Dipole moment of the H2SO4-H2O complex

Geophysical Research Letters

Volumn 33, Issue 23, 2006, Pages

  Brauer, Carolyn S ^a   Sedo, Galen ^a   Leopold, Kenneth R ^a  

^a University of Minnesota   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC DIPOLE MOMENTS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; NUCLEATION; STARK EFFECT;

FOURIER TRANSFORM MICROWAVE SPECTROSCOPY; TUNNELING STATE;

GEOPHYSICS;

CHEMICAL COMPOUND; FOURIER TRANSFORM; MICROWAVE IMAGERY;

EID: 34548669392     PISSN: 00948276     EISSN: None     Source Type: Journal    
DOI: 10.1029/2006GL028110     Document Type: Article

References (41)

1. Al Natsheh, A., A. B. Nadykto, K. V. Mikkelsen, F. Yu, and J. Ruuskanen (2004), Sulfuric acid and sulfuric acid hydrates in the gas phase: A DFT investigation, J Phys. Chem. A, 108, 8914-8929. (Errata, J. Phys. Chem. A, 25, 7982-7983, 2006.)
2. Arstila, H., K. Laasonen, and A. Laaksonen (1998), Ab initio study of gas-phase sufuric acid hydrates containing i to 3 water molecules, J. Chem, Phys., 108, 1031-1039.
3. 4 using density functional theory, J. Phys. Chem. A, 102, 6533-6539.
4. 3, J Chem. Phys., 73, 137-141.
5. Brauer, C. S. (2006), Microsolvation of reactive systems in the gas phase via Fourier transform microwave spectroscopy, Ph.D. thesis, Univ. of Minn., Minneapolis.
6. Clarke, A. D. (1992), Atmospheric nuclei in the remote free-troposphere, J. Atmos. Chem., 14, 479-488.
7. Clarke, A. D. (1993), Atmospheric nuclei in the pacific midtroposphere: Their nature, concentration and evaluation, J. Geophys. Res., 98, 20,633-20,647.
8. 2O, J. Chem. Phys., 59, 2254-2259.
9. 2O: Formation of condensed phase molecular sulfuric acid hydrates, J. Am. Chem. Soc., 125, 1999-2003.
10. Couling, S. B., J. Fletcher, A. B. Horn, D. A. Newnham, R. A. McPheat, and R. G. Williams (2003b), First detection of molecular hydrate complexes in sulfuric acid aerosols, Phys. Chem. Chem. Phys., 5, 4108-4113.
11. Doyle, G. J. (I961), Self-nucleation in the sulfuric acid-water system, J. Chem. Phys., 35, 795-799.
12. Drdla, K., A. Tabazadeh, R. P. Turco, M. Z. Jacobson, J. E. Dye, C. Twohy, and D. Baumgardner (1994), Analysis of the physical state of one arctic polar stratospheric cloud based on observations, Geophys. Res. Lett., 21, 2475-2478.
13. Fiacco, D. L., S. H. Hunt, and K. R. Leopold (2002), Microwave investigation of sulfuric acid monohydrate, J. Am. Chem. Soc., 124, 4504-4511.
14. Finlayson-Pitts, B. J., and J. N. Pitts Jr. (2000), Chemistry of the Upper and Lower Atmosphere: Theory, Experiments, and Applications, Elsevier, New York.
15. 2O, J. Chem. Soc. Faraday Trans., 94, 827-835.
16. Hamill, P., R. P. Turco, C. S. Kiang, O. B. Toon, and R. C. Whitten (1982), An analysis of various nucleation mechanisms for sulfate particles in the stratosphere, J. Aerosol Sci., 13, 561-585.
17. Heist, R. H., and H. Reiss (1974), Hydrates in supersaturated binary sulfuric acid-water vapor, J. Chem. Phys., 61, 573-581.
18. Hoppel, W. A., G. M. Frick, J. W. Fitzgerald, and R. E. Larson (1994), Marine boundary layer measurements of new particle formation and the effects nonprecipitating clouds have on aerosol size distribution, J. Geophys. Res., 99, 14,443-14,459.
19. Jaecker-Voirol, A., P. Mirabel, and H. Reiss (1987), Hydrates in supersaturated binary sulfuric acid-water vapor: A reexamination, J. Chem. Phys., 87, 4849-4852.
