Synthesis of the 2,4,5-tri-tert-butyl-1,3-diphospholide anion by phosphinidene elimination from 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene on treatment with the amide Li[NPh(SiMe3)]

Chemistry - A European Journal

Volumn 13, Issue 25, 2007, Pages 7121-7128

  Clendenning, Scott B ^a   Hitchcock, Peter B ^a   Lappert, Michael F ^a   Merle, Philippe G ^a   Nixon, John F ^a   Nyulászi, László ^b  

^a UNIVERSITY OF SUSSEX   (United Kingdom)

^b BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

Author keywords

Amides; Density functional calculations; Phosphinidenes; Phosphorus heterocycles; Reaction mechanisms; Reactivity

Indexed keywords

LITHIUM AMIDES; PHOSPHINIDENES; PHOSPHORUS HETEROCYCLES; REACTION MECHANISMS;

DENSITY FUNCTIONAL THEORY; MOLAR MASS; REACTION RATES; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

LITHIUM COMPOUNDS;

2,4,6 TRI TERT BUTYL 1,3,5 TRIPHOSPHABENZENE; 2,4,6-TRI-TERT-BUTYL-1,3,5-TRIPHOSPHABENZENE; AMIDE; ANION; LITHIUM; ORGANOMETALLIC COMPOUND; ORGANOPHOSPHORUS COMPOUND; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

AMIDES; ANIONS; CRYSTALLOGRAPHY, X-RAY; LITHIUM; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; ORGANOPHOSPHORUS COMPOUNDS;

EID: 34548296993     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200601626     Document Type: Article

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