A simple relation for the concentration dependence of osmotic pressure and depletion thickness in polymer solutions

Macromolecular Theory and Simulations

Volumn 16, Issue 5, 2007, Pages 531-540

  Fleer, Gerard J ^a   Skvortsov, Alexander M ^b   Tuinier, Remco ^c  

^a WAGENINGEN UNIVERSITY   (Netherlands)

^b ST PETERSBURG STATE CHEMICAL PHARMACEUTICAL ACADEMY   (Russian Federation)

^c FORSCHUNGSZENTRUM JÜLICH   (Germany)

Author keywords

Depletion thickness; Osmotic pressure; Polymer solutions; Solution properties; Thermodynamics

Indexed keywords

CONCENTRATION (PROCESS); EXTRAPOLATION; POLYMER SOLUTIONS; THERMODYNAMICS;

DEPLETION THICKNESS; EXTRAPOLATION CONCENTRATION; SOLUTION PROPERTIES;

OSMOSIS;

EID: 34547634771     PISSN: 10221344     EISSN: 15213919     Source Type: Journal    
DOI: 10.1002/mats.200700022     Document Type: Article

References (35)

1. P. J. Flory, "Principles of Polymer Chemistry", Cornell University Press, Ithaca, New York 1953.
2. G. J. Fleer, M. A. Cohen Stuart, J. M. H. M. Scheutjens, T. Cosgrove, B. Vincent, "Polymers at Interfaces", Chapman & Hall, London 1993.
3. H. Yamakawa, "Modern Theory of Polymer Solutions", Harper and Row, New York 1971.
4. G. J. Fleer, A. M. Skvortsov, R. Tuinier, Macromolecules 2003, 36, 7857.
5. L. T. Lee, O. Guiselin, A. Lapp, B. Farnoux, Phys. Rev. Lett. 1991, 67, 2838.
6. P.-G. De Gennes, "Scaling Concepts in Polymer Physics", Cornell University Press, Ithaca, New York 1979.
7. J. Des Cloiseaux, G. Jannink, "Polymers in Solution", Oxford University Press, Oxford 1990.
8. D. G. A. L. Aarts, R. Tuinier, H. N. W. Lekkerkerker, J. Phys.: Condens. Matter 2002, 14, 7551.
9. W. W. Yau, J. J. Kirkland, D. D. Bly, "Modern Size Exclusion Liquid Chromatography", John Wiley, New York 1979.
10. H. Pasch, B. Trathnigg, "HPLC of Polymers", Springer, Berlin 1997.
11. A. Baumgärtner, "Application of the Monte Carlo Method in Statistical Polymers", K. Binder, Ed., Springer, New York 1984, Chap. 4.
12. R. Dickman, J. Chem Phys. 1989, 91, 454;
13. 1988, 89, 7577;
14. 1987, 87, 2246.
15. A. Milchev, W. Paul, K. Binder, J. Chem. Phys. 1993, 99, 4786.
16. A. Pelisetto, E. Vicari, Phys. Rep. 2002, 368, 549.
17. T. Ohta, Y. Oono, Phys. Lett. 1982, 89A, 460.
18. A. Nakanishi, T. Ohta, J. Phys A: Math. Gen. 1985, 18, 127.
19. L. Schäfer, Macromolecules 1984, 17, 1357.
20. L. Schäfer, "Excluded Volume Effects in Polymer Solutions", Springer Verlag, Berlin 1999.
21. I. Noda, N. Kato, T. Kitano, M. Nagasawa, Macromolecules 1981, 14, 688.
22. P. G. Bolhuis, A. A. Louis, J.-P. Hansen, E. J. Meijer, J. Chem. Phys. 2001, 114, 4296.
23. A. A. Louis, P. G. Bolhuis, E. J. Meijer, J. Chem. Phys. 2002, 116, 10547.
24. E. F. Casassa, J. Pol. Sci. B 1967, 5, 773;
25. Macromolecules 1969, 2, 14.
26. E. Eisenriegler, "Polymers near Surfaces", World Scientific, Singapore 1993.
27. A. Hanke, E. Eisenriegler, S. Dietrich, Phys. Rev. E. 1999, 59, 6853.
28. W. Y. Shih, W.-H. Shih, I. A. Aksay, Macromolecules 1990, 23, 3291.
29. G. J. Fleer, A. M. Skvortsov, Macromolecules 2005, 38, 2492.
30. P. Cifra, T. Bleha, J. Wang, I. Teraoka, J. Chem. Phys. 2000, 113, 8313.
31. P. G. Bolhuis, A. A. Louis, Macromolecules 2002, 35, 1860.
32. C. N. Satterfield, C. K. Colton, B. de Turckheim, T. M. Copeland, AIChE J. 1978, 24, 937.
33. P. Wiltzius, H. R. Haller, D. S. Canell, Phys Rev. Lett. 1983, 51, 1183.
34. F. Hamada, S. Kinugasa, H. Hayashi, A. Nakajima, Macromolecules 1985, 18, 2290.
35. H. Meirovitch, Macromolecules. 1985, 18, 569.