Low-lying excited states and primary photoproducts of [Os 3(CO)10-(s-cis-L)] (L = cyclohexa-1,3-diene, buta-1,3-diene)] clusters studied by picosecond time-resolved UV/Vis and IR spectroscopy and by density functional theory

Chemistry - A European Journal

Volumn 10, Issue 14, 2004, Pages 3451-3460

  Vergeer, Frank W ^a   Matousek, Pavel ^b   Towrie, Michael ^b   Costa, Paulo J ^c,d   Calhorda, Maria J ^c,d   Hartl, František ^a  

^a UNIVERSITY OF AMSTERDAM   (Netherlands)

^b Harwell Science and Innovation Campus   (United Kingdom)

^c INSTITUTO DE TECNOLOGIA QUÍMICA E BIOLÓGICA   (Portugal)

^d UNIVERSITY OF LISBON   (Portugal)

Author keywords

Cluster compounds; Density functional calculations; Diene ligands; IR spectroscopy; Photochemistry

Indexed keywords

CARRIER CONCENTRATION; CHEMICAL BONDS; INFRARED SPECTROSCOPY; ISOMERS; ULTRAVIOLET SPECTROSCOPY;

ELECTRON DEFICIENCY; PHOTOPRODUCTS;

INFRARED RADIATION;

1,3 BUTADIENE DERIVATIVE; ALKENE DERIVATIVE; CARBON MONOXIDE; COORDINATION COMPOUND; CYCLOHEXA 1,3 DIENE DERIVATIVE; HEXANE; LIGAND; OSMIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; DEGRADATION; DENSITY; DENSITY FUNCTIONAL THEORY; ELECTRON; ENERGY; INFRARED SPECTROSCOPY; ISOMER; PHOTOCHEMISTRY; ULTRAVIOLET SPECTROSCOPY;

EID: 3442893915     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400086     Document Type: Article

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