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Volumn 9, Issue 14, 2007, Pages 2661-2664

Effective monoallylation of anilines catalyzed by supported KF

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL COMPOUND; ANILINE DERIVATIVE; DYES, REAGENTS, INDICATORS, MARKERS AND BUFFERS; INFUSORIAL EARTH; SOLVENT;

EID: 34547481476     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol070890o     Document Type: Article
Times cited : (39)

References (35)
  • 11
    • 0035840229 scopus 로고    scopus 로고
    • For a review, see:, and references therein
    • For a review, see: Salvatore, R. N.; Yoon, C. H.; Jung, K. W. Tetrahedron 2001, 57, 7785 and references therein.
    • (2001) Tetrahedron , vol.57 , pp. 7785
    • Salvatore, R.N.1    Yoon, C.H.2    Jung, K.W.3
  • 31
    • 34547430804 scopus 로고    scopus 로고
    • Typical experimental procedure: To a stirred solution of aniline derivative (1.20 mmol) and KF-Celite (1.25 mmol) in anhydrous acetonitrile (3.5 mL), the allyl halide (1.00 mmol) was added. Then, the mixture was continued for stirring at reflux up to completion of the reaction. The reaction mixture was filtered to remove catalyst and rinsed several times with dichloromethane, after the filtrate was evaporated under reduced pression. The product was purified, whenever necessary, by column chromatography on silica gel using various solvent systems as eluents.
    • Typical experimental procedure: To a stirred solution of aniline derivative (1.20 mmol) and KF-Celite (1.25 mmol) in anhydrous acetonitrile (3.5 mL), the allyl halide (1.00 mmol) was added. Then, the mixture was continued for stirring at reflux up to completion of the reaction. The reaction mixture was filtered to remove catalyst and rinsed several times with dichloromethane, after the filtrate was evaporated under reduced pression. The product was purified, whenever necessary, by column chromatography on silica gel using various solvent systems as eluents.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.