Chlorite dissolution in the acid ph-range: A combined microscopic and macroscopic approach

Geochimica et Cosmochimica Acta

Volumn 67, Issue 8, 2003, Pages 1451-1461

  Brandt, Felix ^a   Bosbach, Dirk ^a   Krawczyk Barsch, Evelyn ^b   Arnold, Thuro ^b   Bernhard, Gert ^b  

^a KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^b INSTITUTE OF ION BEAM PHYSICS AND MATERIALS RESEARCH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORITE; DISSOLUTION; EXPERIMENTAL STUDY; MICROSCOPY; PH; VERMICULITE;

EID: 0037447438     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(02)01293-0     Document Type: Article

References (60)

1. Acker, J. G., Bricker, O. P., (1995). The Influence of pH on Biotite Dissolution and Alteration Kinetics at low-temperature. Geochim. Cosmochim. Acta 56(8), 3073-3082.
2. Adams, W. A., (1976). Experimental evidence on the origin of vermiculite in soils of lower Palaeozoic sediments. Soil Sci. Soc. Am. J. 40, 793-796.
3. Adams, W. A., Kassim, J. K., (1983). The origin of vermiculite in soils developed from lower Palaeozoic sedimentary rocks in Mid-Wales. Soil Sci. Soc. Am. J. 47, 316-320.
4. Arnold, T., Zorn, T., Zanker, H., Bernhard, G., Nitsche, H., (2001) Sorption behavior of U(VI) on phyllite: experiments and modeling. J. Cont. Hydrol 47(2-4), 219-231.
5. Bain, D. C., (1977). Weathering of chlorite minerals in some Scottish soils. Soil Sci. Soc. Am. J. 28, 144-164.
6. Banfield, J.F., Murakami, T., (1998). Atomic-resolution transmission electron microscope evidence for the mechanism by which chlorite weathers to 1:1 semi-regular chlorite-vermiculite. Am. Mineral 83(3-4), 348-357.
7. Barnhisel R. I., and Bertsch P. M., (1989) Chlorites and Hydroxy- Interlayered Vermiculite and Smectite. In Minerals in Soil Environments. Soil Science Society of America.
8. Bickmore, B. R., Bosbach, D., Hochella, M. F., Charlet, L., Rufe, E., (2001). In situ atomic force microscopy study of hectorite and nontronite dissolution: Implications for phyllosilicate edge surface structures and dissolution mechanisms. Am. Mineral 86(4), 411-423.
9. Bickmore, B.R., Hochella, M.F., Bosbach, D., Charlet, L., 1999. Methods for performing atomic force microscopy imaging of clay minerals in aqueous solutions. Clays Clay Min 47 (5), 573-581.
10. Blum, A. E., Lasaga, A. C., (1988). Role of surface speciation in the low-temperature dissolution of minerals. Nature 331, 431-433.
11. Bosbach, D., Charlet, L., Bickmore, B., Hochella, M. F., 2000. The dissolution of hectorite: In-situ, real-time observations using atomic force microscopy. American Mineral 85(9), 1209-1216.
12. Brantley S. and Chen Y., 1995 Chemical Weathering Rates Of Pyroxenes and Amphiboles. In Reviews in Mineralogy (ed White A. F. and Brantley S. L.) Vol. 31 pp. 119-172. Min. Soc. Am
13. Brindley G. W. and Brown G., 1984 Crystal Structures of Clay Minerals and their X-Ray Identification. Mineralogical Society.
14. Brunauer, S., Emmet, P. H., Teller, E., (1938). Adsorption of gas in multimolecular layers. J. Am. Chem. Soc 60, 309-319.
15. Cama, J., Ayora, C., Lasaga, A. C., (1999). The deviation-from- equilibrium effect on dissolution rate and on apparent variations in activation energy. Geochim. Cosmochim. Acta 63(17), 2481-2486.
16. Cama, J., Ganor, J., Ayora, C., Lasaga, C. A., (2000). Smectite dissolution kinetics at 80 degrees C and pH 8.8. Geochim. Cosmochim. Acta 64(15), 2701-2717.
17. Cama, J., Ganor, J., Lasaga, A. C., (1994). The kinetics of smectite dissolution. Min. Mag 58(A), 140-141.
18. Caroll, S. A., Walther, J. V., (1990). Kaolinite dissolution at 25°, 60° and 80°C. Am J Sci 290, 797-810.
