Preparation and crystal structures of low-valent zirconocene complexes containing tetramethyl(phenyl)cyclopentadienyl ligands

Collection of Czechoslovak Chemical Communications

Volumn 72, Issue 5-6, 2007, Pages 679-696

  Horáček, Michal ^a   Pinkas, Jiří ^a   Kubišta, Jiří ^a   Císařová, Ivana ^b   Gyepes, Róbert ^b   Štěpnička, Petr ^b  

^a J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

^b CHARLES UNIVERSITY   (Czech Republic)

Author keywords

Alkynes; Bis(trimethylsilyl)acetylene; Crystal structures; Cyclopentadienyl ligand; Low valent zirconium complexes; Metallocenes; X ray diffraction; Zirconocenes

Indexed keywords

EID: 34548049735     PISSN: 00100765     EISSN: None     Source Type: Journal    
DOI: 10.1135/cccc20070679     Document Type: Article

References (47)

1. a) Binger P., Podubrin S. in: Comprehensive Organometallic Chemistry II (M. F. Lappert, Ed.), Chap. 7, pp. 439-463. Pergamon, Elsevier Science Ltd., Oxford 1995;
2. b) Hoveyda A. H. in: Transition Metal for Organic Synthesis (M. Beller and C. Bolm, Eds), Chap. 2.12, pp. 257-269. Wiley-VCH, Weinheim 2004;
3. c) Negishi E., Huo S. in: Titanium and Zirconium in Organic Synthesis (I. Marek, Ed.), Chap. 1, pp. 1-49. Wiley-VCH, Weinheim 2002;
4. d) Takahashi T., Li Y. in: Titanium and Zirconium in Organic Synthesis (I. Marek, Ed.), Chap. 2, pp. 50-85. Wiley-VCH, Weinheim 2002;
5. e) Kaminsky W., Arndt M. in: Applied Homogeneous Catalysis with Organometallic Compounds (B. Cornils and W. A. Herrmann, Eds), Chap. 2.3, pp. 220-236. Wiley-VCH, Weinheim 1996;
6. f) Rosenthal U., Burlakov V. V. in: Titanium and Zirconium in Organic Synthesis (I. Marek, Ed.), Chap. 10, pp. 355-389; and references therein. Wiley-VCH, Weinheim 2002
7. Horáček M., Štèpnic̀ka P., Kubista J., Gyepes R., Mach K.: Organometallics 2004, 23, 3388.
8. a) Rosenthal U., Pellny P.-M., Kirchbauer F. G., Burlakov V. V.: Acc. Chem. Res. 2000, 33, 119;
9. b) Rosenthal U., Burlakov V. V., Arndt P., Baumann W., Spannenberg A., Shur V. B.: Eur. f. Inorg. Chem. 2004, 4739.
10. a) Negishi E., Cederbaum F. E., Takahashi T.: Tetrahedron Lett. 1986, 27, 2829;
11. b) Goddard R., Binger P., Hall S. R., Muller P.: Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1990, 46, 998;
12. c) Erker G.: Angew. Chem., Int. Ed. Engl. 1989, 28, 397;
13. d) Rosenthal U., Ohff A., Michalik M., Görls H., Burlakov V. V., Shur V. B.: Angew. Chem., Int. Ed. Engl. 1993, 32, 1193;
14. e) Rosenthal U., Ohff A., Baumann W., Tillack A., Görls H., Burlakov V. V., Shur V. B.: Z. Anorg. Allg. Chem. 1995, 621, 77.
15. a) Rosenthal U., Ohff A., Michalik M., Gorls H., Burlakov V. V., Shur V. B.: Angew. Chem., Int. Ed. Engl. 1993, 32, 1193;
16. b) Hiller J., Thewalt U., Polášek M., Petrusová L., Varga V., Sedmera P., Mach K.: Organometallics 1996, 25, 3752.
