Fenton reaction in the presence of humates. Treatment of highly contaminated wastewater at neutral pH

Environmental Technology

Volumn 28, Issue 9, 2007, Pages 1007-1013

  Kochany, J ^a   Lipczynska Kochany, E ^b  

^a Conestoga Rovers and Associates ^*  (Canada)

^b Environmental Consultant   (Canada)

Author keywords

Chemical oxidation; Fenton reagent; Humates; Wastewater treatment

Indexed keywords

CONTAMINATION; IRON COMPOUNDS; REAGENTS; SALTS; WASTEWATER TREATMENT; WATER POLLUTION; WATER TREATMENT;

CHEMICAL OXIDATION; CONTAMINANTS OF CONCERNS; CONTAMINATED WASTEWATER; CONTAMINATED WATER; FENTON REACTIONS; FENTON REAGENTS; HUMATES; HUMIC SUBSTANCES;

OXIDATION;

AMMONIA; ARSENIC; CYANIDE; FERROUS ION; HYDROGEN PEROXIDE; PHENOL; THIOCYANATE;

CONTAMINATION; DEGRADATION; OXIDATION; PH EFFECTS; WASTEWATER TREATMENT;

CHEMICAL REACTION; HUMIC SUBSTANCE; OXIDATION; PH; REMOVAL EXPERIMENT; WASTE TREATMENT; WASTEWATER;

ARTICLE; BIODEGRADATION; CHEMICAL OXYGEN DEMAND; FENTON REACTION; HUMIC SUBSTANCE; OXIDATION REDUCTION REACTION; PH; WASTE COMPONENT REMOVAL; WASTE WATER MANAGEMENT; WATER ANALYSIS; WATER CONTAMINATION; WATER QUALITY;

EID: 34648833652     PISSN: 09593330     EISSN: None     Source Type: Journal    
DOI: 10.1080/09593332808618859     Document Type: Article

References (33)

