The solvent extraction of iron(III) from chloride solutions by N,N′-tetrasubstituted malonamides: Structure-activity relationships

Solvent Extraction and Ion Exchange

Volumn 25, Issue 4, 2007, Pages 463-484

  Costa, M C ^a   Peczek I ^b   Sadowski, Z ^b   Natu, S ^c   Paiva, A P ^c  

^a UNIVERSITY OF ALGARVE   (Portugal)

^b WROCLAW UNIVERSITY OF TECHNOLOGY   (Poland)

^c UNIVERSITY OF LISBON   (Portugal)

Author keywords

Hydrochloric acid; Iron(III) extraction; Malonamide derivatives

Indexed keywords

DERIVATIVES; HYDROCHLORIC ACID; IRON; STRUCTURE (COMPOSITION);

ALKYL CHAIN; TETRASUBSTITUTED MALONAMIDES;

SOLVENT EXTRACTION;

DERIVATIVES; HYDROCHLORIC ACID; IRON; SOLVENT EXTRACTION; STRUCTURE (COMPOSITION);

EID: 34447315540     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366290701415952     Document Type: Article

References (32)

1. Musikas, C. (1987) Solvent extraction for the chemical separation of the 5f elements. Inorg. Chim. Acta, 140:1, pp. 197-206.
2. Musikas, C. and Hubert, H. (1987) Extraction by N,N′-tetralkylmalonamides II. Extraction of metal ions. Solvent Extr. Ion Exch., 5:5, pp. 877-893.
3. Musikas, C., Schulz, W. W. and Liljenzin, J. O. (2004) Solvent Extraction-Principles and Practice, pp. 507-557. Marcel Dekker Inc, New York, Basel
4. Chan, G. Y.S., Drew, M. G.B. and Hudson, M. J. (1997) Solvent extraction of metal ions from nitric acid solutions using N,N ′-substituted malonamides. Experimental and crystallographic evidence for two mechanisms of extraction, metal complexation and ion-pair formation. J. Chem. Soc. Dalton Trans., 4, pp. 649-660.
5. Spjuth, L., Liljenzin, J. O. and Skalberg, M. (1997) Extraction of actinides and lanthanides from nitric acid solution by malonamides. Radiochim. Acta, 78, pp. 39-46.
6. Mowafi, E. A. and Aly, H. F. (2002) Extraction behaviours of Nd (III), Eu (III), La (III), Am (III) and U (VI) with some substituted malonamides from nitric acid medium. Solvent Ext. Ion Exch., 20:2, pp. 177-194.
7. Tian, Q. and Hughes, A. (1994) Synthesis and characterization of diamide extractants for the extraction of neodymium. Hydrometallurgy, 36, pp. 79-94.
8. Spjuth, L., Liljenzin, J. O. and Hudson, M. J. (2000) Comparison of extraction behaviour and basicity of some substituted malonamides. Solvent Extr. Ion Exch., 18:1, pp. 1-23.
9. Fritz, J. S. and Orf, G. M. (1975) Extraction of metal ions with N,N-disubstituted amides. Anal. Chem., 47:12, pp. 2043-2045.
10. Laskorin, B. N., Yakshim, V. V. and Filipov, E. A. (1978) Extraction of uranium and transuranium elements by amides of carboxylic acids. Radiokhimiya, 20:4, pp. 511-515.
11. Gasparini, G. M. and Grossi, G. (1980) Application of N,N-dialkyl aliphatic amides in the separation of some actinides. Sep. Sci. Technol., 15:4, pp. 825-844.
12. Pohlandt, C. and Fritz, J. S. (1979) Extraction of metal ions from chloride solution with N,N-dioctylacetamide. Talanta, 26, pp. 395-410.
13. Siddall, T. H. (1961) Applications of amides as extractants.
14. Cuillerdier, C., Musikas, C. and Hoel, P. (1991) Malonamides as new extractants for nuclear waste solutions. Sep. Sci. Technol., 26:9, p. 1229.
15. Mowafy, E. A. and Aly, H. F. (2006) Extraction behaviors of trivalent lanthanides from nitrate medium by selected substituted malonamides. Solvent Extr. Ion Exch., 24, pp. 677-692.
16. Costa, M. C., Carvalho, A., Uryga, A. and Paiva, A. P. (2003) Solvent extraction of iron (III) from hydrochloric acid solutions using N,N′-dimethyl-N,N′-diphenylmalonamide and N,N′-dimethyl-N,N′-diphenyltetradecylmalonamide. Solvent Extr. Ion Exch, 21:5, pp. 653-686.
