Investigation of synthetic Mg1.3V1.7O4 spinel with MgO inclusions: Case study of a spinel with an apparently occupied interstitial site

American Mineralogist

Volumn 92, Issue 7, 2007, Pages 1031-1037

  Uchida, Hinako ^a   Righter, Kevin ^b   Lavina, Barbara ^c,d   Nowell, Matthew M ^e   Wright, Stuart I ^e   Downs, Robert T ^a   Yang, Hexiong ^a  

^a University of Arizona   (United States)

^b NASA JOHNSON SPACE CENTER   (United States)

^c UNIVERSITY OF NEVADA   (United States)

^d UNIVERSITY OF CHICAGO   (United States)

^e EDAX TSL   (United States)

Author keywords

Crystal chemistry; Electron backscatter diffraction; Inclusion; Periclase; Spinel; XRD

Indexed keywords

BACKSCATTERING; CRYSTAL CHEMISTRY; ELECTRON DIFFRACTION; ELECTRON PROBE MICROANALYSIS; ELECTRONS; ENERGY DISPERSIVE SPECTROSCOPY; INCLUSIONS; MAGNESIA; MAGNESIUM METALLOGRAPHY; MATRIX ALGEBRA; OXIDE MINERALS; POSITIVE IONS; SINGLE CRYSTALS; X RAY DIFFRACTION;

BACKSCATTERED ELECTRONS; CHEMICAL DETERMINATION; ELECTRON BACK SCATTER DIFFRACTION; PERICLASE; SINGLE CRYSTAL X-RAY DIFFRACTION; SPINEL; X-RAY DIFFRACTION DATA; X-RAY ENERGY DISPERSIVE SPECTROSCOPY;

VANADIUM COMPOUNDS;

BACKSCATTER; CRYSTAL CHEMISTRY; CRYSTALLOGRAPHY; ELECTRON PROBE ANALYSIS; MAGNESIUM; PERICLASE; SPINEL; X-RAY DIFFRACTION;

EID: 34547453703     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2007.2445     Document Type: Article

References (45)

