Fe-oxide fracture fillings as a palæo-redox indicator: Structure, crystal form and Fe isotope composition

Chemical Geology

Volumn 244, Issue 1-2, 2007, Pages 330-343

  Dideriksen, K ^a   Christiansen, B C ^a   Baker, J A ^b   Frandsen, C ^c   Balic Zunic, T ^a   Tullborg, E ^d   Morup S ^c   Stipp, S L S ^a  

^a UNIVERSITY OF COPENHAGEN   (Denmark)

^b VICTORIA UNIVERSITY OF WELLINGTON   (New Zealand)

^c TECHNICAL UNIVERSITY OF DENMARK   (Denmark)

^d Terralogica AB   (Sweden)

Author keywords

Fe isotope; Fe oxide; Fractures; Granite; Oxidation; Radioactive waste repository

Indexed keywords

CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; DEGLACIATION; FRACTURE PROPAGATION; INDUCTIVELY COUPLED PLASMA METHOD; IRON OXIDE; ISOTOPIC COMPOSITION; ISOTOPIC FRACTIONATION; MOSSBAUER SPECTROSCOPY; RADIOACTIVE WASTE; REDOX CONDITIONS; REPOSITORY; UNDERGROUND STORAGE; X-RAY DIFFRACTION;

EID: 34548463795     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2007.06.027     Document Type: Article

References (33)

