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The absorption cross section of PTCDA was calculated from the molar extinctions coefficient e of PTCDA in solution [M. Hoffmann, K. Schmidt, T Fritz, T Hasche, V. M. Agranovich, and K. Leo, The lowest energy frenkel and charge-transfer excitons in quasi-one-dimensional structures: application to MePTCDI and PTCDA crystals, Chem. Phys. 258, 73-96 2000, according to σ, 2.303/NA × ε. We note that the averaged σ on the fiber may differ from the value obtained in solution by a factor of the order of one due to geometric reasons and differences in the refractive indices
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The offset accounts for the fact that spectrum B still contains a monolayer component and thus an admixture of spectrum A
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The offset accounts for the fact that spectrum B still contains a monolayer component and thus an admixture of spectrum A.
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