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The "packing fraction" is defined as the product of solvent density p (mot/L) and the molar volume Vo of the solvent atoms, which is assumed to be given as I'o = ]/b.~rtPN,\, with d being the Lennard-Jones diameter and N,\ Avosadro's number. Lennard-Jones diameters: He, 2.576 A; Ne, 2.789 A; Ar, 3.418 A; Kr, 3.6 A; I, 4.982 A.
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85033065893
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note
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2) and sometimes to be a distance (m), we denote the Lennard-Jones diameter by d. The following parameters have been used: Lennard-Jones diameters: He, 2.576 A; Ne, 2.789 A; Ar, 3.418 A; Kr, 3.6 A; 12, 4.982 A; H-hexane, 5.909 A.
-
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116
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85033044859
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note
-
The followins parameters have been used: Lennard-Jones diameters: He, 2.576 A; Ne, 2.789 A; Ar, 3.418 A; Kr, 3.6 A: K 4.982 A; ;i-hexane, 5.909 A. Polarizabilities (lO"30 m3): He, 0.2050; Ne, 0.3956; Ar, 1.6411; Kr, 2.4844; hexane, 11.78. lonization potentials (eV): He, 24.587; Ne, 21.564; Ar, 15.795; Kr, 13.999; hexane, 10.18.
-
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85033058189
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We assume a laser pulse energy of 10 ft], or 3 x 10° photons per pulse at 620 nm, a beam diameter of 2 mm. and an optical path length of 6 mm. The iodine vapor pressure at room temperature is about 0.3 mbar, corresponding to an iodine concentration of 1.4 x 10~5 mol L~'. For an extinction coefficient of 78 L mol"1 cm"1, Lambert-Beer's law gives a total absorption of the laser pulse of 0.15%. This corresponds to 4.5 x 10'° photoexcited iodine molecules or, correspondingly, a concentration of 4 x 10-' mol L"1.
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118
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85033059785
-
-
note
-
Recombination amplitudes larger than one do not correspond to quantum yields for geminate recombination larger than one. At 310 nm the A/A' state extinction coefficient (ss\2 000 L mol"' cm"1) is significantly larger than that of the B state.
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