17. a) Horác̀ek M., Štěpnic̀ka P., Kubišta J., Fejfarová K., Gyepes R., Mach K.: Organometallics 2003, 22, 861;
18. b) Langmaier J., Samec Z., Varga V., Horác̀ek M., Choukroun R., Mach K.: J. Organomet. Chem. 1999, 554, 323.
19. Schmid G., Thewalt U., Sedmera P., Hanuš V., Mach K.: Collect. Czech. Chem. Commun. 1998, 63, 636.
20. Erker G., Wicher J., Engel K., Rosenfeldt F., Dietrich W., Kruger C.: J. Am. Chem. Soc. 1980, 102, 6344.
21. a) Lefeber C., Ohff A., Tillack A., Baumann W., Kempe R., Burlakov V. V., Rosenthal U., Gorls H.: J. Organomet. Chem. 1995, 502, 179;
22. b) Klein R., Sedmera P., C̀ejka J., Mach K.: J. Organomet. Chem. 1992, 436, 143;
23. c) Vollhardt K. P. C.: Acc Chem. Res. 1977, 10, 1.
24. a) Borkowsky S. L., Jordan R. F., Hinch G. D.: Organometallics 1991, 10, 1268;
25. b) Breen T. L., Stephan D. W.: Inorg. Chem. 1992, 31, 4019.
26. a) Bartmann E.: J. Organomet. Chem. 1985, 284, 149;
27. b) Steudel W., Gilman H.: J. Am. Chem. Soc. 1960, 82, 6129;
28. c) Kang J., Kim S. H.: Bull. Korean Chem. Soc. 2000, 21, 611;
29. d) Eisch J. J., Gitua J. N.: Organometallics 2007, 26, 778.
30. a) Janiak C., Versteeg U., Lange K. C. H., Weimann R., Hahn E.: J. Organomet. Chem. 1995, 501, 219;
31. b) Krut'ko D. P., Borzov M. V., Kirsanov R. S., Antipin M. Y., Churakov A. V.: J. Organomet. Chem. 2004, 689, 595;
32. c) Kurz S., Hey-Hawkins E.: Z. Kristallogr. 1993, 205, 61;
33. d) Pinkas J., Horác̀ek M., Kubišta J., Gyepes R., Císařová I., Pirio N., Meunier P., Mach K.: J. Organomet. Chem. 2004, 689, 1623.
34. Horác̀ek M., Kupfer V., Thewalt U., Ště pnička P., Polášek M., Mach K.: Organometallics 1999, 18, 3572.
35. a) Mach K., Gyepes R., Horáček M., Petrusová L., Kubišta J.: Collect. Czech. Chem. Commun. 2003, 68, 1877;
36. b) Horáček M., Polášek M., Kupfer V., Thewalt U., Mach K.: Collect. Czech. Chem. Commun. 1999, 64, 61;
37. c) Kupfer V., Thewalt U., Horáček M., Petrusová L., Mach K.: Inorg. Chem. Commun. 1999, 2, 540.
38. Gyepes R.: Unpublished results.
39. a) Erker G., Hehr G., Fröhlich R.: J. Organomet. Chem. 2004, 689, 4305, and references therein;
40. b) Dahlmann M., Erker G., Fröhlich R., Meyer O.: Organometallics 1999, 18, 4459;
41. c) Erker G., Wicher J., Engel K., Rosenfeldt F., Dietrich W.: J. Am. Chem. Soc. 1980, 102, 6344.
42. Antropiusová H., Dosedlová A., Hanuš V., Mach K.: Transition Met. Chem. (London) 1981, 6, 90.
43. Otwinowski Z., Minor W.: HKL Denzo and Scalepack, Program Package by Nonius.
44. For a reference, see Otwinowski Z., Minor W.: Methods Enzymol. 1997, 276, 307.
45. Altomare A., Burla M. C., Camalli M., Cascarano G., Giacovazzo C., Guagliardi A., Polidori G.: J. Appl. Crystallogr. 1994, 27, 435.
46. Sheldrick G. M.: SHELXL97, Program for Crystal Structure Refinement from Diffraction Data. University of Göttingen, Göttingen 1997.
47. Spek A. L.: PLATON, A Multipurpose Crystallographic Tool. Utrecht University, Utrecht 2007.