Substrate-controlled asymmetric total synthesis of (+)-microcladallene B with a bromination strategy based on a nucleophile-assisting leaving group

Angewandte Chemie - International Edition

Volumn 46, Issue 25, 2007, Pages 4726-4728

  Park, Janghyun ^a   Kim, Byungsook ^a   Kim, Hyoungsu ^a   Kim, Sanghee ^a   Kim, Deukjoon ^a  

^a Seoul National University   (South Korea)

Author keywords

Bromination; Dianion alkylation; Natural products; Nucleophile assisting leaving groups; Total synthesis

Indexed keywords

BROMINATION; CHEMOSELECTIVE SYNTHESIS; DIANION ALKYLATION; NATURAL PRODUCTS; NUCLEOPHILE ASSISTING LEAVING GROUPS; TOTAL SYNTHESIS;

ALKYLATION; BROMINE; NUCLEOPHILES; STEREOSELECTIVITY; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

OLEFINS;

BROMINE; MICROCLADALLENE B; SESQUITERPENE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; ENZYME SPECIFICITY; STEREOISOMERISM; SYNTHESIS;

BROMINE; CATALYSIS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; SESQUITERPENES; STEREOISOMERISM; SUBSTRATE SPECIFICITY;

EID: 34347223272     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200700854     Document Type: Article

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