17. Paiva, A. P. and Costa, M. C. (2005) Application of N,N′-tetrasubstituted malonamides to the recovery of iron(III) from chloride solutions. Hydrometallurgy, 77:1, pp. 103-108.
18. Costa, M. C., Fernandes, C. E., Hudson, M. J. and Iveson, P. B. (2001) Proceedings of the International Solvent Extraction Conference, ISEC'99 Barcelona, Spain Society of Chemical Industry, pp. 271-275. Society of Chemical Industry, London
19. Costa, M. C. and Paiva, A. P. (2002) Solvent extraction of iron (III) from hydrochloric acid solutions using N,N′-dimethyl-N,N′-diphenylmalonamide. Proceedings of the International Solvent Extraction Conference, ISEC'02 Cape Town, South Africa Chris van Rensburg Publications Ltd, pp. 371-376.
20. Costa, M. C., Martins, M. and Paiva, A. P. (2004) Solvent extraction of iron (III) from acidic chloride media using N,N′-dimethy-N,N′-dibutylmalonamide. Sep. Sci. Technol., 39:15, pp. 3573-3599.
21. Fritz, J. S. (1953) Differential titration of amines. Analytical Chemistry, 25:3, pp. 407-411.
22. Lefrançois, L., Hébrant, M. and Tondre, C. (1999) Z,E isomerism and hindered rotations in malonamides: An NMR study of N,N′-dimethyl-N,N′-dibutyl-2-tetradecylpropane-1,3-diamide. J. Chem. Soc., Perkin Trans. 2, 2, pp. 1149-1158.
23. Erlinger, C., Belloni, L., Zemb, T. and Madic, C. (1999) Attractive interactions between reverse aggregates and phase separation in concentrated malonamide extractant solutions. Langmuir, 15, pp. 2290-2300.
24. Abécassis, B., Testard, F. and Zemb, T. (2003) Effect of n-octanol on the structure at the supramolecular scale of concentrated dimethyldioctylhexylethoxymalonamide extractant solutions. Langmuir, 19, pp. 6638-6644.
25. Erlinger, C., Gazeau, D. and Zemb, T. (1998) Effect of nitric acid extraction on phase behavior, microstructure and interactions between primary aggregates in the system dimethyldibutyltetradecylmalonamide. (DMDBTDMA)/n-dodecane/water: A phase analysis and small angle X-ray scattering (SAXS) characterization study. Solvent Extr. Ion Exch., 16:3, pp. 707-738.
26. Martinet, L., Berthon, L., Peineau, N., Madic, C. and Zemb, T. (2002) Aggregation of the solvates formed in liquid-liquid extraction of metallic cations by malonamides: Study of the Nd(NO3)3/H2O/LiNO3/ DMDBTDMA/dodecane system. Proceedings of the International Solvent Extraction Conference, ISEC'02 Cape Town, South Africa Chris van Rensburg Publications Ltd, pp. 1161-1167. Chris van Rensburg Publications Ltd, Melville
27. Charbonnel, M. C. and Musikas, C. (1986) Extraction of actinides and fission product ions by non-chelating N,N′-Tetraalkyldiamides. Proceedings of the International Solvent Extraction Conference, ISEC86 Munich, Germanypp. 1686-1693.
28. Nakamura, T. and Miyake, C. (1995) Extraction of lanthanide(III) and uranyl(VI) from nitric acid solution by N,N′-dimethyl-N,N′-dibutylmalonamide. Solvent Extr. Ion Exch., 13:2, pp. 235-273.
29. Nigond, L. (1992) Extracting properties of N,N,N′,N′-tetraalkyl-2-alkylpropane-1,3-diamides. University of Clermont-Ferrand II, France
30. Nakamoto, K. (1986) Infrared and Raman spectra of inorganic and coordination compounds, p. 102. John Wiley and Sons Inc, New York
31. Gamlen, G. A. and Jordan, D. O. (1953) A spectrophotometric study of the iron(III) chloro-complexes. J. Chem. Soc., pp. 1435-1443.
32. 3+ from chloride solution by D2EHPA in kerosene. Hydrometallurgy, 50, pp. 153-168.