19. Caroll-Webb, S., Walther, J., (1988). A surface complex reaction model for the pH dependence of corundum and kaolinite dissolution rates. Geochim. Cosmochim. Acta 52, 2609-2623.
20. Casey W.H. and Bunker B. 1990 Leaching of mineral and glass surfaces during dissolution. In Mineral-Water Interface Geochemistry (ed. M. F. Hochella Jr. and A. F. White) Vol. 23, pp. 397-426. Min. Soc. America
21. Chou, L., and Wollast, R. (1984). Study of the weathering of albite at room temperature and pressure in a fluidized bed reactor. Geochim. Cosmochim. Acta 48, 2205-2217.
22. Coffman, C. B., and Fanning, D. S. (1975). Maryland soils developed in residuum from chlorite metabasalt having high amounts of vermiculite in sand and silt fractions. Soil Sci. Soc. Am. Proc. 39, 723-732.
23. Ganor, J., Mogollon, J. L., and Lasaga, A. C. (1995). The Effect of pH on Kaolinite Dissolution Rates and on Activation-Energy. Geochim. Cosmochim. Acta 59(6), 1037-1052.
24. Ganor, J., Mogollon, J. L., and Lasaga, A. C. (1999). Kinetics of gibbsite dissolution under low ionic strength conditions. Geochim. Cosmochim. Acta 63(11-12), 1635-1651.
25. Helgeson, H., Murphy, W., and Aagard, P. (1984). Thermodynamic and kinetic constraints on reaction rates among minerals and aquaeous solutions. II. Rate constants, effective surface area, and the hydrolysis of feldspar. Geochim. Cosmochim. Acta 48, 2405-2432.
26. Herbillon, A. J., and Makumbi, M. N. (1975). Weathering of chlorite in a soil derived from a chlritoischist under humid tropical conditions. Geoderma 13, 89-104.
27. Herrmann G. A. (1975) Praktikum der Gesteinsanalyse. Springer.
28. Hochella, M. F., Moore, J. N., Golla, U., and Putnis, A. (1999). A TEM study of samples from acid mine drainage systems: Metal- mineral association with implications for transport. Geochim. Cosmochim. Acta 63(19-20), 3395-3406.
29. Johnsson P., Hochella Jr. M. F., Parks G., Blum A. E. and Sposito G. (1992) Direct observation of muscovite basal-plane dissolution and secondary phase formation: An XPS,LEED and SFM study. In Water Rock Interactions (ed. Y. Kharaka and A. Maes), pp. 159-162. AA Balkema.
30. Jordan, G., and Rammensee, W. (1996). Dissolution rates and activation energy for dissolution of brucite (001): A new method based on the microtopography of crystal surfaces. Geochim. Cosmochim. Acta 60(24), 5055-5062.
31. Joswig, W., Fuess, H., Rothbauer, R., Takeuchi, Y., and Mason, S. (1980). A neutron diffraction studey of a one-layer triclinic chlorite (pennite). Am. Mineral 65, 349-352.
32. Knauss, K. G., and Wolery, T. J. (1988). The dissolution kinetics of quarz as function of pH and time at 70°. Geochim. Cosmochim. Acta 53, 43-53.
33. Knauss, K. G., and Wolery, T. J. (1989). Muscovite dissolution kinetics as a function of pH and time at 70°C. Geochim. Cosmochim. Acta 53, 1493-1501.
34. Krawczyk-Bärsch E., Arnold T., Hüttig G., Zänker H., Brandt F., Bosbach D., and Bernhard G. (2001). The effect of secondary iron mineral and colloid formation on uranium sorption during the dissolution of chlorite. In Eleventh Annual V. M. Goldschmidt Conference, Abstract Nr. 3161. LPI Contribution No. 1088, Lunar and Planetary Institute, Houston (CD-ROM).
35. Lougear, A., Grodzicki, M., Bertoldi, C., Trautwein, A. X., Steiner, K., and Amthauer, G. (2000). Mössbauer and molecular orbital study of chlorites. Phys. Chem. Min 27(4), 258-269.
36. Lowson R., Comarmond M., Rajaratnam G., and Brown P. (2002). Personal communication.
37. Malmström M. and Banwart S. (1997) Biotite dissolution at 25°C: The pH dependence of dissolution rate and stoichiometry. Geochim. Cosmochim. Acta 61(14), 2779-2799.
38. Malmström M., Banwart S., Lewenhagen J., Duro L., and Bruno J. (1996) The dissolution of biotite and chlorite at 25°C in the near-neutral pH region. J. Contam. Hydrol. 21(1-4), 201-213.
