Self-assembled antimony-thiolate Sb2L3 and Sb2L2Cl2 complexes

Main Group Chemistry

Volumn 5, Issue 1, 2006, Pages 51-59

  Jake Vickaryous, W ^a   Zakharov, Lev N ^a   Johnson, Darren W ^a  

^a UNIVERSITY OF OREGON   (United States)

Author keywords

Antimony compounds; Antimony arene interactions; Coordination chemistry; Pnictogens; Supramolecular chemistry; Thiolate ligands

Indexed keywords

EID: 34547527927     PISSN: 10241221     EISSN: 17451167     Source Type: Journal    
DOI: 10.1080/10241220600857710     Document Type: Conference Paper

References (40)

1. N.C. Gianneschi, M.S. Masar, III, C.A. Mirkin. Development of a coordination chemistry-based approach for functional supramolecular structures. Acc. Chem. Res., 38, 825 (2005).
2. D. Fiedler, D.H. Leung, R.G. Bergman, K.N. Raymond. Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels. Acc. Chem. Res., 38, 351 (2005).
3. M. Fujita, M. Tominaga, A. Hori, B. Therrien. Coordination assemblies from a Pd(II)-cornered square complex. Acc. Chem. Res., 38, 371 (2005).
4. L.M.C. Beltran, J.R. Long. Directed assembly of metal-cyanide cluster magnets. Acc. Chem. Res., 38, 325 (2005).
5. D.R. Turner, A. Pastor, M. Alajarin, J.W. Steed. Molecular containers: design approaches and applications. Structure and Bonding (Berlin, Germany), 108, 97 (2004).
6. M. Ruben, J. Rojo, F.J. Romero-Salguero, L.H. Uppadine, J.-M. Lehn. Grid-type metal ion architectures: Functional metallosupramolecular arrays. Angew. Chem. Int. Ed., 43, 3644 (2004).
7. S.R. Seidel, P.J. Stang. High-symmetry coordination cages via self-assembly. Acc. Chem. Res., 35, 972 (2002).
8. F. Hof, S.L. Craig, C. Nuckolls, J. Rebek, Jr. Molecular encapsulation. Angew. Chem. Int. Ed., 41, 1488 (2002).
9. P.H. Dinolfo, J.T. Hupp. Supramolecular coordination chemistry and functional microporous molecular materials. Chem. Mater., 13, 3113 (2001).
10. B.J. Holliday, C.A. Mirkin. Strategies for the construction of supramolecular compounds through coordination chemistry. Angew. Chem. Int. Ed., 40, 2022 (2001).
11. D.W. Johnson, K.N. Raymond. The role of guest molecules in the self-assembly of metal-ligand clusters. Supramol. Chem., 13, 639 (2001).
12. S. Leininger, B. Olenyuk, P.J. Stang. Self-assembly of discrete cyclic nanostructures mediated by transition metals. Chem. Rev., 100, 853 (2000).
13. G.F. Swiegers, T.J. Malefetse. New self-assembled structural motifs in coordination chemistry. Chem. Rev., 100, 3483 (2000).
14. D.L. Caulder, K.N. Raymond. Supermolecules by design. Acc. Chem. Res., 32, 975 (1999).
15. C. Piguet, G. Bernardinelli, G. Hopfgartner. Helicates as versatile supramolecular complexes. Chem. Rev., 97, 2005 (1997).
16. E.R. Healey, W.J. Vickaryous, O.B. Berryman, D.W. Johnson. Self-Assembled Supramolecular Main Group Coordination Complexes. In BOTTOM-UP NANOFABRICATION: Supramolecules, Self-Assemblies, and Organized Films, H.S. Nalwa (Ed.), American Scientific Publishers, New York.
17. M. Albrecht, O. Blau, R. Frohlich. An expansible metalla-cryptand as a component of a supramolecular combinatorial library formed from di(8-hydroxyquinoline) ligands and gallium(III) or zinc(II) ions. Eur. J. Chem., 5, 48 (1999).
18. F.P. Gabbai, A. Schier, J. Riede. A bifunctional Lewis acidic spacer in self-assembled molecular stairs and ladders. Angew. Chem. Int. Ed., 37, 622 (1998).
19. A.M. Garcia, F.J. Romero-Salguero, D.M. Bassani, J.-M. Lehn, G. Baum, D. Fenske. Self-assembly and characterization of multimetallic grid-type lead(II) complexes. Eur. J. Chem., 5, 1803 (1999).
20. R. Garcia-Zarracino, J. Ramos-Quinones, H. Hopfl. Self-assembly of dialkyltin(IV) moieties and aromatic dicarboxylates to complexes with a polymeric or a discrete trinuclear macrocyclic structure in the solid state and a mixture of fast interchanging cyclooligomeric structures in solution. Inorg. Chem., 42, 3835 (2003).
