Modification of sulfonated poly(ether ether ketone) with phenolic resin

Polymers for Advanced Technologies

Volumn 18, Issue 6, 2007, Pages 419-426

  Deb, Pramil C ^a,b   Rajput, L D ^a,c   Hande, V R ^a   Sasane, S ^a   Kumar, A ^a  

^a NAVAL MATERIALS RESEARCH LABORATORY   (India)

^b DEFENCE INSTITUTE OF ADVANCED TECHNOLOGY   (India)

^c INDIAN INSTITUTE OF TECHNOLOGY   (India)

Author keywords

Crosslinking; Phenol formaldehyde resin; Proton conductivity; Sulfonated poly (ether ether ketone)

Indexed keywords

ASSOCIATION REACTIONS; CROSSLINKING; DIMETHYLFORMAMIDE; ION EXCHANGE; PHENOLIC RESINS; POLARIZATION; PROTON CONDUCTIVITY;

DIMETHYL AMINE; SULFONATED POLYETHER ETHER KETONE; WATER UPTAKE;

POLYETHER ETHER KETONES;

ASSOCIATION REACTIONS; CROSSLINKING; DIMETHYLFORMAMIDE; ION EXCHANGE; PHENOLIC RESINS; POLARIZATION; POLYETHER ETHER KETONES; PROTON CONDUCTIVITY;

ALKALI TREATMENT; CONDUCTIVITY; CROSS LINKING; CURING; FILM; FORMALDEHYDE; FUEL CELL; ION EXCHANGE; MECHANICAL PROPERTY; MODIFICATION; POLYETHER ETHER KETONE; SOLUBILITY; SOLVENT; SYNTHETIC RESIN;

EID: 34250674064     PISSN: 10427147     EISSN: 10991581     Source Type: Journal    
DOI: 10.1002/pat.830     Document Type: Article

References (21)

1. Guo Q, Pintauro PN, Tang H, O'Connor S. Sulfonated and Crosslinked Polyphosphazene-Based Proton-Exchange Membranes. J. Membr. Sci. 1999; 154: 175.
2. Kim H, Litt M. Synthesis and characterization of sulfonated polyamide for fuel cell application. Polym. Prepr. Am. Chem. Soc. Divn. Polym. Chem. 2002; 42: 486.
3. Wainright JS, Wang JT, Weng D, Savinell RF, Litt M. Acid-Doped Polybenzimidazoles: A New Polymer Electrolyte. J. Electrochem. Soc. 1995; 142: L121.
4. Nolte R, Ledjeff K, Bauer M, Mülhaupt R. Partially sulfonated poly(arylene ether sulfone) - A versatile proton conducting membrane material for modern energy conversion technologies. J. Membr. Sci. 1993; 83: 211.
5. Park HB, Shin HS, Lee YM, Rhim JW. Annealing effect of sulfonated polysulfone ionomer membranes on proton conductivity and methanol transport. J. Membr. Sci. 2005; 247: 103.
6. Wang F, Hickner M, Kim YS, Zawodzinski TA, McGrath JE. Direct polymerization of sulfonated poly(arylene ether sulfone) random (statistical) copolymers: candidates for new proton exchange membranes. J. Membr. Sci. 2002; 197: 231.
7. Xing P, Robertson GP, Guiver MD, Mikhailenko SD, Wang K, Kaliaguine S. Synthesis and characterization of sulfonated poly(ether ether ketone) for proton exchange membranes. J. Membr. Sci. 2004; 229: 95.
8. Kobayashi T, Rikukawa M, Sanui K, Ogata N. Proton-conducting polymers derived from poly (ether-etherketone) and poly (4- phenoxybenzoyl-1, 4-phenylene). Solid State Ionics 1998; 106: 219.
9. Zaidi SMJ, Mikhailenko SD, Robertson GP, Guiver MD, Kaliaguine S. Proton conducting composite membranes from polyether ether ketone and heteropolyacids for fuel cell applications. J. Membr. Sci. 2000; 173: 17.
10. Ren S, Li C, Zhao X, Wu Z, Wang S, Sun G, Xin Q, Yang X. Surface modification of sulfonated poly (ether ether ketone) membranes using Nafion solution for direct methanol fuel cells. J. Membr. Sci. 2005; 247: 59.
11. Kreuer KD. On the Development of Proton Conducting Polymer Membranes for Hydrogen and Methanol Fuel Cells. J. Membr. Sci. 2001; 185: 29.
12. Harrison WL, Wang F, Mecham JB, Bhanu VA, Hill M, Kim YS, McGrath JE. Influence of the bisphenol structure on the direct synthesis of sulfonated poly (arylene ether) copolymers. J. Polym. Sci. Polym. Chem. 2003; 41: 2264.
13. Gil M, Ji X, Li X, Na H, Hampsey JE, Lu Y. Direct synthesis of sulfonated aromatic poly (ether ether ketone) proton exchange membranes for fuel cell applications. J. Membr. Sci. 2004; 234: 75.
14. Trotta F, Drioli E, Morgalio, G, Baima Poma E. Sulfonation of polyetheretherketone by chlorosulfuric acid. J. Appl. Polym. Sci. 1998; 70: 477.
15. Helmer-Metzmann F, Osan F, Schneller A, Ritter H, Ledjeff K, Nolte R, Thorwirth R. US Patent No. 5438082, 1995.
16. Mao S, Hamrock SJ, Ylitalo, DA. US Patent No. 6090895, 2000.
17. Mikhailenko, SD, Wang K, Kaliaguine S, Xing P, Robertson GP, Guiver MD. Proton conducting membranes based on cross-linked sulfonated poly (ether ether ketone). J. Membr. Sci. 2004; 233: 93.
18. Robertson GP, Mikhailenko SD, Wang K, Xing P, Guiver MD, Kaliaguine S. Casting Solvent Interactions with Sulfonated Poly (Ether Ether Ketone) during Proton Exchange Membrane Fabrication. J. Membr. Sci. 2004; 219: 93.
19. Slade S, Campbell SA, Ralph TR, Walsh FC. Ionic Conductivity of an Extruded Nafion 1100 EW Series of Membranes. J. Electrochem. Soc. 2002; 149: A-1556.
20. Yin Y, Hayashi S, Yamada O, Kita H, Okamoto K. Pranched/Crosslinked Sulfonated Polylmide Membranes for Polymer Electrolyte Fuel Cells. Macromol. Rapid Commun. 2005; 26; 696.
21. Muthu Lakshmi RTS, Choudhary V, Varma IK. Sulphonated poly (etheretherketone): Synthesis and characterization. J. Mater. Sci. 2005; 40: 629.