Chemical pathway and kinetics of phenol oxidation by Fenton's reagent

Environmental Science and Technology

Volumn 39, Issue 23, 2005, Pages 9295-9302

  Zazo, J A ^a   Casas, J A ^a   Mohedano, A F ^a   Gilarranz, M A ^a   Rodriguez J J ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; CARBON; INDUSTRIAL WASTES; ORGANIC ACIDS; OXIDATION; SOLUTIONS; TOXICITY; WASTEWATER;

FENTON'S REAGENT; HYDROQUINONE; PHENOLIC INDUSTRIAL WASTEWATER; TOTAL ORGANIC CARBON (TOC);

PHENOLS;

1,4 BENZOQUINONE; ACETIC ACID; CATECHOL; FENTON REAGENT; FORMIC ACID; FUMARIC ACID; HYDROGEN PEROXIDE; HYDROQUINONE; IRON; MALEIC ACID; MALONIC ACID; MUCONIC ACID; OXALIC ACID; PHENOL; REAGENT; UNCLASSIFIED DRUG;

OXIDATION; PHENOL;

AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; HYDROXYLATION; OXIDATION; PH; STOICHIOMETRY; TEMPERATURE; TEMPERATURE DEPENDENCE; TOTAL ORGANIC CARBON; WASTE WATER; X RAY FLUORESCENCE;

ACIDS; CARBON; HYDROGEN PEROXIDE; IRON; KINETICS; ORGANIC CHEMICALS; PHENOL;

EID: 28444459841     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es050452h     Document Type: Article

References (28)

1. Ding, Z.; Aki, S.; Abraham, M. A. Catalytic supercritical water oxidation: Phenol conversion and product selectivity. Environ. Sci. Technol. 1995, 29 (11), 2748-2753.
2. Bigda, R. J. Consider Fenton's chemistry for wastewater treatment. Chem. Eng. Prog. 1995, 91 (12), 62-66.
3. Esplugas, S.; Giménez, J.; Contreras, S.; Pascual, E.; Rodríguez, M. Comparison of different advanced oxidation processes for phenol degradation. Water Res. 2002, 36 (4), 1034-1042.
4. Neyens, E.; Baeyens, J. A review of classic Fenton's peroxidation as an advanced oxidation technique. J. Hazard. Mater. 2003, 98, 33-50.
5. 2. Chemosphere l999, 39 (15), 2693-2706.
6. Benitez, F. J.; Beltran-Heredia, J.; Acero, J. L; Rubio, F. J. Oxidation of several chlorophenolic derivatives by UV irradiation and hydroxyl radicals. J. Chem. Technol. Biotechnol. 2001, 76 (3), 312-320.
7. Munter, R. Advanced oxidation processes. Current status and prospects. Proc. Est. Acad. Sci., Chem. 2001, 50 (2), 59-80.
8. Potter, F. J.; Roth, J. A. Oxidation of chlorinated phenols using Fenton's reagent. Hazard. Waste Hazard. Mater. 1993, 10 (2), 157-170.
9. Jones, C. W. Applications of Hydrogen Peroxide and Derivatives; Royal Society of Chemistry: Cambridge, U. K., 1999.
10. Goi, A.; Trapido, M. Hydrogen peroxide photolysis, Fenton reagent and photo-Fenton for the degradation of nitrophenols: A comparative study. Chemosphere 2002, 46 (6), 913-922.
11. Kwon, B. G.; Lee, D. S.; Kang, N.; Yoon, J. Characteristics of p-chlorophenol oxidation by Fenton's reagent. Water Res. 1999, 33 (9), 2110-2118.
12. Basu, S.; Wei, I. W. Mechanism and kinetics of oxidation of 2,4,6-trichlorophenol by Fenton's Reagent. Environ. Eng. Sci. 2000, 17 (5), 279-290.
13. Kavitha, V.; Palanivelu, K. Degradation of 2-chlorophenol by Fenton and photo-Fenton proceses. A comparative study. J. Environ. Sci. Health, Part A 2003, 38 (7), 1215-1231.
14. Beitran de Heredia, J.; Dominguez, J. R.; Peres, J. A. Eliminatión de compuestos fenólicos por oxidación avanzada. Estimation de costes. Ing. Quim. 2002, 386, 142-146.
15. Ferez, M.; Torrades, F.; García-Hortal, J.A.; Doménech,X; Peral J. Removal of organic contaminants in paper pulp treatment effluents under Fenton and photo-Fenton conditions. Appl. Catal., B 2002, 36 (1), 63-74.
16. Chen, R.; Pignatello, J. J. Role of quinone intermediates as electron shuttles in Fenton and photoassisted Fenton oxidations of aromatic compounds. Environ. Sci. Technol. 1997, 31 (8), 2399-2406.
17. Beitran de Heredia, J.; Torregrosa, J.; Domínguez, J. R.; Peres, J. A. Kinetic model for phenolic compound oxidation by Fenton's reagent. Chemosphere 2001, 45 (1), 85-90.
18. Kang, N.; Lee, D. S.; Yoon, I. Kinetic modeling of Fenton oxidation of phenol and monochlorophenols. Chemosphere 2002, 47 (9), 915-924.
19. Rivas, F. J.; Beltran, F. J.; Frades, J.; Buxeda, P. Oxidation of p-hydroxybenzoic acid by Fenton's reagent. Water Res. 2001, 35 (2), 387-396.
20. Al-Hayek, N.; Eymery, I. P.; Doré, M. Catalytic oxidation of phenols with hydrogen peroxide. Water Res. 1985, 19 (5), 657-666.
21. Andreozzi, R.; Caprio, V.; Insola, A.; Marotta, R. Advanced oxidation processes (AOP) for water purification and recovery. Catal. Today 1999, 53 (1), 51-59.
22. Santos, A.; Yustos, P.; Quintanilla, A.; Garcia-Ochoa, F.; Casas, J. A.; Rodriguez, J. J. Evolution of toxicity upon wet catalytic oxidation of phenol. Environ. Sci. Technol. 2004, 38, 133-138.
23. Eisenberg, G. M. Colorimetric determination of hydrogen peroxide. Ind. Eng. Chem. Anal. 1943, 15 (5), 327-328.
24. Alnaizy, R.; Akgerman, A. Advanced oxidation of phenolic compounds. Adv. Environ. Res. 2000, 4, 233-244.
25. Eisenhauer, H. R. Oxidation of phenolic wastes. J. Water Pollut. Control Fed. 1964, 36, 1116-1128.
26. Alegría, Y.; Liendo, F.; Nuñez, O. On the Fenton degradation mechanism. The role of oxalic acid. Arkivoc 2003, 10, 538-549.
27. Scott, A. I. Interpretation of the Ultraviolet Spectra of Natural Products; Pergamon: Oxford, U. K., 1964.
28. Scheck, C. K.; Frimmel, F. H. Degradation of phenol and salicylic acid by ultraviolet radiation/hydrogen peroxide/oxygen. Water Res. 1995, 29 (10), 2346-2352.