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Volumn 2, Issue 2, 2007, Pages 290-300

Boomerang-type substitution reaction: Reactivity of fullerene epoxides and a halofullerenol

Author keywords

Epoxides; Fullerenes; Halohydrins; Peroxides; Single electron transfer

Indexed keywords


EID: 34250868362     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.200600268     Document Type: Article
Times cited : (11)

References (52)
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    • Angew. Chem. Int. Ed. 2006, 45, 5337.
    • (2006) Chem. Int. Ed , vol.45 , pp. 5337
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    • for a review on the chirality of fullerencs, see: b
    • for a review on the chirality of fullerencs, see: b) C. Thilgen, F. Diederich, Top. Curr. Chem. 1999, 199,135.
    • (1999) Top. Curr. Chem , vol.199 , pp. 135
    • Thilgen, C.1    Diederich, F.2
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    • 34250834743 scopus 로고    scopus 로고
    • Crystal data for 6 (C78H42Cl 4O10, Mr= 1280.92, triclinic, P1, a= 14.204(3, b=14.679(3, c=14.867(3) Å, α=90.40(3, β=97.88(3, γ=114.35(3)°, V=2774.4(10)Å3, T=143(2) K. Z=2, ρcaled= 1.533 Mgm-3, graphite-monochromated Mo Ka radiation, λ= 0.71073 Å, crystal size 0.50×0.35×0.10 mm3. Data collected on a Rigaku RAXIS RAPID IP diffractometer, 9285 unique reflections (Rint=0.0577, Refinement on F2, final residuals R1=0.0880 for 4441 reflections with I> 2o1, wR2=0.2336 for all data. CCDC-289585 contains the supplementary crystallographic data for this compound
    • 2, final residuals R1=0.0880 for 4441 reflections with I> 2o(1), wR2=0.2336 for all data. CCDC-289585 contains the supplementary crystallographic data for this compound.
  • 33
    • 34250853821 scopus 로고    scopus 로고
    • Crystal data for 8a (C77H36Cl 2O9S2, Mr=1240.08, monoclinic, P21/ n, a=14.620(3, b=13.968(3, c=26.487(5) Å, α=90, β=101.70(3, γ=90°, V=5296.6(18) Å3, T=143(2) K, Z=4, ρcaled=1.555 Mgm-3, graphite-monochromated Mo Ka radiation, λ, 0.71073 Å, crystal size 0.50×0.20×0.14 mm3. Data collected on a Rigaku RAXIS RAPID IP diffractometer, 9340 unique reflections (Rint, 0.0516, Refinement on F2, final residuals R1 =0.0457 for 5093 reflections with I > σI, wR2, 0.0916 for all data. CCDC-289586 contains the supplementary crystallographic data for this compound
    • 2, final residuals R1 =0.0457 for 5093 reflections with I > σ(I), wR2 = 0.0916 for all data. CCDC-289586 contains the supplementary crystallographic data for this compound.
  • 34
    • 34250882467 scopus 로고    scopus 로고
    • Crystal data for 10 (C80H48Br 2O11, Mr= 1345.00, monoclinic, P21/c, a=22.264(5, b=13.809(3, c=18.716(4) Å, α=90, β=100.64(3, γ=90°, V=5655(2) Å3 T=143(2) K, Z=4, ρcaled=1.555 Mgm-3, graphite-monochromated Mo Ka radiation. λ=0.71073 Å, crystal size 0.50×0.25×0.08 mm3. Data collected on a Rigaku RAXIS RAPID IP diffractometer. 9505 unique reflections (Rint=0.0813, Refinement on F2, final residuals R1=0.0783 for 3903 reflections with 1> 2σ(I, wR2, 0.1629 for all data. CCDC-289585 (6, 289586 (8a, and -290715 (10) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB12 1EZ, UK (fax:, 44)1223-366-033; e-mail: deposit@ccdc.cam.ac.uk) or at
    • 2, final residuals R1=0.0783 for 3903 reflections with 1> 2σ(I), wR2 = 0.1629 for all data. CCDC-289585 (6), -289586 (8a), and -290715 (10) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB12 1EZ, UK (fax: (+44)1223-366-033; e-mail: deposit@ccdc.cam.ac.uk) or at www.ccdc.cam.ac.uk/data_request/cif.
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    • 33646503908 scopus 로고    scopus 로고
    • For a recent review, see: a
    • For a recent review, see: a) G. P. Miller, C. R. Chim. 2006, 9,952;
    • (2006) C. R. Chim , vol.9 , pp. 952
    • Miller, G.P.1
  • 51
    • 0004106186 scopus 로고    scopus 로고
    • 2nd ed, McGraw Hill, Singapore
    • M. B. Smith, Organic Synthesis, 2nd ed., McGraw Hill, Singapore, 2004, p. 104.
    • (2004) Organic Synthesis , pp. 104
    • Smith, M.B.1
  • 52
    • 34250857196 scopus 로고    scopus 로고
    • C1-symmetric compounds were prepared as racemates
    • 1-symmetric compounds were prepared as racemates.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.