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Volumn 28, Issue 37, 1987, Pages 4303-4306

Synthesis of (±)-prepinnaterpene, a bromoditerpene from the red alga Laurencia Pinnata Yamada

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[No Author keywords available]

Indexed keywords


EID: 0000519465     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(00)96491-8     Document Type: Article
Times cited : (69)

References (14)
  • 8
    • 84919145584 scopus 로고    scopus 로고
    • The numbering of all synthetic perhydroindans refers to that of irieols.
  • 9
    • 84919145583 scopus 로고    scopus 로고
    • 2, room temp, 1.5 h; v) NaOMe, MeOH, room temp, 21 h. NOE: 10-H → 5α-H, 6α-H, 8α-H for i: 10-H → 2α-H, 6α-H, 8α-H for ii.
  • 11
    • 84919145581 scopus 로고    scopus 로고
    • The same bromination of the mesylate of 13 at 80 °C for 16 h gave a 1:4:3 mixture of 14, 15, and 13. This result suggested that 14 would be formed by double inversion of 13 via 15, and olefin 16 would be derived from 15.
  • 14
    • 84919145580 scopus 로고    scopus 로고
    • 3P, 100°C, 7 h; v) MeI, BuLi, room temp, 15 min; vi) LDA, THF, room temp, 2 h.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.