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For high electronic excitation of metal substrate-adsorbate systems, desorption is generally associated with a DIMET (desorption induced by multiple electronic transitions) picture of repeated electron attachment to a short-lived adsorbate electronic state. Such a picture is not expected to be applicable here, given the system properties. The multielectron effect here is presumably caused by the relatively high density of electrons injected into the water layer
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For high electronic excitation of metal substrate-adsorbate systems, desorption is generally associated with a DIMET (desorption induced by multiple electronic transitions) picture of repeated electron attachment to a short-lived adsorbate electronic state. Such a picture is not expected to be applicable here, given the system properties. The multielectron effect here is presumably caused by the relatively high density of electrons injected into the water layer.
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Note that a similar fluence dependence and 2PC have previously been observed for femtosecond laser-induced water desorption from Ag nanoparticles (ref 22). On these grounds, phonon-mediated desorption was concluded in that study, in which TOF measurements were not reported. Our results show that these results may also be explained by an electron-mediated, many-electron process.
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Note that a similar fluence dependence and 2PC have previously been observed for femtosecond laser-induced water desorption from Ag nanoparticles (ref 22). On these grounds, phonon-mediated desorption was concluded in that study, in which TOF measurements were not reported. Our results show that these results may also be explained by an electron-mediated, many-electron process.
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We carefully checked that the H2O does not contain traces of D2O
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2O.
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22
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