39. May H. M., Acker J. G., Smyth J. R., Bricker O. P., and Dyar M. D. (1995) Aqueous dissolution of Low-Iron Chlorite in dilute acid solutions at 25°C. 32nd Ann. Meeting Clay Minerals Society.
40. Metz V. and Ganor J. (2001) Stirring effect on kaolinite dissolution rate. Geochim. Cosmochim. Acta 65(20), 3475-3490.
41. Moore D. M. and Reynolds R. C. (1997) X-Ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press.
42. Nagy K. L. (1996) Dissolution and precipitation kinetics of sheet silicates. In Rev. Mineral (ed. A. F. White and S. L. Brantley) Vol. 31, pp. 173-233. Mineralogical Society of America.
43. Nagy K. L., Blum A. E., and Lasaga A. C. (1991) Dissolution and precipation kinetics of kaolinite at 80°C and pH 3: The dependence on solution saturation state. Am. J. Sci. 291, 649-686.
44. Nagy K. L. and Lasaga A. C. (1992) Dissolution and precipitation kinetics of gibbsite at 80°C and pH 3: The dependence on solution saturation state. Geochim. Cosmochim. Acta 56, 3093-3111.
45. Oelkers E. H. (2001a) An experimental study of forsterite dissolution rates as a function of temperature and aqueous Mg and Si concentrations. Chem. Geol. 175(3-4), 485-494.
46. Oelkers E. H. (2001b) General kinetic description of multioxide silicate mineral and glass dissolution. Geochim. Cosmochim. Acta 65(21), 3703-3719.
47. Parkhurst D. and Appelo C. (1999) PHREEQC for Windows. A hydrochmical transport model. Graphical user interface by V.E.A. Post.
48. Rochelle C. A., Bateman K., MacGregor R., Pearce J. M., Savage D., and Wetton P. D. (1996) Experimental determination of chlorite dissolution rates. Materials Research Society Symposium.
49. Ross G. J. (1969) Acid dissolution of chlorites: Release of Magnesium, Iron and Aluminum and mode of acid attack. Clays Clay Mineral. 17, 347-354.
50. Rufe E. and Hochella Jr. M. F. (1999) Quantitative Assessment of Reactive Surface Area of Phlogopite During Acid Dissolution. Science 285(5429), 874-876.
51. Rule A. C. and Bailey S. W. (1987) Refinement of the crystal structure of a monoclinic ferroan clinochlore. Clays Clay Mineral. 35(2), 129-138.
52. Salmon S. U., and Malmström M. E. (2001) Mineral weathering Rates in Mill Tailings From Kristinenberg, Northern Sweden. In Eleventh Ann. V.M. Goldschmidt Conference, Abstract # 3375. LPI Contribution No. 1088, Lunar and Planetary Institute, Houston (CD-ROM).
53. Schwertmann U. and Cornell R. M. (2000) Iron. Oxides in the Laboratory. Second Edition. Wiley-VCH Verlag.
54. Steinfink H. (1958a) The crystal structure of chlorite. I. A monoclinic polymorph. Acta Crystall. 11, 191-195.
55. Steinfink H. (1958b) The crystal structure of chlorite. II. A triclinic polymorph. Acta Crystall. 11, 195-198.
56. Steinfink H. (1961) Accuracy in structure analysis of layer silicates: Some further comments on the structure of prochlorite. Acta Crystall. 14, 198-199.
57. Stumm W. and Wollast R. (1990) Coordination chemistry of weathering: Kinetics of the surface controlled dissolution of oxide minerals. Rev. Geophys. 28, 53-69.
58. Turpault M. P. and Trotignon L. (1994) The dissolution of biotite single crystals in dilute HNO3 at 24°C: Evidence of an anisotropic corrosion process of micas in acidic solutions. Geochim. Cosmochim. Acta 58(13), 2761-2775.
59. Wherli B. (1989) Monte Carlo simulations of surface morphologies during mineral dissolution. J. Coll. Interface Sci. 132, 230-242.
60. White A. F. and Brantley S. L. (1995) Chemical Weathering Rates of Silicate Minerals: An Overview In Rev. Mineral (ed. A. F. White and S. L. Brantley) Vol. 31, pp. 1-21. Mineralogical Society of America.