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Volumn 46, Issue 25, 2007, Pages 4775-4779

Stepwise synthesis and coordination compound of an inorganic cryptand

Author keywords

Cage compounds; Cryptands; Phosphorus; Silicon; Weakly coordinating anions

Indexed keywords

LIGANDS; LITHIUM COMPOUNDS; PHOSPHORUS; SILICON; SYNTHESIS (CHEMICAL);

EID: 34347209913     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200604673     Document Type: Article
Times cited : (29)

References (38)
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    • STOE-IPDS2, MoKα radiation, graphite monochromator, λ, 0.71073 Å. The structures were solved by direct methods and refined by full-matrix least-squares techniques against F2 (SHELX-97 program package, G. Sheldrick, Universität Göttingen, Germany 1997, Molecular diagrams were prepared using the SCHAKAL-97 program (SCHAKAL-97, E. Keller, Universität Freiburg, Germany 1997, 3: C36H88Li2N4O 2P2Si4, Mr, 797.3 gmol -1, 2.0 x 0.2 x 0.2 mm3, a, 1915.9(4, b, 1317.4(3, c, 2017.4.5(3) pm, β, 106.11(3)°, V, 5065.5(17) × 106 pm3, monoclinic, space group P21/n, Z, 4, ρcalcd, 1.045 gcm -3, μMoKα, 0.211 mm-1, T, 190 K, 2Θmax
    • -3. CCDC-627532 (3), -627533 (4), and -627534 (5) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_ request/cif.
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    • An inversion center can be excluded because of the noncentrosymmetric molecular structures of the anions and the cations, and because of the almost parallel orientation of the two [Al(ORF)4, anions with one tetrahedron corner along the crystallographic c axis
    • - anions with one tetrahedron corner along the crystallographic c axis.
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    • G. Becker, H.-M. Hartmann, W. Schwarz, Z. Anorg. Allg. Chem. 1989, 577, 9-22;
    • b) G. Becker, H.-M. Hartmann, W. Schwarz, Z. Anorg. Allg. Chem. 1989, 577, 9-22;
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    • All calculations were carried out with the TURBOMOLE program system (a); DFT calculations were performed with the B-P86 functional (b, c) within the RI-J approximation (d), using def2-TZVP basis sets (e) and appropriate RI-J auxiliary basis sets (f). a) TURBOMOLE, Version 5-8, Universität Karlsruhe, 2005;
    • All calculations were carried out with the TURBOMOLE program system (a); DFT calculations were performed with the B-P86 functional (b, c) within the RI-J approximation (d), using def2-TZVP basis sets (e) and appropriate RI-J auxiliary basis sets (f). a) TURBOMOLE, Version 5-8, Universität Karlsruhe, 2005;


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.