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The estimation leading to 0.7 eV for the electron affinity of phosphabenzene in ref 6 was based on the admittedly rough assumption that the IBs and the VAEs show the same linear dependence on the C-heteroatom bond length along the pyridine-stibabenzene series. Furthermore, although not clearly stated, the result reported there is more likely associated with the adiabatic (rather than the vertical) electron affinity.
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