21. M.A. Paver, J.S. Joy, M.B. Hursthouse. A twenty-four membered mixed-metal macrocycle; Synthesis and structure of cyclo-[(3-Me-1,2-C6H3O2)2SbNa(THF)2]6. Chem. Commun., 2150 (2002).
22. U. Radhakrishnan, P.J. Stang. Synthesis and characterization of cationic iodonium macrocycles. J. Org. Chem., 68, 9209 (2003).
23. H. Schmidbaur, R. Nowak, O. Steigelmann, G. Mueller. p-Complexes of p-block elements: synthesis and structures of adducts of arsenic and antimony halides with alkylated benzenes. Chem. Ber., 123, 1221 (1990).
24. W.J. Vickaryous, R. Herges, D.W. Johnson. Arsenic-p interactions stabilize a self-assembled As2L3 supramolecular complex. Angew. Chem. Int. Ed., 43, 5831 (2004).
25. W.J. Vickaryous, E. Rather Healey, O.B. Berryman, D.W. Johnson. Synthesis and characterization of two isomeric, self-assembled arsenic-thiolate macrocycles. Inorg. Chem., 44, 9247 (2005).
26. DFT calculations with the AsCl3-benzene dimer found a 688 angle between As(III) lone pair and the arene ring to be optimal
27. Y. Liu, E.R.T. Tiekink. Supramolecular associations in binary antimony(III) dithiocarbamates: influence of ligand steric bulk, influence on coordination geometry, and competition with hydrogenbonding. CrystEngComm, 7, 20 (2005).
28. E.R.T. Tiekink. Aggregation patterns in the crystal structures of organometallic group XV 1,1-dithiolates: the influence of the lewis acidity of the central atom, metal-and ligand-bound steric bulk, and coordination potential of the 1,1-dithiolate ligands upon supramolecular architecture. CrystEng Comm, 8, 104 (2006).
29. D.B. Werz, T.H. Staeb, C. Benisch, B.J. Rausch, F. Rominger, R. Gleiter. Self-organization of chalcogen-containing cyclic alkynes and alkenes to yield columnar structures. Org. Lett., 4, 339 (2002).
30. H. Schmidbaur, W. Bublak, B. Huber, G. Muller. Arene adducts with weak interactions: Hexaethylbenzene-bis(tribromoarsane). Angew. Chem. Int. Ed. Engl., 26, 234 (1987).
31. A. Bondi. van der Waals volumes and radii. J. Phys. Chem., 68, 441 (1964).
32. C. Bleiholder, D.B. Werz, H. Koeppel, R. Gleiter. Theoretical investigations on chalcogen-chalcogen interactions: What makes these nonbonded interactions bonding? J. Am. Chem. Soc., 128, 2666 (2006).
33. R.E. Rosenfield, Jr., R. Parthasarathy, J.D. Dunitz. Directional preferences of nonbonded atomic contacts with divalent sulfur. 1. Electrophiles and nucleophiles. J. Am. Chem. Soc., 99, 4860 (1977).
34. N. Burford, J.A.C. Clyburne, J.A. Wiles, T.S. Cameron, K.N. Robertson. Tethered diarenes as four-site donors to SbCl3. Organometallics, 15, 361 (1996).
35. M. Filella, N. Belzile, Y.-W. Chen. Antimony in the environment: a review focused on natural waters. I. Occurrence. Earth-Science Reviews, 57, 125 (2002).
36. M. Krachler, J. Zheng, R. Koerner, C. Zdanowicz, D. Fisher, W. Shotyk. Increasing atmospheric antimony contamination in the northern hemisphere: snow and ice evidence from Devon Island, Arctic Canada. J. Environ. Monit., 7, 1169 (2005).
37. W. Shotyk, M. Krachler, B. Chen. Contamination of Canadian and European bottled waters with antimony from PET containers. J. Environ. Monit., 8, 288 (2006).
38. T. Gebel. Arsenic and antimony: comparative approach on mechanistic toxicology. Chem. Biol. Interact., 107, 131 (1997).
39. T. Gebel. Confounding variables in the environmental toxicology of arsenic. Toxicology, 144, 155 (2000).
40. P. Zhang, D.R. Bundle. Synthesis of three tethered trisaccharides to probe entropy contributions in carbohydrate-protein interactions. Isr. J. Chem., 40, 189 (2000).