A new synthesis of β,γ-unsaturated esters from three components, aldehydes, chloromethyl p-tolyl sulfoxide, and tert-butyl acetate, via magnesium carbenoid 1,2-CH and 1,2-CC insertion as the key reaction

Tetrahedron Letters

Volumn 48, Issue 41, 2007, Pages 7295-7300

  Satoh, Tsuyoshi ^a   Yamashita, Hironori ^a   Musashi, Jun ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

, Unsaturated ester; 1,2 CC insertion; 1,2 CH insertion; Magnesium carbenoid; Sulfoxide magnesium exchange reaction

Indexed keywords

1 CHLOROVINYL 4 TOLYL SULFOXIDE DERIVATIVE; ACETIC ACID DERIVATIVE; ALDEHYDE DERIVATIVE; BETA,GAMMA UNSATURATED ESTER DERIVATIVE; CARBENOID; CHLOROMETHYL 4 TOLYL SULFOXIDE; ESTER DERIVATIVE; MAGNESIUM CARBENOID; SULFOXIDE; TERT BUTYL ACETATE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; STEREOSPECIFICITY; SYNTHESIS;

EID: 34548487950     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.08.039     Document Type: Article

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