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33746294933
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note
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The inner diameters are calculated as geometrically opposing atomic distances, minus the following van der Waals radii: P, 0.18 nm; Cu, 0.14 nm. The outer diameter is taken as twice the largest distance from the theoretical center of the molecule to the tBu hydrogen atoms, plus twice the van der Waals radius for H (2 x 0.12 nm). For the inner cavity, the term "diameter" is defined here as the diameter of the largest spherical form that is geometrically allowed inside the cavity by the given atoms.
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20
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33746271795
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31P MAS NMR spectrum of 2 at room temperature, a broad, unresolved signal is observed at δ = -70 ppm, which is broadened as a result of the P,P and in particular the P,Cu coupling.
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