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Angewandte Chemie - International Edition

Volumn 46, Issue 24, 2007, Pages 4461-4463

A coordination polymer of gold(I) with heterotactic architecture and a comparison of the structures of isotactic, syndiotactic, and heterotactic isomers

(2) Wheaton, Craig A a Puddephatt, Richard J a

a UNIVERSITY OF WESTERN ONTARIO (Canada)

Author keywords

Chirality; Gold; Polymers; Self assembly; Supramolecular chemistry

Indexed keywords

CHIRALITY; LIGANDS; POLYMER BLENDS; SELF ASSEMBLY; SUPRAMOLECULAR CHEMISTRY; SYNTHESIS (CHEMICAL);

HETEROTACTIC ARCHITECTURE; NAPHTHYL GROUPS; STRUCTURAL COMPARISON; SYNDIOTACTIC;

GOLD COMPOUNDS;

EID: 34250719933 PISSN: 14337851 EISSN: None Source Type: Journal
DOI: 10.1002/anie.200701325 Document Type: Article

Times cited : (38)

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18
- 34250707582
- 2: C58H40Au2F6N 2O4P2, Mr, 1398.82, orthorhombic, space group C2221, Z, 8, a, 11.8033(3, b, 28.8564(4, c, 38.3325(9) Å, V, 13056.1(5) Å3, μ(MoKα, 0.71073 Å, T, 150(2) K, 21457 reflections collected, 11503 unique, R 1(I>2σI, 0.0425, wR2, 0.1246. 4: C61.50H51Au2Cl3F6N 2O6P2, Mr, 1590.27, orthorhombic, space group Pbca, a, 14.6995(2, b, 25.8284(3, c, 32.3400(4) Å, V, 12278.4(3) Å3, μ(MoKα, 0.71073 Å, T, 150(2) K, 40220 reflections collected, 10836 unique, R1I>2σI, 0.0476, wR
- - anions and 2.35 dichloroethane molecules per asymmetric unit of 5. CCDC-641696-641698 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.

19
- 34250722432
- 31P NMR resonances are too broad to allow resolution of peaks for specific triads S,S,S, S,R,S, S,S,R.
- 31P NMR resonances are too broad to allow resolution of peaks for specific triads S,S,S, S,R,S, S,S,R.

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