywords available]

Indexed keywords

ESTER DERIVATIVE; PERFLUORO COMPOUND; TITANIUM DERIVATIVE;

EID: 34748831868     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja074642z     Document Type: Article
Times cited : (27)

References (39)
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    • For Ti- and Li-enolate species, B3LYP/631LAN (LANL2DZ for Ti 6-31G* for others) was adopted. For Ti-ate-enolate, B3LYP/631+LAN (LANL2DZ for Ti, 6-31+G* for others) was adopted. (a) Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270-283.
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    • Donation of the lone electron pair of the oxygen to the empty d-orbital of Ti causes the linear multiple bonding see ref 5
    • Donation of the lone electron pair of the oxygen to the empty d-orbital of Ti causes the linear multiple bonding (see ref 5).
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    • 4 did not give any adduct of benzoate at room temperature for 3 h.
    • 4 did not give any adduct of benzoate at room temperature for 3 h.
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    • This reaction mechanism can also be supported by the formation of the perfluoroalkyl adduct of acetone which is derived from isopropoxide
    • This reaction mechanism can also be supported by the formation of the perfluoroalkyl adduct of acetone which is derived from isopropoxide.
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    • When aluminium tri(iso-propoxide) was used for the reaction of perfluoroalkyl metal-ate reagent with aldehyde, no perfluoroalkylation took place
    • When aluminium tri(iso-propoxide) was used for the reaction of perfluoroalkyl metal-ate reagent with aldehyde, no perfluoroalkylation took place.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.