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Volumn 349, Issue 4-5, 2007, Pages 680-684

Suppression of β-hydride elimination in the intramolecular hydrocarboxylation of alkynes leading to the formation of lactones

Author keywords

Asymmetric catalysis; C C bond formation; Cross coupling; Enzyme catalysis; Homogeneous catalysis

Indexed keywords


EID: 34547233221     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200600507     Document Type: Article
Times cited : (29)

References (63)
  • 17
  • 25
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    • a) B. M. Trost, Science 1991, 254, 1471-1477;
    • (1991) Science , vol.254 , pp. 1471-1477
    • Trost, B.M.1
  • 28
    • 34547173344 scopus 로고    scopus 로고
    • The addition of carbon, amine and alcohol nucleophiles across an activated C-C bond is referred to as hydrocarbonation, hydroamination and hydroalkoxylation, respectively
    • The addition of carbon, amine and alcohol nucleophiles across an activated C-C bond is referred to as hydrocarbonation, hydroamination and hydroalkoxylation, respectively.
  • 55
    • 33646244777 scopus 로고    scopus 로고
    • we have also reported the intramolecular hydroamination of alkynes in the absence of carboxylic acids, see
    • m) N. T. Patil, Z. Huo, G. B. Bajracharya, Y. Yamamoto, J. Org. Chem. 2006, 71, 3612-3614; we have also reported the intramolecular hydroamination of alkynes in the absence of carboxylic acids, see:
    • (2006) J. Org. Chem , vol.71 , pp. 3612-3614
    • Patil, N.T.1    Huo, Z.2    Bajracharya, G.B.3    Yamamoto, Y.4
  • 57
    • 29244491425 scopus 로고    scopus 로고
    • N. T. Patil, N. K. Pahadi, Y. Yamamoto, Can. J. Chem. 2005, 83, 569-573; for a similar report published by other laboratories, see: for intermolecular reactions
    • a) N. T. Patil, N. K. Pahadi, Y. Yamamoto, Can. J. Chem. 2005, 83, 569-573; for a similar report published by other laboratories, see: for intermolecular reactions
  • 60
    • 0000793787 scopus 로고    scopus 로고
    • For the formation of 1,3-dienes from π-allylpalladium species, see: a
    • For the formation of 1,3-dienes from π-allylpalladium species, see: a) J. M. Takacs, E. C. Lawson, F. Clement, J. Am. Chem. Soc. 1997, 117, 5956-5957;
    • (1997) J. Am. Chem. Soc , vol.117 , pp. 5956-5957
    • Takacs, J.M.1    Lawson, E.C.2    Clement, F.3
  • 62
    • 34547189380 scopus 로고    scopus 로고
    • Other metal catalysts include Pt(PPh3)4, Ni(PPh3)4, RhCl(PPh3)4, RuCl 2(PPh3)3, PdCl2(PPh 3)2 were screened. Only Pd(PPh3)4 was found to be effective
    • 4 was found to be effective.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.