1. 1-xO. Acta Crystallographica A, 33, 268-276.
2. Bordes, N., Wang, L.M., Ewing, R.C., and Sickafus, K.E. (1995) Ion-beam induced disordering and onset of amorphization in spinet by defect accumulation. Journal of Materials Research, 10, 981-985.
3. Canil, D. (1999) Vanadium partitioning between orthopyroxene, spinel and silicate melt and the redox states of mantle source regions for primary magmas. Geochimica et Cosmochimica Acta, 63, 557-572.
4. 1-xO. Journal of Physics C: Solid State Physics, 8, 3267-3279.
5. Devanathan, R., Yu, N., Sickafus, K.E., and Nastasi, M. (1996) Structure and mechanical properties of irradiated magnesium aluminate spinet. Journal of Nuclear Materials, 232, 59-64.
6. Di Matteo, S., Jackeli, G., and Perkins, N.H. (2005) Orbital order in vanadium spinels. Physical Review B, 72, 020408.
7. Doyle, P.A. and Turner, P.S. (1968) Relativistic Hartree-Fock X-ray and electron scattering factors. Acta Crystallographica A, 24, 390-397.
8. Fleet, M.E. (1981) The structure of magnetite. Acta Crystallographica B, 37, 917-920.
9. Gibson, A., Haydock, R., and LaFemina, J.P. (1994) Stability of vacancy defects in MgO: The role of charge neutrality. Physical Review B, 50, 2582-2592.
10. 3) with spinel-type structure. Neues Jahrbuch für Mineralogie - Monatshefte, 217-226.
11. 1-xO): A review of its defect structure and physical properties. Reviews of Geophysics and Space Physics, 22, 37-46.
12. Hazen, R.M. and Yang, H. (1999) Effects of cation substitution and order-disorder on P-V-T equations of state of cubic spinels. American Mineralogist, 84, 1956-1960.
13. Hill, R.J., Craig, J.R., and Gibbs, G.V. (1979) Systematics of the spinel structure type. Physics and Chemistry of Minerals, 4, 317-339.
14. 4-δ. Journal of the Electrochemical Society, 144, L52-L53.
15. xO and the Earth's lower mantle. Science, 261, 923-924.
16. 4 ferrite spinel. Journal of Solid State Chemistry, 145, 276-282.
17. Kanno, R., Kondo, A., Yonemura, M., Gover, R., Kawamoto, Y., Tabuchi, M., Kamiyama, T., Izumi, F., Masquelier, C., and Rousse, G. (1999) The relationships between phases and structures of lithium manganese spinels. Journal of Power Sources, 81-82, 542-546.
18. Karki, B.B. and Khanduja, G. (2006) Vacancy defects in MgO at high pressure. American Mineralogist, 91, 511-516.
19. Karner, J.M., Sutton, S.R., Papike, J.J., Shearer, C.K., Jones, J.H., and Newville, M. (2006) Application of a new vanadium valence oxybarometer to basaltic glasses from the Earth, Moon, and Mars. American Mineralogist, 91, 270-277.
20. Lavina, B., Salviulo, G., and Della Giusta, A. (2002) Cation distribution and structure modelling of spinel solid solutions. Physics and Chemistry of Minerals, 29, 10-18.
21. 3+ on structural stability. Physics and Chemistry of Minerals, 30, 599-605.
22. Lavina, B., Reznitskii, L.Z., and Della Giusta, A. (2003b) A new Mg-Cr-V oxide mineral from Sludyanka (SW Lake Baikal, Russia) with a spinel-like defect structure. Joint Congress AIC-SILS, 50.
23. Lavina, B., Princivalle, F., and Della Giusta, A. (2005) Controlled time-temperature oxidation reaction in a synthetic Mg-hercynite. Physics and Chemistry of Minerals, 32, 83-88.
24. 2 during partial melting: Prospects, limitations, and implications. Geochimica et Cosmochimica Acta, 67, 3045-3064.
25. 4. Materials Science and Engineering B, 111, 82-89.
26. 4. Solid State Communications, 95, 217-221.
27. 2O4. Journal of Applied Physics, 81, 5289-5291.
28. Menegazzo, G., Carbonin, S., and Della Giusta, A. (1997) Cation and vacancy distribution in an artificially oxidized natural spinel. Mineralogical Magazine, 61, 411-421.
29. 4(A = Zn, Mg, or Cd). Physica B, 359-361, 1222-1224.
30. Nowell, M.M. and Wright, S.I. (2004) Phase differentiation via combined EBSD and XEDS. Journal of Microscopy, 213, 296-305.
31. Papike, J.J., Karner, J.M., and Shearer, C.K. (2004) Comparative planetary mineralogy: V/(Cr + Al) systematics in chromite as an indicator of relative oxygen fagacity. American Mineralogist, 89, 1557-1560.
32. Pyatikop, P.D. (1971) Microstructure and mineral composition of magnesium-aluminum spinel specimens synthesized under conditions of periclase excess and addition of chromite ore. Konstitutsiya i Svoystva Mineralov, 5, 115-118.
33. 3, a metal-deficient spinel. Journal of Solid State Chemistry, 2, 203-208.
34. Roth, W.L. (1960) Defects in the crystal and magnetic structures of ferrous oxide. Acta Crystallographica, 13, 140-149.
35. Shannon, R.D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica A, 32, 751-767.
36. Sheldrick, G.M. (1997) SHELX97 and SHELXS97. University of Göttingen, Germany.
37. Sheldrick, G.M. (2005) SADABS v.2. 10. University of Göttingen, Germany.
38. Somogyvári, Z., Sváb, E., Mészáros, G., Krezhov, K., Nedkov, I., Sajó, I., and Bourée, F. (2002) Vacancy ordering in nanosized maghemite from neutron and X-ray powder diffraction. Applied Physics A, 74, S1077-S1079.
39. 4-δ. Journal of Power Sources, 68, 641-645.
40. Sutton, S.R., Karner, J., Papike, J., Delaney, J.S., Shearer, C., Newville, M., Eng, P., Rivers, M., and Dyar, M.D. (2005) Vanadium K edge XANES of synthetic and natural basaltic glasses and application to microscale oxygen barometry. Geochimica et Cosmochimica Acta, 69, 2333-2348.
41. 1-xO solid solution. Journal of Solid State Chemistry, 177, 3301-3309.
42. 1-xO. Journal of Solid State Chemistry, 140, 38-45.
43. 1-xO. Journal of Solid State Chemistry, 117, 398-406.
44. 1-xO. Physics and Chemistry of Minerals, 24, 24-38.
45. Zhang, J. (2000) Effect of pressure on the thermal expansion of MgO up to 8.2 GPa. Physics and Chemistry of Minerals, 27, 145-148.