Novel analytical method for the crosslinking process: Infrared thermographic analysis of the thermally latent cationic polymerization of a spiroorthoester and a bifunctional oxetane for the construction of a low-shrinkage curing system

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 45, Issue 13, 2007, Pages 2820-2826

  Ochiai, Bungo ^a   Nagasawa, Tomomi ^a,c   Asano, Yasuhiro ^a   Nagai, Daisuke ^a,d   Sudo, Atsushi ^b   Endo, Takeshi ^a,b  

^a YAMAGATA UNIVERSITY   (Japan)

^b KINKI UNIVERSITY   (Japan)

^c YOKOHAMA RUBBER CO LTD   (Japan)

^d GUNMA UNIVERSITY   (Japan)

Author keywords

Cationic polymerization; Copolymerization; Crosslinking; Infrared spectroscopy; Latent initiators; Ring opening polymerization

Indexed keywords

CATIONIC POLYMERIZATION; COPOLYMERIZATION; CROSSLINKING; INFRARED SPECTROSCOPY; RING OPENING POLYMERIZATION; THERMOGRAPHY (TEMPERATURE MEASUREMENT);

BENZYL TETRAHYDROTHIOPHENIUM HEXAFLUOROANTIMONATE (BTHT); BIFUNCTIONAL OXETANE; INFRARED THERMOGRAPHIC ANALYSIS; LATENT INITIATORS;

POLYESTERS;

EID: 34547341005     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.22038     Document Type: Article

References (38)

1. Chikaoka, S.; Takata, T.; Endo, T. Macromolecules 1992, 25, 25.
2. Brady, R. F., Jr. J Macromol Sci Rev Macromol Chem Phys 1992, 32, 135.
3. Endo, T.; Sanda, F. Polym Mater Encyclopedia 1996, 10Q-S, 7554.
4. Takata, T.; Endo, T. Prog Polym Sci 1993, 18, 839.
5. Chikaoka, S.; Takata, T.; Endo, T. Macromolecules 1992, 25, 625.
6. Igarashi, M.; Takata, T.; Endo, T. Macromolecules 1994, 27, 2628.
7. Kume, M.; Hirano, A.; Ochiai, B.; Endo, T. J Polym Sci Part A: Polym Chem 2006, 44, 3666.
8. Nagasawa, T.; Ochiai, B.; Endo, T. J Polym Sci Part A: Polym Chem 2006, 44, 5519.
9. Nagasawa, T.; Ochiai, B.; Endo, T. J Polym Sci Part A: Polym Chem 2007, 45, 1388-1393.
10. Uno, H.; Endo, T. J Polym Sci Polym Lett Ed 1985, 23, 359.
11. Hamazu, F.; Akashi, S.; Koizumi, T.; Takata, T.; Endo, T. J Polym Sci Part A: Polym Chem 1991, 29, 1675.
12. Sasaki, H.; Crivello, J. V. J Macromol Sci Pure Appl Chem 1992, 29, 915.
13. McGowen, J. A.; Mathias, L. J. Polym Compos 1997, 18, 348.
14. Endo, T.; Sanda, F. Macromol Symp 1996, 107, 237.
15. Crivello, J. V. J Polym Sci Part A: Polym Chem 1999, 37, 4241.
16. Hino, T.; Endo, T. J Polym Sci Part A: Polym Chem 2004, 42, 5407.
17. Hino, T.; Endo, T. Macromolecules 2003, 36, 5902.
18. Miller, M. D.; Holder, A. J.; Guthrie, J. R.; Pinzino, C. S.; Chappelow, C. C.; Eick, J. D. J Polym Sci Part A: Polym Chem 2005, 43, 5962.
19. Morikawa, H.; Sudo, A.; Nishida, H.; Endo, T. J Appl Polym Sci 2005, 96, 372.
20. Crivello, J. V.; Falk, B. J Polym Sci Part A: Polym Chem 2003, 41, 579.
21. Crivello, J. V.; Jang, M. J Polym Sci Part A: Polym Chem 2003, 41, 3056.
22. Crivello, J. V.; Falk, B.; Zonca, M. R. J Appl Polym Sci 2004, 92, 3303.
23. Lin, P.; Falk, B.; Jang, M.; Crivello, J. V. Macromol Chem Phys 2004, 205, 2040.
24. Bulut, U.; Crivello, J. V. Macromolecules 2005, 38, 3584.
25. Crivello, J. V. Polymer 2005, 46, 12109.
26. Bulut, U.; Crivello, J. V. J Polym Sci Part A: Polym Chem 2005, 43, 3205.
27. Crivello, J. V. J Polym Sci Part A: Polym Chem 2006, 44, 3036.
28. Georgiades, G.; Self, V. A.; Sermon, P. A. Angew Chem Int Ed Engl 1987, 26, 1042.
29. Pawlicki, P. C.; Schmitz, R. A. Chem Eng Prog 1987, 83, 40.
30. Lobban, L.; Philippou, G.; Luss, D. J Phys Chem 1989, 93, 733.
31. Taylor, S. J.; Morken, J. P. Science 1998, 280, 267.
32. Holzwarth, A.; Schmidt, H. W.; Maier, W. F. Angew Chem Int Ed 1998, 37, 2644.
33. Reetz, M. T. Angew Chem Int Ed 2000, 39, 1236.
34. Biniwale, R. B.; Yamashiro, H.; Ichikawa, M. Catal Lett 2005, 102, 23.
35. Johansson, K. J.; Andreae, M. R. M.; Berkessel, A.; Davis, A. P. Tetrahedron Lett 2005, 46, 3923.
36. Kong, J.; White, C. A.; Krylov, A. L.; Sherrill, C. D.; Adamson, R. D.; Furlani, T. R.; Lee, M. S.; Lee, A. M.; Gwaltney, S. R.; Adams, T. R.; Oschenfeld, C.; Gilbert, A. T. B.; Kedziora, G. S.; Rassolov, V. A.; Maurice, D. R.; Nair, N.; Shao, Y.; Besley, N. A.; Maslen, P. E.; Dombroski, J. P.; Daschel, H.; Zhang, W.; Korambath, P. P.; Baker, J.; Byrd, E. F. C.; Van Voorhis, T.; Oumi, M.; Hirata, S.; Hsu, C.-P.; Ishikawa, N.; Florian, J.; Warshel, A.; Johnson, B. G.; Gill, P. M. W.; Head-Gordon, M.; Pople, J. A. J Comput Chem 2000, 21, 1532.
37. Hehre, W. J. A Guide to Molecular Mechanics and Quantum Chemical Calculations; Wavefunction: Irvine, CA, 2003.
38. This computational evaluation deals only with the internal energy changes and is not appropriate for the presumption of copolymerization abilities unless entropy changes are taken into account.