1. 2+: implications for iron stable isotope geochemistry. Geochim. Cosmochim. Acta 69 (2005) 825-837
2. Bødker F., Hansen M.F., Bender Koch C., Lefmann K., and Mørup S. Magnetic properties of hematite nanoparticles. Phys. Rev., B 61 (2000) 6826-6838
3. Borggaard O.K., Lindgreen H.B., and Mørup S. Oxidation and reduction of structural iron in chlorite at 480 °C. Clays Clay Miner. 30 (1982) 353-364
4. Brandt F., Bosbach D., Krawczyk-Bärsch E., Arnold T., and Bernhard G. Chlorite dissolution in the acid pH-range: a combined microscopic and macroscopic approach. Geochim. Cosmochim. Acta 67 (2003) 1451-1461
5. Brantley S.L., Liermann L.J., Guynn R.L., Anbar A., Icopini G.A., and Barling J. Fe isotopic fractionation during mineral dissolution with and without bacteria. Geochim. Cosmochim. Acta 68 (2004) 3189-3204
6. Broecker W.S. The end of the present interglacial: how and when?. Quat. Sci. Rev. 17 (1998) 689-694
7. Cornell R.M., and Schwertmann U. The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses (1996), Wiley VCH, New York
8. 54Fe double spike. Geochim. Cosmochim. Acta 70 (2006) 118-132
9. Drake H., and Tullborg E.-L. Fracture mineralogy and wall rock alteration. Results from drill core KSH01A+B. Oskarshamn site investigation (2004), Swedish Nuclear Fuel and Waste Managements Co SKB P-04-250
10. Epstein S., Buchsbaum R., Lowenstam H.A., and Urey H.C. Revised carbonate-water isotopic temperature scale. Geol. Soc. Amer. Bull. 64 (1953) 1315-1325
11. García K.E., Morales A.L., Arroyave C.E., Barrero C.A., and Cook D.C. Mössbauer characterization of rust obtained in an accelerated corrosion test. Hyperfine Interact. 148/149 (2003) 177-183
12. Glynn P.D., Voss C.I., and Provost A.M. Deep penetration of oxygenated meltwaters from warm based ice sheets into the Fennoscandian shield. Use of Hydrogeochemical Information in Testing Groundwater Flow Models. Technical summary and proceedings of a workshop, Borgholm, Sweden, September 1-3, 1997 (1999), Nuclear Energy Agency and Organization of Economically Developed Countries 201-241
13. Hillier S. Origin, diagenesis, and mineralogy of chlorite minerals in Devonian lacustrine mudrocks, Orcadian Basin, Scotland. Clays Clay Miner. 41 (1993) 240-259
14. Johnson C.M., Skulan J.L., Beard B.L., Sun H., Nealson K.H., and Braterman P.S. Isotopic fractionation between Fe(III) and Fe(II) in aqueous solutions. Earth Planet. Sci. Lett. 195 (2002) 141-153
15. King-Clayton L.M., Chapman N.A., Kautsky F., Svensson N.-O., Marsely G., and Ledoux M. The Central Scenario for SITE-94: A Climate Change Scenario. SKI report vol. 95:42 (1995), Swedish Nuclear Power Inspectorate (SKI). http://www.ski.se (Can be ordered free of charge at www.ski.se)
16. Kloprogge J.T., and Frost R.L. Thermal decomposition of Ferrian chamosite: an infrared emission spectroscopic study. Contrib. Mineral. Petrol. 138 (2000) 59-67
17. Kornfält K.A., Persson P.O., and Wikman H. Granitoids from the Äspö area, southeastern Sweden: geochemical and geochronological data. GFF 119 (1997) 109-114
18. In: Laaksoharju M. (Ed). Hydrogeological evaluation for Simpevarp model version 1.2. Preliminary site description of the Simpevrp area (2004), Swedish Nuclear Fuel and Waste Managements Co SKB R-04-74
19. Levasseur S., Frank M., Hein J.R., and Halliday A.N. The global variation in the iron isotope composition of marine hydrogenetic ferromanganese deposits: implications for seawater chemistry. Earth Planet. Sci. Lett. 224 (2004) 91-105
20. Mørup S., and Ostenfeld C.W. On the use of Mössbauer spectroscopy for characterisation of iron oxides and oxyhydroxides in soils. Hyperfine Interact. 136 (2001) 125-131
21. Mørup S., Bødker F., Hendriksen P.V., and Linderoth S. Spin-glass-like ordering of the magnetic moments of interacting nano-sized maghemite particles. Phys. Rev., B 52 (1995) 287-294
22. 39Ar an (U-Th)/He geochronology. Forsmark site investigation (2004), Swedish Nuclear Fuel and Waste Managements Co SKB P-04-126
23. Pedersen H.D., Postma D., Jakobsen R., and Larsen O. Fast transformation of iron oxyhydroxides by the catalytic action of aqueous Fe(II). Geochim. Cosmochim. Acta 69 (2005) 3967-3977
24. Polyakov V., and Mineev S. The use of Mössbauer spectroscopy in stable isotope geochemistry. Geochim. Cosmochim. Acta 64 (2000) 849-865
25. Schauble E.A., Rossman G.R., and Taylor Jr. H.P. Theoretical estimates of equilibrium Fe-isotope fractionation from vibrational spectroscopy. Geochim. Cosmochim. Acta. 65 (2001) 2487-2497
26. Schwertmann U., Friedl J., Stanjek H., and Schulze D.G. The effect of Al on Fe oxides. XIX. Formation of Al-substituted hematite from ferrihydrite at 25 degrees C and pH 4 to 7. Clays Clay Miner. 48 (2000) 159-172
27. Severmann S., Johnson C.M., Beard B.L., and McManus J. The effect of early diagenesis on the Fe isotope compositions of porewaters and authigenic minerals in continental margin sediments. Cosmochim. Acta 70 (2006) 2006-2022
28. Skulan J.L., Beard B.L., and Johnson C.M. Kinetic and equilibrium Fe isotope fractionation between aqueous Fe(III) and hematite. Geochim. Cosmochim. Acta 66 (2002) 2995-3015
29. Tullborg E.-L., Smellie J.A.T., and MacKenzie A.B. The use of natural uranium decay series studies in support of understanding redox conditions at potential radioactive waste disposal sites. MRS. Scientific basis for Nuclear Waste Management XXVII vol. 807 (2003) 571-576
30. Urey H.C. The thermodynamic properties of isotopic substances. J. Chem. Soc. Lond. (1947) 562-581
31. Walker J.R. Chlorite polytype geothermometry. Clays Clay Miner. 41 (1993) 260-267
32. Welch S.A., Beard B.L., Johnson C.M., and Braterman P.S. Kinetic and equilibrium Fe isotope fractionation between aqueous Fe(II) and Fe(III). Geochim. Cosmochim. Acta 67 (2003) 4231-4250
33. Williams H.M., McCammon C.A., Peslier A.H., Halliday A.N., Teutsch N., Levasseur S., and Burg J.-P. Iron isotope fractionation and the oxygen fugacity of the mantle. Science 304 (2004) 1656-1659