Linear dimerization of terminal alkynes by bis(tetramethylphenylcyclopentadienyl)titanium-magnesium hydride and acetylide complexes

Collection of Czechoslovak Chemical Communications

Volumn 68, Issue 10, 2003, Pages 1877-1896

  Mach, Karel ^a   Gyepes, Róbert ^b   Horáček, Michal ^a   Petrusová, Lidmila ^a   Kubišta, Jiří ^a  

^a J HEYROVSKÝ INSTITUTE OF PHYSICAL CHEMISTRY   (Czech Republic)

^b CHARLES UNIVERSITY   (Czech Republic)

Author keywords

Alkynes; Crystal structure; Dimerization; ESR spectroscopy; Homogeneous catalysis; Hydrides; Magnesium; Metallocenes; Titanium; Titanocene acetylide

Indexed keywords

ACETIC ACID DERIVATIVE; ACETYLENE DERIVATIVE; ALKYNE DERIVATIVE; DIMER; MAGNESIUM DERIVATIVE; TITANIUM DERIVATIVE; TITANOCENE;

CONFERENCE PAPER; CRYSTAL STRUCTURE; DIMERIZATION; DISSOCIATION; ELECTRON SPIN RESONANCE; REACTION ANALYSIS;

EID: 0345015521     PISSN: 00100765     EISSN: None     Source Type: Journal    
DOI: 10.1135/cccc20031877     Document Type: Conference Paper

References (42)

1. a) For Ti: Akita H., Yasuda H., Nakamura A.: Bull. Chem. Soc. Jpn. 1984, 57, 480;
2. b) for Zr: Horton A. D.: J. Chem. Soc., Chem. Commun. 1992, 185;
3. c) for Hf: Yoshida M., Jordan R. F.: Organometallics 1997, 16, 4508.
4. a) For Sc: Thompson M. E., Baxter S. M., Bulls A. R., Burger B. J., Nolan M. C., Santarsiero B. D., Schaefer W. P., Bercaw J. E.: J. Am. Chem. Soc. 1987, 109, 203;
5. b) for Y: den Haan K. H., Wielstra Y., Teuben J. H.: Organometallics 1987, 6, 2053;
6. c) for Y, La, Ce: Heeres H. J., Teuben J. H.: Organometallics 1991, 10, 1980.
7. Varga V., Petrusová L., Čejka J., Mach K.: J. Organomet. Chem. 1997, 532, 251.
8. Horáček M., Císařová I., Karban J., Petrusová L., Mach K.: J. Organomet. Chem. 1999, 577, 103.
9. a) Troyanov S. I., Varga V., Mach K.: J. Chem. Soc., Chem. Commun. 1993, 1174;
10. b) Gyepes R., Mach K., Císařová I., Loub J., Hiller J., Šindelář P.: J. Organomet. Chem. 1995, 497, 33.
11. Troyanov S. I., Varga V., Mach K.: J. Organomet. Chem. 1993, 461, 85.
12. Luinstra G. A., ten Cate L. C., Heeres H. J., Pattiasina J. W., Meetsma A., Teuben J. H.: Organometallics 1991, 10, 3227.
13. a) Varga V., Petrusová L., Čejka J., Hanuš V., Mach K.: J. Organomet. Chem. 1996, 509, 235;
14. b) Štěpnička P., Gyepes R., Císař ová I., Horáček M., Kubišta J., Mach K.: Organometallics 1999, 18, 4869;
15. c) Gyepes R., Císařová I., Horáček M., Čejka J., Petrusová L., Mach K.: Collect. Czech. Chem. Commun. 2000, 65, 1248.
16. Horáček M., Polášek M., Kupfer V., Thewalt U., Mach K.: Collect. Czech. Chem. Commun. 1999, 64, 61.
17. Langmaier J., Samec Z., Varga V., Horáček M., Mach K.: J. Organomet. Chem. 1999, 579, 348.
18. a) Samuel E., Harrod J. F., Gourier D., Dromzee Y., Robert F., Jeannin Y.: Inorg. Chem. 1992, 31, 3252;
19. b) Mach K., Varga V., Schmid G., Hiller J., Thewalt U.: Collect. Czech. Chem. Commun. 1996, 61, 1285.
20. de Wolf J. M., Meetsma A., Teuben J. H.: Organometallics 1995, 14, 5466.
21. Lukens W. W., Matsunaga P. T., Andersen R. A.: Organometallics 1998, 17, 5240.
22. a) Pattiasina J. W., Heeres H. J., van Bolhuis F., Meetsma A., Teuben J. H., Spek A. L.: Organometallics 1987, 6, 1004;
23. b) Lukens W. W., Smith III, M. R., Andersen R. A.: J. Am. Chem. Soc. 1996, 118, 1719.
24. Kupfer V., Thewalt U., Horáček M., Petrusová L., Mach K.: Inorg. Chem. Commun. 1999, 2, 540.
25. a) Brintzinger H. H.: J. Am. Chem. Soc. 1967, 89, 6871;
26. b) Kenworthy J. G., Myatt J., Symons M. C. R.: J. Chem. Soc. A 1971, 1020;
27. c) Horáček M., Hiller J., Thewalt U., Poláš ek M., Mach K.: Organometallics 1997, 16, 4185.
28. Troyanov S. I., Varga V., Mach K.: Organometallics 1993, 12, 2820.
29. a) Varga V., Hiller J., Polášek M., Thewalt U., Mach K.: J. Organomet. Chem. 1996, 515, 57;
30. b) Hiller J., Varga V., Thewalt U., Mach K.: Collect. Czech. Chem. Commun. 1997, 62, 1446.
31. Mach K., Raynor J. B.: J. Chem. Soc., Dalton Trans. 1992, 683.
32. Kirchbauer F. G., Pellny P.-M., Sun H., Burlakov V. V., Arndt P., Baumann W., Spannenberg A., Rosenthal U.: Organometallics 2001, 20, 5289.
33. Allen F. H., Kennard O., Watson D. G., Brammer L., Orpen A. G., Taylor R.: J. Chem. Soc., Perkin Trans. 2 1987, S1.
34. Markies P. R., Akkerman O. S., Bickelhaupt F., Smeets W. J. J., Spek A. L.: Adv. Organomet. Chem. 1991, 32, 147; and references therein.
35. Varga V., Mach K., Schmid G., Thewalt U.: J. Organomet. Chem. 1994, 475, 127.
36. Mach K., Antropiusová H., Polášek J.: J. Organomet. Chem. 1990, 385, 335.
37. Antropiusová H., Dosedlová A., Hanuš V., Mach K.: Transition Met. Chem. (London) 1981, 6, 90.
38. Varga V., Mach K., Polášek M., Sedmera P., Hiller J., Thewalt U., Troyanov S. I.: J. Organomet. Chem. 1996, 506, 241.
39. Otwinowski Z., Minor W.: HKL Denzo and Scalepack Program Package. Nonius BV, Delft 1997. For a reference, see: Otwinowski Z., Minor W.: Methods Enzymol. 1997, 276, 307.
40. Otwinowski Z., Minor W.: HKL Denzo and Scalepack Program Package. Nonius BV, Delft 1997. For a reference, see: Otwinowski Z., Minor W.: Methods Enzymol. 1997, 276, 307.
41. Altomare A., Burla M. C., Camalli M., Cascarano G., Giacovazzo C., Guagliardi A., Polidori G.: J. Appl. Crystallogr. 1994, 27, 435.
42. Sheldrick G. M.: SHELXL97. Program for Crystal Structure Refinement from Diffraction Data. University of Göttingen, Göttingen 1997.