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Examples of oxidative transformations of N-aryl sulfonamide: (a) Akai, S.; Kawashita, N.; Morita, N.; Nakamura, Y.; Iio, K.; Kita, Y. Heterocycles 2002, 58, 75.
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Examples of oxidative transformations of N-aryl sulfonamide: (a) Akai, S.; Kawashita, N.; Morita, N.; Nakamura, Y.; Iio, K.; Kita, Y. Heterocycles 2002, 58, 75.
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0035861606
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Obtained in high yield by treatment of aniline with mesyl chloride and pyridine: Wang, Y.; Guziec, F.-S. J. Org Chem. 2001, 66, 8293.
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Obtained in high yield by treatment of aniline with mesyl chloride and pyridine: Wang, Y.; Guziec, F.-S. J. Org Chem. 2001, 66, 8293.
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38
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34547171604
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a ca. 9.3, nucleophilicity ca. -4.2).
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a ca. 9.3, nucleophilicity ca. -4.2).
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39
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34547151567
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Excess of thiophen is easily removed at the end of the reaction and could be recycled
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Excess of thiophen is easily removed at the end of the reaction and could be recycled.
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40
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34547184445
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An additional side product occasionally detected in crude reaction mixtures 5-10, remains as of yet unidentified
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An additional side product occasionally detected in crude reaction mixtures (5-10%) remains as of yet unidentified.
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41
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0442265978
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