Linear gold(I) coordination polymers: A polymer with a unique sine wave conformation

Journal of the American Chemical Society

Volumn 118, Issue 51, 1996, Pages 13101-13102

  Irwin, Michael J ^a   Vittal, Jagadese J ^a   Yap, Glenn P A ^b   Puddephatt, Richard J ^a  

^a UNIVERSITY OF WESTERN ONTARIO   (Canada)

^b UNIVERSITY OF WINDSOR   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

GOLD DERIVATIVE;

ARTICLE; DRUG STRUCTURE; POLYMERIZATION;

EID: 0030461906     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja963441k     Document Type: Article

References (15)

1. Che, C. M.; Lo, W. C.; Peng, S. M.; Tzeng, B. C. J. Chem. Soc., Chem. Commun. 1996, 181-182.
2. Irwin, M. J.; Jia, G.; Payne, N. C.; Puddephatt, R. J. Organometallics 1996, 15, 51-57.
3. Che, C. M.; Hong, X.; Peng, S. M.; Shieh, S. J. J. Chem. Soc., Dalton Trans. 1994, 3067-3068.
4. Van Calcar, P. M.; Olmstead, M. M.; Balch, A. L. J. Chem. Soc., Chem. Commun. 1995, 1773-1774.
5. Mingos, D. M. P.; Yau, J.; Menzer, S.; Williams, D. J. Angew. Chem., Int. Ed. Engl. 1995, 34, 1894-1895.
6. Irwin, M. J.; Puddephatt, R. J.; Rendina, L. M.; Vittal, J. J. J. Chem. Soc., Chem. Commun. 1996, 1281-1282.
7. Jia, G.; Scott, J. D.; Vittal, J. J.; Puddephatt. R. J. Organometallics 1993, 12, 3565-3574.
8. (a) Schmidbaur, H.; Wohlleben. A.; Wagner, F.; Orama, O.; Huttner, G. Chem. Ber. 1977, 110, 1748-1754.
9. (b) Bates, P. A.; Waters, J. M. Inorg. Chim. Acta 1985, 98, 125-129.
10. (c) Chodosh, D. F.; Eggleston, D. S.; Girard, G. R.; Hill, D. T. Inorg. Chim. Acta 1985, 108, 221-226.
11. (d) Cooper, M. K.; Hendrick, K.; McPartlin, M. L.; Mitchell, E.; Scott, A. Inorg. Chim. Acta 1984, 84, L9-L10.
12. Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1990, 112, 1546-1554.
13. 31P NMR spectrum of 10 at -90°C contains three sharp peaks at δ(P) = 23.4, 26.8, and 27.1, probably indicating the presence of at least two rapidly equilibrating species.
14. w = 0.0633. (The shortest Au..O(trifluoroacetate) contact is 2.91 Å.)
15. Note that a coordination polymer with trigonal planar gold(I) centers has been characterized and that several simple gold(I) compounds, such as AuCl, have polymeric structures. Hor, T. S. A.; Houlton, A.; Mingos, D. M. P.; Murphy, D. M.; Phang, L. T.; Williams, D. J. J. Chem. Soc., Dalton. Trans. 1993, 3629-3630.