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Volumn , Issue 16, 2007, Pages 2274-2287

Synthesis, coordination and catalytic utility of novel phosphanyl- ferrocenecarboxylic ligands combining planar and central chirality

Author keywords

Allylic alkylation; Asymmetric catalysis; Ferrocene ligands; Palladium; Rhodium

Indexed keywords

ALKYLATION; ALUMINA; ALUMINUM OXIDE; CHELATION; CHLORINE COMPOUNDS; IRON COMPOUNDS; LIGANDS; ORGANOMETALLICS; PALLADIUM COMPOUNDS; RHODIUM COMPOUNDS; SILICA GEL; SULFUR COMPOUNDS;

EID: 34347400430     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200700093     Document Type: Article
Times cited : (28)

References (69)
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    • This is best indicated by the ring puckering parameters for the cyclohexyl rings: C(31-36, Q, 0.579(4) Å, θ, 176.5(4)°; C(41-46, Q, 0.583(4) Å, θ, 0.4(4)°; C(51-56, Q, 0.558(4) Å, θ, 5.2(4)°. Note: An ideal envelope requires θ, 0 or 180°. For reference, see: D. Cremer, J. A. Pople, J. Am. Chem. Soc. 1975, 97, 1354-1358
    • This is best indicated by the ring puckering parameters for the cyclohexyl rings: C(31-36): Q = 0.579(4) Å, θ = 176.5(4)°; C(41-46): Q = 0.583(4) Å, θ = 0.4(4)°; C(51-56): Q = 0.558(4) Å, θ = 5.2(4)°. Note: An ideal envelope requires θ = 0 or 180°. For reference, see: D. Cremer, J. A. Pople, J. Am. Chem. Soc. 1975, 97, 1354-1358.
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    • The bond lengths were retrieved from the Cambridge Structural Database (version 5.27 of November 2005 with updates from January, May, and August 2006).
    • The bond lengths were retrieved from the Cambridge Structural Database (version 5.27 of November 2005 with updates from January, May, and August 2006).
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