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Reviews include the following: Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity (Eds.: M. T. Pope, A. Müller), Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994, pp. 1-141.
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Actually, depending on the experimental conditions ionic strength, nature of the mixed acid salt or concentration of the polyanion, these lines may be split into single components
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Actually, depending on the experimental conditions (ionic strength, nature of the mixed acid salt or concentration of the polyanion), these lines may be split into single components.
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34548359856
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W-O-W coupling constants are in the range 15-25 Hz for corner junctions (W-O-W ≈ 150°) and about 4-7 Hz for W coupled through edge junctions (W-O-W ≈125°).
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W-O-W coupling constants are in the range 15-25 Hz for corner junctions (W-O-W ≈ 150°) and about 4-7 Hz for W coupled through edge junctions (W-O-W ≈125°).
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35
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34548357779
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In the 2D 183W NMR spectrum of 4, most couplings through edge junctions are too weak to give rise to off-diagonal cross-peaks
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183W NMR spectrum of 4, most couplings through edge junctions are too weak to give rise to off-diagonal cross-peaks.
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G. M. Sheldrick, SADABS, Program for scaling and correction of area detector data, University of Göttingen, Germany, 1997.
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G. M. Sheldrick, SHELX-TL version 5.03, Software Package for Crystal Structure Determination, Siemens Analytical X-ray Instrument Division, Madison, WI, USA, 1994.
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