1. Fenton, H.J. Oxidation of tartaric acid in presence of iron. J. Chem. Soc. 65, 899-910 (1894).
2. Lipczynska-Kochany, E. Degradation of aquous nitrophenols and nitrobenzene by means of the Fenton reaction, Chemosphere, 22, 529-536 (1991).
3. Lipczynska-Kochany, E., Sprah, G. and Harms, S. Influence of some groundwater and surface waters constituents on the degradation of 4-chlorophenol by the Fenton reaction. Chemosphere, 30, 9-20 (1995).
4. 2 propagations (modified Fenton's reagent). Water Res., 40, 2477-2484 (2006).
5. Pignatello, J. J., Oliveros, E. and MacKay, A., Advanced oxidation processes for organic contaminant destruction based on the Fenton reaction and related chemistry. Crit. Rev. Environ. Sci. Technol., 36, 1-84 (2006).
6. Kochany, J. and Lugowski, A., Application of Fenton's reagent and activated carbon for removal of nitrification inhibitors, Environ. Technol., 19, 425-429 (1998).
7. Buyuksonmez, F., Hess, T. F., Crawford, R. L., Paszczynski, A. and Watts, R. J., Optimization of simultaneous chemical and biological mineralization of perchloroethylene, Appl. Environ. Microbiol., 65, 2784-2788 (1999).
8. Aronstein, B. N. and Rice, L.E., Biological and integrated chemical-biological treatment of PCB congeners in soil/sediment containing system, J. Chem. Technol. Biotechnol., 65, 321-328 (1995).
9. Lipczynska-Kochany, E. Novel method for a photocatalytic degradation of 4-nitrophenol on homogeneous aqueous solution. Environ. Technol. 12, 87-92 (1991)
10. 3+-catalyzed degradation of chlorophenoxy herbiddes by hydrogen peroxide, Environ, Sci., Technol. 26, 944-951, (1992).
11. Sun, Y. and Pignatello, J. J. Chemical treatment of pesticide wastes, Evaluation of Fe (III) chelates for catalytic hydrogen peroxide oxidation of 2,4-D at neutral pH, J. Agric. Food Chem. 40, 322-327 (1992).
12. Walling, C., Fenton's reagent revisited, Acc. Chem. Res., 8, 125-131 (1975).
13. Goldstein, S., Meyerstein, D. and Czapski, G. The Fenton reagent. Free Radic. Biolo. Med., 15, 435-445 (1993).
14. Buxton, G.V., Greenstock. C.L., Helman, W.P. and Ross, A.B. Critical review of rate constants for reaction of hydrated electrons. Hydrogen atoms and hydroxyl radicals (OH/O), J. Phys. Chem. 17, 513-886 (1988).
15. Paul, A., Stosser, R., Zehl, A., Zwirnmann, E. and Steinberg, C. E., Nature and abundance of organic radicaLs in natural organic matter: Effect of pH and irradiation, Environ. Sci. Technol., 40, 5897-5903 (2006).
16. Davies, G. and Ghabbour, E. A., Humic Substances: Structures, Properties and Uses. Royal Society of Chemistry, Cambridge, UK, 147-164 (1998).
17. Bogan, B.W. and Trbovic, V. Effect of sequestration on PHA degradability with Fenton's reagent: roles of total organic carbon, humin, and soil porosity, J. Hazard. Mater. 100, 285-300 (2003).
18. Lindsey, M. E. and Tarr, M. A., Inhibition of hydroxy radical reaction with aromatics by dissolved natural organic matter, Environ. Sci. Technol., 34, 444-449 (2000).
19. Li, Z.M., Shea, P.J. and Comfort, S.D. Nitrotoluene destruction by UV-catalyzed Fenton oxidation. Chemosphere, 36, 1849-1865 (1998).
20. Watts, R., Udeli M.D., Rauch P.A. and Leung S.W. Treatment of contaminated soils using catalyzed hydrogen peroxide. Haz. Waste Mater, 7 (4) 335-345 (1990).
21. Huling, S.G., Arnold, R.G., Sierka, R.A. and Miller, M. R. Influence of peat on Fenton oxidation. Water Res. 35. 1687-1694 (2001).
22. Voelker, B. M. and Sulzberger, B., Effect of fulvic acids on Fe(II) oxidation by hydrogen peroxide, Environ. Sci. Technol., 30, 1106-1114 (1996).
23. Vione, D, Merlo, F., Maurino, V. and Minero, C. Effect of humic acids on the Fenton degradation of phenol. Environ. Chemistry Letts, 2, 129-133 (2004).
24. Georgi, A, Schierz, A. and Kopinke, F. D. Activation of hydrogen peroxide complexes of iron (III) with humic acid for chemical degradation of organic compounds in water. Book of Abstracts. Environmental Applications of Advanced Oxidation Processes (EAAOP) Conference, The Centre for Research and Technology Hellas, CE.R.T.H., Chania, Greece, September 7-9, (2006).
25. Kochany, J. Unpublished results.
26. Lipczynska-Kochany, E. Degradation of aromatic pollutants by means of Advanced oxidation processes in homogeneous phase: hydrogen peroxide versus the Fenton Reaction. In: Chemical Oxidation. Technology for the Nineties, vol 3. Eckenfelder, W.W., Bowers, A.R., Roth, J.A. (Eds.) Technomic Publishing Co., Lancaster, PA, USA 12-27 (1993).
27. Zaao, J.A., Casas, J.A. Mohedano, A.F., Gilarranz, M.A. and Rodrigues, J.J. Chemical pathway and kinetics of phenol oxidation by Fenton's Reagent. Environ. Sci. Technol., 39, 9295-9302 (2005).
28. Eilbeck, W.J. and Mattock, G. Chemical Processes in Waste Water Treatment. Ellis Horwood, Chichester, UK, pp.146-147 (1987).
29. U.S. Environmental Protection Agency. Arsenic Treatment Technologies for Soil, Waste and Water; EPA-542-R-02-004, Washington D.C. 2002.
30. Davies. G., Fataftah, A and Cherkasskiy, T. Tight metal binding by humic acids and its role in biomineralization, J. Chem. Soc. Dalton Trans. 21, 4047-4060 (1997).
31. Li, Z.M., Shea, P.J. and Comfort, S.D., Fenton oxidation of 2,4,6-trinitrotoluene in contaminated soil oxidation. Environ Eng. Sci. 14 (1) 55-66 (1997).
32. Chen, R. and Pignatello, J.J. Role of quinone intermediates as electron shuttles in Fenton and photoassisted Fenton oxidation of aromatic compounds. Environ. Sci. Technol., 31, 2399-2406 (1997).
33. Hoigne, J., Faust, B.C., Haag, W.R., Scully, F.E. and Zepp, R.G. Aquatic humic substances as sources of sinks of photochemistry produced transient reactions. In: Aquatic Humic Substances: Influence on Fate and Treatment of Pollutants; Suffett, I.H. and MacCarthy, P., (Eds), ACS Advances in Chemistry Series, Washington, D.C., 219, 363-381 (1989).