20. 2O particles in smog, Atmos. Environ., 28, 2399-2406.
21. 2HBr from Stark effects in their rotational spectra, Chem. Phys, Lett., 325, 523-530.
22. Kuczkowski, R. L., R. D. Suenram, and F. J. Lovas (1981), Microwave spectrum, structure, and dipole moment of sulfuric acid, J. Am. Chem. Soc., 103, 2561-2566.
23. Kurtén, T., M. R. Sundberg, H. Vehkarnäki, M. Noppel, J. Blomqvist, and M. Kulmala (2006), Ab initio and density functional theory reinvestigation of gas-phase sulfuric acid monohydrate and ammonium hydrogen sulfate, J. Phys. Chem. A, 110, 7178-7188.
24. Kusaka, I., Z.-G. Wang, and J. H. Seinfeld (1998), Binary nucleation of sulfuric acid-water: Monte Carlo simulation, J. Chem. Phys., 108, 6829-6848.
25. Laakso, L., J. M. Mäkelä, L. Prijola, and M. Kulmala (2002), Model studies on ion-induced nucleation in the atmosphere, J. Geophys. Res., 107(D20), 4427, doi:10.1029/2002JD002140.
26. Mirabel, P., and J. L. Katz (1974), Binary homogeneous nucleation as a mechanism for the formation of aerosols, J. Chem. Phys., 60, 1138-1144.
27. Nadykto, A. B., and F. Yu (2003), Uptake of neutral polar vapor molecules by charged dusters/particles: Enhancement due to dipole-charge interaction, J. Geophys. Res., 108(D23), 4717, doi:10.1029/ 2003JD003664.
28. Nadykto, A. B., and F. Yu (2004), Dipole moment of condensing monomers: A new parameter controlling the ion-induced nucleation, Phys. Rev. Lett., 93, 016101-1-4.
29. Nadykto, A. B., A. Al Natsheh, F. Yu, K. V. Mikkelsen, and J. Ruuskanen (2004), Effect of molecular structure and hydration on the uptake of gas-phase sulfuric acid by charged clusters/ultrafine particles, Aerosol Sci. Technol., 38, 349-353.
30. Noppel, M., H. Vehkamäki, and M. Kulmala (2002), An improved model for hydrate formation in sulfuric acid-water nucleation, J. Chem. Phys., 116, 218-228.
31. 3, J. Am. Chem. Soc., 117, 12,549-12,556.
32. Pirjola, L., A. Laaksonen, P. Aalto, and M. Kulmala (1998), Sulfate aerosol formation in the arctic boundary layer, J. Geophys. Res., 103, 8309-8321.
33. Raes, F., A. Janssens, and R. Van Dingenen (1986), The role of ion-induced aerosol formation in the lower atmosphere, J. Aerosol Sci., 17, 466-470.
34. 2O)n (n = 1 - 5): A molecular orbital study, J. Phys. Chem. A, 103, 3535-3547.
35. Schreiner, J., C. Voigt, A. Kohlmann, F. Arnold, K. Mauersberger, and N. Larsen (1999), Chemical analysis of polar stratospheric cloud particles, Science, 283, 968-970.
36. Schwartz, S. E. (1996), The whitehouse effect - Shortwave radiative forcing of climate by anthropogenic aerosols: An overview, J. Aerosol Sci., 27, 359-382.
37. 4 mixtures: A stochastic approach, J. Chem. Phys., 65, 2827-2840.
38. Vaida, V., H. G. Kjaergaard, P. E. Hintze, and D. J. Donaldson (2003), Photolysis of sulfuric acid vapor by visible solar radiation, Science, 299, 1566-1568.
39. Van Dingenen, R., F. Raes, and N. R. Jensen (1995), Evidence for anthropogenic impact on number concentration and sulfate content of cloud-processed aerosol particles over the north Atlantic, J. Geophys. Res., 100, 21,057-21,067.
40. Yu, F., and R. P. Turco (2000), Ultrafine aerosol formation via ion-mediated nucleation, Geophys. Res. Lett., 27, 883-886.
41. Yu, F., and R. P. Turco (2001), From molecular clusters to nanoparticles: Role of ambient ionization in tropospheric aerosol formation, J. Geophys. Res., 106, 4794-4814.